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We present a setup for time-resolved X-ray diffraction based on a short pulse, laser-driven plasma X-ray source. The employed modular design provides high flexibility to adapt the setup to the specific requirements (e.g., X-ray optics and sample environment) of particular applications. The configuration discussed here has been optimized toward high angular/momentum resolution and uses Kα-radiation (4.51 keV) from a Ti wire-target in combination with a toroidally bent crystal for collection, monochromatization, and focusing of the emitted radiation. 2 × 10 5 Ti-Kα1 photons per pulse with 10 − 4 relative bandwidth are delivered to the sample at a repetition rate of 10 Hz. This allows for the high dynamic range (104) measurements of transient changes in the rocking curves of materials as for example induced by laser-triggered strain waves.

Intense femtosecond laser excitation can produce transient states of matter that would otherwise be inaccessible to laboratory investigation. At high excitation densities, the interatomic forces that bind solids and determine many of their properties can be substantially altered. Here, we present the detailed mapping of the carrier density-dependent interatomic potential of bismuth approaching a solid-solid phase transition. Our experiments combine stroboscopic techniques that use a high-brightness linear electron accelerator-based x-ray source with pulse-by-pulse timing reconstruction for femtosecond resolution, allowing quantitative characterization of the interatomic potential energy surface of the highly excited solid.

In the last few years, bent crystal x-ray mirrors have played an important role in time-resolved x-ray diffraction experiments when x-ray pulses from femtosecond laserproduced plasmas were used. Improvements in manufacturing techniques have significantly increased the quality of this type of mirror.

The transient acoustic response of a free-standing, polycrystalline thin Au film upon femtosecond optical excitation has been studied by time-resolved Debye-Scherrer X-ray diffraction using ultrashort Cu K\\(_{\\alpha}\\) X-ray pulses from a laser-driven plasma X-ray source. The temporal strain evolution has been determined from the transient shifts of multiple Bragg diffraction peaks. The experimental data are in good agreement with the results of calculations based on the two-temperature model and an acoustic model assuming uni-axial strain propagation in the laser-excited thin film.

In phase-change memory devices, a material is cycled between glassy and crystalline states. The highly temperature-dependent kinetics of its crystallization process enables application in memory technology, but the transition has not been resolved on an atomic scale. Using femtosecond x-ray diffraction and ab initio computer simulations, we determined the time-dependent pair-correlation function of phase-change materials throughout the melt-quenching and crystallization process.We found a liquid–liquid phase transition in the phase-change materials Ag₄In₃Sb67Te26 and Ge15Sb85 at 660 and 610 kelvin, respectively. The transition is predominantly caused by the onset of Peierls distortions, the amplitude of which correlates with an increase of the apparent activation energy of diffusivity. This reveals a relationship between atomic structure and kinetics, enabling a systematic optimization of the memory-switching kinetics.

In phase-change memory devices, a material is cycled between glassy and crystalline states. The highly temperature-dependent kinetics of its crystallization process enables application in memory technology, but the transition has not been resolved on an atomic scale. Using femtosecond x-ray diffraction and ab initio computer simulations, we determined the time-dependent pair-correlation function of phase-change materials throughout the melt-quenching and crystallization process. We found a liquid–liquid phase transition in the phase-change materials Ag4In3Sb67Te26 and Ge15Sb85 at 660 and 610 kelvin, respectively. The transition is predominantly caused by the onset of Peierls distortions, the amplitude of which correlates with an increase of the apparent activation energy of diffusivity. As a result, this reveals a relationship between atomic structure and kinetics, enabling a systematic optimization of the memory-switching kinetics.