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The other dark matter : the science and business of turning waste into wealth and health
\"In the world today, we face considerable challenges, and while new ones pile on, the old standbys of fossil fuel overuse, greenhouse gas emissions, resource scarcity, food security, and weather and water extremes like droughts and floods remain. Fortunately, scientists are studying myriad ways human waste can help. Science journalist Lina Zeldovich argues in The Other Dark Matter that human excrement is a resource, cheap and widely available, that can be converted into a sustainable energy source, act as an organic fertilizer, provide effective medicinal therapy for resistant bacterial infection, and much more. Zeldovich profiles the pioneers of this repurposing, including startups in remote African villages and those in American cities that convert sewage into crude oil and collect specimens from volunteers to treat patients battling superbugs. The Other Dark Matter begins with a broad overview of our history of excrement disposal. The author's vignettes touch on ancient Roman sewage systems, Medieval latrines, and other methods used around the world to distance people from their excrement. Today's immense, computerized treatment plants are only the latest in a long line of engineering marvels that have distanced us from disease, she shows, but, importantly, they have also caused considerable damage to our earth's ecology. Zeldovich explains the massive redistribution of nutrients and sanitation inequities across the globe, drawing on her research and many interviews\"-- Provided by publisher.
Book
Analysis of the comprehensive management of sewage sludge in Poland
The methods of sewage sludge management in Poland have largely been determined by the legal requirements related to the Poland’s membership in the European Union. Since 1st January 2016, sewage sludge landfilling is prohibited. It must be emphasised that legal changes regarding wastewater management, along with the systematic increase in the volume of produced sludge, entail the necessity to change the existing method of sewage sludge management. This paper contains an analysis of solutions for management of sewage sludge produced in Poland over the period of 8 years. The goal of the work was an assessment of comprehensive management of sewage sludge produced in Poland from 2009 to 2016. Despite the decrease in the agricultural use of sewage sludge, their average share of 32% was the highest among other forms of sewage sludge management in Poland. Another form, related with the final stage of sewage sludge management, concerned its thermal processing. It was treated as a promising method, with a 19% increase over the analysed period. An optimal solution should be found to ensure safe management of sewage sludge.
Journal Article
Hydrothermal Carbonization of Sewage Sludge into Solid Biofuel: Influences of Process Conditions on the Energetic Properties of Hydrochar
Hydrothermal carbonization (HTC) is an attractive, green technology for the management of sewage sludge. In this study, low-value secondary sewage sludge was subjected to an HTC treatment in a 1 L batch hydrothermal reactor and transformed into a high-energy-density hydrochar under varying HTC conditions (temperature of 150–300 °C, carbonization time of 30–150 min and a solid loading of 10–30%). The resulting hydrochar fuel characteristics were analyzed for ultimate and proximate analyses, functional group composition and energetic parameters. It was found that the hydrochar yield decreased with the increasing HTC temperature and reaction time, primarily due to the loss of organic volatile matter and functional groups. Under the optimum conditions of 150 °C, 30 min of carbonization time and 30% solid loading, 80.56% of the hydrochar was recovered, providing a maximum energy yield of 90.32% and a high heating value of 18.49 MJ/kg. Compared to the raw sewage sludge (H/C ratio of 2.67 and O/C ratio of 0.51), the hydrochar also had lower H/C and O/C atomic ratios of 1.42 and 0.18, respectively. The results suggest that significant dehydration and decarboxylation during the HTC treatment of sewage sludge have resulted in the formation of carbonaceous hydrochar with energetic properties close to the sub-bituminous coals.
Journal Article
Photo-Activated Sludge : a novel algal-bacterial biotreatment for nitrogen removal from wastewater
Ammoniumrijk afvalwater wordt veelal geproduceerd door gemeentelijk, industrieel en landbouwafval, en effluent uit anaerobe afvalwaterzuiveringsmethoden. Dit vormt een risico voor het milieu vanwege de hoge concentratie aan voedingsstoffen (stikstof en fosfor), wat eutrofièering in waterpartijen kan bevorderen en daarmee de kwaliteit van ecosystemen kan aantasten. Als innovatieve oplossing hierop is een nieuw biologisch verwerkingsmechanisme genaamd Photo-Activated Sludge (PAS) geèevalueerd, wat gebruik maakt van een consortium van microalgen en bacterièen voor de zuivering van ammoniumrijk afvalwater.
Book
Present restrictions of sewage sludge application in agriculture within the European Union
The use of sludge in agriculture within the European Union (EU) is currently regulated only by the limits of heavy metals (Cd, Cu, Hg, Ni, Pb and Zn) listed in Council Directive 86/278/EEC. This document is now more than 30 years old. Several European countries have introduced more stringent requirements in comparison with the directive, and have adopted limits for concentrations of other heavy metals, synthetic organic compounds and microbial contamination. The paper provides an overview of the current limits of these substances in sewage sludge and concentration limits of heavy metals in soil intended for sludge application, together with applicable laws and regulations in European Union countries. There is a need to update these regulations taking into account the current risks associated with the application of sludge to agricultural land, with the possibility of using ecotoxicological tests to assess the risks. A wide range of technologies for sewage sludge processing is used in EU countries. The predominant choice is a direct application in agriculture followed by composting. The use of sewage sludge in agriculture in 2014 and 2015 in 13 EU countries that provided data amounted to 22.6% (2014) and 22.1% (2015) of produced sludge and 23.3% (2014) and 23.1% (2015) of sludge disposed. It is also highly variable within EU countries ranging between zero (Malta, Slovenia, Slovakia) and 80% (Ireland). Over 50% of sewage sludge is used in agriculture in Bulgaria according to 2015 data.
Journal Article
Development and Substantiation of Approaches to the Management of Sewage Sludge of Different Storage Periods
A widespread method of sewage sludge disposal is still simple storage in sludge lagoons. Subsequent thermal utilization is hardly possible because sludge properties change over time and energy content is reduced. Use as a soil conditioner in agriculture or landscaping is usually not possible due to high heavy metal contents. This paper describes a method in which a 10-year-old accumulated sewage sludge can be utilized as technical soil by mixing it with pyrolized fresh sewage sludge. For this purpose, physicochemical and toxicological characteristics of sewage sludge of different storage periods were identified, processes of thermal destruction of sewage sludge analyzed, toxicological characteristics of solid products of thermal sludge treatment determined, and the possibility of using the sewage sludge–pyrolysate mixture as technical soil was assessed. Results show that the gross calorific value of fresh and one-year stored sewage sludge is with approx. 15,000 kJ/kg dry basis sufficient to produce pyrolysate autothermally. It is also shown that when the pyrolysis residue is mixed with fresh or 1-year old sewage sludge, heavy metals can be immobilized and thus the leaching of heavy metals significantly reduced by up to 75%. The method described can thus be a possible option for recycling accumulated sewage sludge.
Journal Article
From Sewage Sludge to the Soil—Transfer of Pharmaceuticals: A Review
Sewage sludge, produced in the process of wastewater treatment and managed for agriculture, poses the risk of disseminating all the pollutants contained in it. It is tested for heavy metals or parasites, but the concentration of pharmaceuticals in the sludge is not controlled. The presence of these micropollutants in sludge is proven and there is no doubt about their negative impact on the environment. The fate of these micropollutants in the soil is a new and important issue that needs to be known to finally assess the safety of the agricultural use of sewage sludge. The article will discuss issues related to the presence of pharmaceuticals in sewage sludge and their physicochemical properties. The changes that pharmaceuticals undergo have a significant impact on living organisms. This is important for the implementation of a circular economy, which fits perfectly into the agricultural use of stabilized sewage sludge. Research should be undertaken that clearly shows that there is no risk from pharmaceuticals or vice versa: they contribute to the strict definition of maximum allowable concentrations in sludge, which will become an additional criterion in the legislation on municipal sewage sludge.
Journal Article
Application of electron beam water radiolysis for sewage sludge treatment—a review
A review of the applicability of electron beam water radiolysis for sewage sludge treatment is presented. Electron beam treatment has been proven to be a successful approach to the disinfection of both wastewater and sewage sludge. Nevertheless, before 2000, there were concerns about the perceived high capital costs of the accelerator and with public acceptance of the usage of radiation for water treatment purposes. Nowadays, with increased knowledge and technological development, it may be not only possible but also desirable to use electron beam technology for risk-free sewage sludge treatment, disposal and bio-friendly fertiliser production. Despite the developing interest in this method, there has been no attempt to perform a review of the pertinent literature relating to this technology. It appears that understanding of the mechanism and primary parameters of disinfection is key to optimising the process. This paper aims to reliably characterise the sewage sludge electron beam treatment process to elucidate its major issues and make recommendations for further development and research.
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Journal Article
Study on the performance of sewage sludge biochar modified by nZVI to remove Cu(II) and Cr(VI) in water
In this study, to simultaneously dispose of sludge and wastewater containing heavy metals, sludge biochar loaded with nano zero-valent-iron (nZVI) was prepared at 700 °C (nBC700) to remove Cr(VI) and Cu(II). The results showed the removal capacity of biochar was greatly improved by loading nZVI, and the adsorption capacities of biochar for Cu(II) and Cr(VI) increased by 251.96% and 205.18%. Pseudo-second-order kinetic and Sips isotherm models were fitted to the removal processes. Intraparticle diffusion models showed the removal process was controlled by surface diffusion and intraparticle diffusion. Competitive experiments showed Cr(VI) can compete with Cu(II) for active sites, but Cr(VI) was more easily removed by nBC700 through cation bridge. The removal mechanism illustrated removing Cu(II) mainly depended on complex precipitation, followed by reduction reaction, while Cr(VI) was on the contrary. This work provided effective data for sludge disposal and heavy metal removal.
Journal Article