Asset Details
Do you wish to reserve the book?
Solvent and Zn2+ Binding Effects on the Photo-physical Properties of (Dibenzoylmethanato)boron Difluoride
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Solvent and Zn2+ Binding Effects on the Photo-physical Properties of (Dibenzoylmethanato)boron Difluoride
Do you wish to request the book?
Solvent and Zn2+ Binding Effects on the Photo-physical Properties of (Dibenzoylmethanato)boron Difluoride
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Solvent and Zn2+ Binding Effects on the Photo-physical Properties of (Dibenzoylmethanato)boron Difluoride
2012
Overview
Absorption and emission spectroscopic studies of (dibenzoylmethanato)boron difluoride (1bf) in various polar and non-polar, protic and aprotic solvents are reported. The solvatochromic shifts of the spectral bands were examined in terms of solvent properties, including donor and acceptor numbers, followed by multilinear regression in which several solvent parameters were simultaneously analyzed. This π-conjugated positively charged system exhibits excellent solvatochromism. Variations in the electronic absorption spectral characteristics of 1bf were studied in solution in the presence of zinc perchlorate. Absorption spectral studies indicate stable complex formation between the zinc ion and 1bf in the ground state in aprotic dipolar benzonitrile rather than in protic polar solvent methanol. Zinc ion binding of 1bf was theoretically rationalized through frontier molecular orbital interaction.
Publisher
Springer Nature B.V
Subject
