Asset Details
Do you wish to reserve the book?
Successive Short- and Long-Range Magnetic Ordering in Basub.2Mnsub.3sub.6 with Honeycomb Layers of Mnsup.3+ Ions Alternating with Triangular Layers of Mnsup.2+ Ions
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Successive Short- and Long-Range Magnetic Ordering in Basub.2Mnsub.3sub.6 with Honeycomb Layers of Mnsup.3+ Ions Alternating with Triangular Layers of Mnsup.2+ Ions
Do you wish to request the book?
Successive Short- and Long-Range Magnetic Ordering in Basub.2Mnsub.3sub.6 with Honeycomb Layers of Mnsup.3+ Ions Alternating with Triangular Layers of Mnsup.2+ Ions
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Successive Short- and Long-Range Magnetic Ordering in Basub.2Mnsub.3sub.6 with Honeycomb Layers of Mnsup.3+ Ions Alternating with Triangular Layers of Mnsup.2+ Ions
2023
Overview
Mixed-valent Ba[sub.2]Mn[sup.2+]Mn[sub.2] [sup.3+](SeO[sub.3])[sub.6] crystallizes in a monoclinic P2[sub.1]/c structure and has honeycomb layers of Mn[sup.3+] ions alternating with triangular layers of Mn[sup.2+] ions. We established the key parameters governing its magnetic structure by magnetization M and specific heat C[sub.p] measurements. The title compound exhibits a close succession of a short-range correlation order at Tcorr = 10.1 ± 0.1 K and a long-range Néel order at TN = 5.7 ± 0.1 K, and exhibits a metamagnetic phase transition at T < TN with hysteresis most pronounced at low temperatures. The causes for these observations were found using the spin exchange parameters evaluated by density functional theory calculations. The title compound represents a unique case in which uniform chains of integer spin Mn[sup.3+] (S = 2) ions interact with those of half-integer spin Mn[sup.2+] (S = 5/2) ions.
Publisher
MDPI AG
Subject
