Journal Article

Recent Progress of Ion-Modified TiOsub.2 for Enhanced Photocatalytic Hydrogen Production

Liu, Penglan, Tang, Xiao, Huang, Qiao, Li, Tingxian, Zhao, Dongqiu, Ju, Lin

2024

Overview

Harnessing solar energy to produce hydrogen through semiconductor-mediated photocatalytic water splitting is a promising avenue to address the challenges of energy scarcity and environmental degradation. Ever since Fujishima and Honda’s groundbreaking work in photocatalytic water splitting, titanium dioxide (TiO[sub.2]) has garnered significant interest as a semiconductor photocatalyst, prized for its non-toxicity, affordability, superior photocatalytic activity, and robust chemical stability. Nonetheless, the efficacy of solar energy conversion is hampered by TiO[sub.2]’s wide bandgap and the swift recombination of photogenerated carriers. In pursuit of enhancing TiO[sub.2]’s photocatalytic prowess, a panoply of modification techniques has been explored over recent years. This work provides an extensive review of the strategies employed to augment TiO[sub.2]’s performance in photocatalytic hydrogen production, with a special emphasis on foreign dopant incorporation. Firstly, we delve into metal doping as a key tactic to boost TiO[sub.2]’s capacity for efficient hydrogen generation via water splitting. We elaborate on the premise that metal doping introduces discrete energy states within TiO[sub.2]’s bandgap, thereby elevating its visible light photocatalytic activity. Following that, we evaluate the role of metal nanoparticles in modifying TiO[sub.2], hailed as one of the most effective strategies. Metal nanoparticles, serving as both photosensitizers and co-catalysts, display a pronounced affinity for visible light absorption and enhance the segregation and conveyance of photogenerated charge carriers, leading to remarkable photocatalytic outcomes. Furthermore, we consolidate perspectives on the nonmetal doping of TiO[sub.2], which tailors the material to harness visible light more efficiently and bolsters the separation and transfer of photogenerated carriers. The incorporation of various anions is summarized for their potential to propel TiO[sub.2]’s photocatalytic capabilities. This review aspires to compile contemporary insights on ion-doped TiO[sub.2], propelling the efficacy of photocatalytic hydrogen evolution and anticipating forthcoming advancements. Our work aims to furnish an informative scaffold for crafting advanced TiO[sub.2]-based photocatalysts tailored for water-splitting applications.

• Publisher: MDPI AG
• Subject: Hydrogen