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The pulsed wire method is an attractive option to measure the magnetic field in insertion devices, mainly for those with restricted access (e.g., small gaps, in-vacuum/cryogenic environments, etc.). Besides first and second field integrals, experiments have proved the feasibility of reconstructing the magnetic field profile. Undulators with a small gap and short period are — and are planned to be — used at diffraction-limited storage rings and free-electron lasers. This contribution outlines the pulsed wire system’s requirements to perform magnetic field reconstruction in such undulators. We examine the main expected limitations, particularly the dispersive, finite pulse-width, discretization error, and sag effects. Furthermore, we present the current status of developing the pulsed wire system at the European XFEL.

Bioluminescence (BL) and chemiluminescence (CL) are interesting and intriguing phenomena that involve the emission of visible light as a consequence of chemical reactions. The mechanistic basis of BL and CL has been investigated in detail since the 1960s, when the synthesis of several models of cyclic peroxides enabled mechanistic studies on the CL transformations, which led to the formulation of general chemiexcitation mechanisms operating in BL and CL. This review describes these general chemiexcitation mechanisms—the unimolecular decomposition of cyclic peroxides and peroxide decomposition catalyzed by electron/charge transfer from an external (intermolecular) or an internal (intramolecular) electron donor—and discusses recent insights from experimental and theoretical investigation. Additionally, some recent representative examples of chemiluminescence assays are given.

At the European XFEL, we are designing a superconducting afterburner for the SASE2 hard X-ray beamline. It will consist of a series of five undulator modules plus a pre-series one called S-PRESSO. One module corresponds to two superconducting undulator (SCU) coils of 2m length plus one phase shifter. Such an afterburner will enable photon energies above 30 keV. We foresee to install superconducting (SC) phase shifters in each undulator module to keep the correct phase delay between the electron beam and photon beam. In this contribution, we present the required SC phase shifter parameters to enable operation in the electron beam energy range 11.5-17.5 GeV. We also analyze different magnetic designs satisfying the calculated specifications.

Up to six superconducting undulator (SCU) modules are foreseen to be installed downstream with respect to the permanent magnet undulators of SASE2, one of the two hard X-ray lines at European XFEL. Aim is to provide users with photon energies above 30 keV. The superconducting undulator pre-series module (S-PRESSO) is currently under production. Before installation in the tunnel, the magnetic structures are characterized in the vertical He bath cryostat SUNDAE1 (Superconducting UNDulAtor Experiment), and in the horizontal test stand to perform quality assurance of the SCU coils installed in the final cryostat SUNDAE2. This contribution describes the status of the project.

We propose to develop, characterize and operate a superconducting undulator (SCU) afterburner consisting of 5 undulator modules (1 module = 2 SCU coils of 2 m length and 1 phase shifter) plus a pre-series prototype at the SASE2 hard X-ray beamline of European XFEL. This afterburner will produce an output in the order of 10 10 ph/pulse at photon energies above 30 keV. The project is divided into the production of a pre-series prototype module and a small-series production of 5 modules. Central goals of this R&D activity are: the demonstration of the functionality of SCUs at an X-ray FEL, the set up of the needed infrastructure to characterize and operate SCUs, the industrialization of such undulators, and the reduction of the price per module. In this contribution, the main parameters and specifications of the pre-series prototype module are described.

The implementation and further improvements of superconducting undulators are part of the European XFEL facility development program. Within this program, a magnetic field test facility is being developed. Named SUNDAE2 (Superconducting UNDulAtor Experiment 2), it aims to perform in-vacuum magnetic field measurements of superconducting undulators (SCUs) with three techniques: Hall probe, moving wire, and pulsed wire. This contribution presents the updates and status of SUNDAE2.

Superconducting Undulators (SCUs) can produce higher photon flux and cover a wider photon energy range compared to permanent magnet undulators (PMUs) with the same vacuum gap and period length. To build the know-how to implement superconducting undulators for future upgrades of the European XFEL facility, the test stand SUNDAE1 for the characterization of SCU is being developed. The purpose of SUNDAE1 is the training, tuning and development of new SCU coils by means of precise magnetic field measurements. The experimental setup will allow the characterization of magnets up to 2m in length. These magnets will be immersed in a Helium bath at 4K or 2K temperature. In this article, we describe the experimental setup and highlight its expected performances.

β- and γ-lumicolchicines are photoproducts formed by the cycloisomerization of the tropolone ring of colchicine (COL) alkaloids. The mechanism of the photoconversion, suggested to involve the triplet state, is examined here by studying the effect of the solvent polarity on the lumicolchicine photoisomer ratio. Triplet COL, detected by laser flash photolysis, is quenched by oxygen, but not by trans-stilbene or 1-methylnaphtalene. Neither the quantum yield of conversion of COL nor the photoproduct ratio was altered by the presence of oxygen. Likewise, energy transfer to COL from triplet acetone produced by either isobutanal/horseradish peroxidase system or tetramethyldioxetane thermolysis failed to provoke photoreaction of COL. Our data argue against the intermediacy of a COL triplet state in the photoisomerization and stress on the role of specific solvent–solute interactions in determining the partitioning of excited singlet state into the β- and γ-isomer formation.

β‐ and γ‐lumicolchicines are photoproducts formed by the cycloisomerization of the tropolone ring of colchicine (COL) alkaloids. The mechanism of the photoconversion, suggested to involve the triplet state, is examined here by studying the effect of the solvent polarity on the lumicolchicine photoisomer ratio. Triplet COL, detected by laser flash photolysis, is quenched by oxygen, but not by trans‐stilbene or 1‐methylnaphtalene. Neither the quantum yield of conversion of COL nor the photoproduct ratio was altered by the presence of oxygen. Likewise, energy transfer to COL from triplet acetone produced by either isobutanal/horseradish peroxidase system or tetramethyldioxetane thermolysis failed to provoke photoreaction of COL. Our data argue against the intermediacy of a COL triplet state in the photoisomerization and stress on the role of specific solvent–solute interactions in determining the partitioning of excited singlet state into the β‐ and γ‐isomer formation.