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Volatiles like H2O are present as ice in solids in the cold outer regions of protoplanetary disks and as vapor in the warm inner regions within the water snow line. Icy pebbles drifting inwards from the outer disk sublimate after crossing the snow line, enriching the inner disk with solid mass and water vapor. Meanwhile, protoplanets forming within the disk open gaps in the disk gas, creating traps against the inward drift of pebbles and in turn reducing water enrichment in the inner disk. Recent disk observations from millimeter interferometry and infrared spectroscopy have supported this broad picture by finding a correlation between the outer radial distribution of pebbles and the properties of inner water vapor spectra. In this work, we aim at further informing previous and future observations by building on previous models to explore pebble drift in disks with multiple gaps. We systematically explore multiple gap locations and their depths (equivalent to the specific masses of planets forming within), and different particle sizes to study their impact on inner disk water enrichment. We find that the presence of close-in deep gaps carved by a Jupiter-mass planet is likely crucial for blocking icy pebble delivery into the inner disk, while planets with lower masses only provide leaky traps. We also find that disks with multiple gaps show lower vapor enrichment in the inner disk. Altogether, these model results support the idea that inner disk water delivery and planet formation are regulated by the mass and location of the most massive planets.

Substructures in protoplanetary disks can act as dust traps that shape the radial distribution of pebbles. By blocking the passage of pebbles, the presence of gaps in disks may have a profound effect on pebble delivery into the inner disk, crucial for the formation of inner planets via pebble accretion. This process can also affect the delivery of volatiles (such as H2O) and their abundance within the water snow line region (within a few au). In this study, we aim to understand what effect the presence of gaps in the outer gas disk may have on water vapor enrichment in the inner disk. Building on previous work, we employ a volatile-inclusive disk evolution model that considers an evolving ice-bearing drifting dust population, sensitive to dust traps, which loses its icy content to sublimation upon reaching the snow line. We find that the vapor abundance in the inner disk is strongly affected by the fragmentation velocity (v f) and turbulence, which control how intense vapor enrichment from pebble delivery is, if present, and how long it may last. Generally, for disks with low to moderate turbulence (α ≤ 1 × 10−3) and a range of v f, radial locations and gap depths (especially those of the innermost gaps) can significantly alter enrichment. Shallow inner gaps may continuously leak material from beyond it, despite the presence of additional deep outer gaps. We finally find that for realistic v f (≤10 m s−1), the presence of gaps is more important than planetesimal formation beyond the snow line in regulating pebble and volatile delivery into the inner disk.

We present the Interactive Spectral-Line Analysis Tool (iSLAT), a python-based graphical tool that allows users to interactively explore, inspect, and fit line emission observed in molecular spectra. iSLAT adopts a simple slab model in LTE that simulates emission spectra with a small set of parameters (temperature, emitting area, column density, and line broadening) that users can adjust in real time for multiple molecules or multiple thermal components of a same molecule. A central feature of iSLAT is the possibility to interactively inspect individual lines or line clusters to visualize their properties at high resolution and identify them in the population diagram. iSLAT provides a number of additional features, including the option to identify lines that are not blended at the instrumental resolution, the possibility to save custom line lists selected by the user, and to fit and measure their properties (line flux, width, and centroid) for later analysis. In this paper we launch the tool and demonstrate it on infrared spectra from the James Webb Space Telescope and ground-based instruments that provide higher resolving power. We also share curated line lists that are useful for the analysis of the forest of water emission lines observed from protoplanetary disks. iSLAT is shared with the community on GitHub.

The JWST Disk Infrared Spectral Chemistry Survey (JDISCS) aims to understand the evolution of the chemistry of inner protoplanetary disks using the Mid-InfraRed Instrument (MIRI) on the James Webb Space Telescope (JWST). With a growing sample of >30 disks, the survey implements a custom method to calibrate the MIRI Medium Resolution Spectrometer (MRS) to contrasts of better than 1:300 across its 4.9–28 μm spectral range. This is achieved using observations of Themis family asteroids as precise empirical reference sources. The high spectral contrast enables precise retrievals of physical parameters, searches for rare molecular species and isotopologues, and constraints on the inventories of carbon- and nitrogen-bearing species. JDISCS also offers significant improvements to the MRS wavelength and resolving power calibration. We describe the JDISCS calibrated data and demonstrate their quality using observations of the disk around the solar-mass young star FZ Tau. The FZ Tau MIRI spectrum is dominated by strong emission from warm water vapor. We show that the water and CO line emission originates from the disk surface and traces a range of gas temperatures of ∼500–1500 K. We retrieve parameters for the observed CO and H2O lines and show that they are consistent with a radial distribution represented by two temperature components. A high water abundance of n(H2O) ∼ 10−4 fills the disk surface at least out to the 350 K isotherm at 1.5 au. We search the FZ Tau environs for extended emission, detecting a large (radius of ∼300 au) ring of emission from H2 gas surrounding FZ Tau, and discuss its origin.

Previous analyses of mid-infrared water spectra from young protoplanetary disks observed with the Spitzer-IRS found an anticorrelation between water luminosity and the millimeter dust disk radius observed with ALMA. This trend was suggested to be evidence for a fundamental process of inner disk water enrichment proposed decades ago to explain some properties of the solar system, in which icy pebbles drift inward from the outer disk and sublimate after crossing the snow line. Previous analyses of IRS water spectra, however, were uncertain due to the low spectral resolution that blended lines together. We present new JWST-MIRI spectra of four disks, two compact and two large with multiple radial gaps, selected to test the scenario that water vapor inside the snow line is regulated by pebble drift. The higher spectral resolving power of MIRI-MRS now yields water spectra that separate individual lines, tracing upper level energies from 900 to 10,000 K. These spectra clearly reveal excess emission in the low-energy lines in compact disks compared to large disks, demonstrating an enhanced cool component with T ≈ 170–400 K and equivalent emitting radius R eq ≈ 1–10 au. We interpret the cool water emission as ice sublimation and vapor diffusion near the snow line, suggesting that there is indeed a higher inward mass flux of icy pebbles in compact disks. Observation of this process opens up multiple exciting prospects to study planet formation chemistry in inner disks with JWST.

EX Lup is a low-mass pre-main-sequence star that occasionally shows accretion-related outbursts. Here, we present JWST/MIRI medium-resolution spectroscopy obtained for EX Lup 14 yr after its powerful outburst. EX Lup is now in quiescence and displays a Class II spectrum. We detect a forest of emission lines from molecules previously identified in infrared spectra of classical T Tauri disks: H2O, OH, H2, HCN, C2H2, and CO2. The detection of organic molecules demonstrates that they are back after disappearing during the large outburst. Spectral lines from water and OH are for the first time deblended and will provide a much-improved characterization of their distribution and density in the inner disk. The spectrum also shows broad emission bands from warm, submicron-size amorphous silicate grains at 10 and 18 μm. During the outburst, in 2008, crystalline forsterite grains were annealed in the inner disk within 1 au, but their spectral signatures in the 10 μm silicate band later disappeared. With JWST we rediscovered these crystals via their 19.0, 20.0, and 23.5 μm emission, the strength of which implies that the particles are at ∼3 au from the star. This suggests that crystalline grains formed in 2008 were transported outwards and now approach the water snowline, where they may be incorporated into planetesimals. Containing several key tracers of planetesimal and planet formation, EX Lup is an ideal laboratory to study the effects of variable luminosity on the planet-forming material and may provide an explanation for the observed high crystalline fraction in solar system comets.

Transition disks, with inner regions depleted in dust and gas, could represent later stages of protoplanetary disk evolution when newly formed planets are emerging. The PDS 70 system has attracted particular interest because of the presence of two giant planets in orbits at tens of astronomical units within the inner disk cavity, at least one of which is itself accreting. However, the region around PDS 70 most relevant to understanding the planet populations revealed by exoplanet surveys of middle-aged stars is the inner disk, which is the dominant source of the system’s excess infrared emission but only marginally resolved by the Atacama Large Millimeter/submillimeter Array. Here we present and analyze time-series optical and infrared photometry and spectroscopy that reveal the inner disk to be dynamic on timescales of days to years, with occultation by submicron dust dimming the star at optical wavelengths, and 3–5 μm emission varying due to changes in disk structure. Remarkably, the infrared emission from the innermost region (nearly) disappears for ∼1 yr. We model the spectral energy distribution of the system and its time variation with a flattened warm (T ≲ 600 K) disk and a hotter (1200 K) dust that could represent an inner rim or wall. The high dust-to-gas ratio of the inner disk, relative to material accreting from the outer disk, means that the former could be a chimera consisting of depleted disk gas that is subsequently enriched with dust and volatiles produced by collisions and evaporation of planetesimals in the inner zone.

The mid-infrared water vapor emission spectrum provides a novel way to characterize the delivery of icy pebbles toward the innermost (<5 au) regions of planet-forming disks. Recently, JWST MIRI-MRS showed that compact disks exhibit an excess of low-energy water vapor emission relative to extended multigapped disks, suggesting that icy pebble drift is more efficient in the former. We carry out detailed emission-line modeling to retrieve the excitation conditions of rotational water vapor emission in a sample of four compact and three extended disks within the JWST Disk Infrared Spectral Chemistry Survey. We present two-temperature H2O slab model retrievals and, for the first time, constrain the spatial distribution of water vapor by fitting parametric radial temperature and column density profiles. Such models statistically outperform the two-temperature slab fits. We find a correlation between the observable hot water vapor mass and stellar mass accretion rate, as well as an anticorrelation between cold water vapor mass and submillimeter dust disk radius, confirming previously reported water line flux trends. We find that the mid-IR spectrum traces H2O with temperatures down to 180–300 K, but the coldest 150–170 K gas remains undetected. Furthermore the H2O temperature profiles are generally steeper and cooler than the expected “superheated” dust temperature in passive irradiated disks. The column density profiles are used to estimate icy pebble mass fluxes, which suggest that compact and extended disks may produce markedly distinct inner-disk exoplanet populations if local feeding mechanisms dominate their assembly.

It has been proposed, and confirmed by multiple observations, that disks around low-mass stars display a molecule-rich emission and carbon-rich disk chemistry as compared to their hotter, more massive solar counterparts. In this work, we present JWST Disk Infrared Spectral Chemistry Survey MIRI-MRS observations of the solar-mass star DoAr 33, a low-accretion rate T Tauri star showing an exceptional carbon-rich inner disk. We report detections of H2O, OH, and CO2, as well as the more complex hydrocarbons, C2H2 and C4H2. Through the use of thermochemical models, we explore different spatial distributions of carbon and oxygen across the inner disk and compare the column densities and temperatures obtained from LTE slab model retrievals. We find the best match to the observed column densities with models that have carbon enrichment, and the retrieved emitting temperature and area of C2H2 with models that have C/O = 2–4 inside the 500 K carbon-rich dust sublimation line. This suggests that the origin of the carbon-rich chemistry is likely due to the sublimation of carbon-rich grains near the soot line. This would be consistent with the presence of dust processing as indicated by the detection of crystalline silicates. We propose that this long-lived hydrocarbon-rich chemistry observed around a solar-mass star is a consequence of the unusually low M-star-like accretion rate of the central star, which lengthens the radial mixing timescale of the inner disk, allowing the chemistry powered by carbon grain destruction to linger.

We present a MIRI-MRS spectrum of the high-inclination protoplanetary disk around the solar-mass (K0) star MY Lup, obtained as part of the JWST Disk Infrared Spectral Chemistry Survey (JDISCS). The spectrum shows an unusually weak water emission spectrum for a disk around a star of its spectral type, but strong emission from CO2, HCN, and isotopologues of both molecules. This includes the first ever detection of C18O16O and H13CN in an inner disk, as well as tentative detections of C17O16O and HC15N. Slab modeling provides the molecular temperatures, column densities, and emitting areas of the detected molecules. The emitting molecular gas is cold compared to that of other observed protoplanetary disk spectra. We estimate the isotopologue ratios of CO2 and HCN, albeit with significant uncertainty. We suggest that the unusual spectrum of MY Lup arises from a combination of inner-disk clearing, which removes emission from warm water, and its nearly edge-on inclination, which enhances line-of-sight column densities, although unusual chemistry may also be required. MY Lup’s spectrum highlights the potential to detect and measure trace isotopologues to study isotopic fractionation in protoplanetary disks; observations at higher spectral resolving power are needed to constrain the isotopologue ratios to greater precision.