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Background Vaccine hesitancy is a concerning menace to the control of vaccine-preventable diseases. Effective health communication could promote an overall understanding of the importance, risks, and benefits of vaccination and reduce vaccine hesitancy. Methods In this survey, four fictitious newspaper articles addressing an emerging bogus disease and its vaccine were randomly assigned to participants. The first version focused on information about the disease; the second was akin to the first, including a case description and image. The third version focused on vaccine safety/efficacy; the fourth version was like the third, including a case description and image. After reading a single version of the article, participants responded if they would take the vaccine and if they would vaccinate their children. We used chi-squared tests for comparisons and investigated interactions with vaccine-hesitant attitudes. Results We included 5233 participants between August/2021 and January/2022; 790 were caregivers of a child ≤ 5 years old, and 15% had prior vaccine hesitancy. Although most declared intention to take the vaccine, the percentage was highest among those exposed to the newspaper article focusing on the vaccine safety/efficacy with the case description and picture (91%; 95% confidence interval 89–92%), and lowest among participants exposed to the article focusing on the disease with no case description (84%; 95% confidence interval 82–86%). Similar trends were observed in the intention of offspring vaccination. We found evidence of effect modification by vaccine-hesitant attitudes, with a higher impact of communication focusing on vaccine safety/efficacy compared to that focusing on disease characteristics among hesitant participants. Conclusion Communication strategies focusing on different aspects of the disease-vaccine duet may impact vaccine hesitancy, and storytelling/emotive imagery descriptions may improve risk perception and vaccine uptake. Moreover, the effect of message framing strategies may differ according to previous vaccine hesitant attitudes.

In the present work, a statistical optimization of a sustainable coating for core–shell NPK (Nitrogen–Phosphorus–Potassium) fertilizers was investigated. The environmental green coating was enriched in nitrogen using a biomass and renewable source, namely the nitrogen rich fraction of black soldier fly larvae (BSFL) ( Hermetia Illucens , Diptera: Stratiomyidae) reared on vegetable waste. A rational approach was proposed with the aim of calculating the best formulation of the coating, considering both its manufacturing behavior, such as adhesion to the core, and its physical properties, such as homogeneity or plasticity. From a circular economy perspective, together with the nitrogen-rich fraction from BSFL (from 51 to 90 wt.%), water and glycerol were considered for the coating formulation in different proportion: from 10 to 32 wt.% and from 0 to 17 wt.% respectively. The Design of Experiments technique was implemented to limit the total number of tests for the coating formulation (18 tests). ANOVA was employed, with the aim of obtaining mathematical models to derive a better precise and objective formulation. The results show that the use of glycerol can be avoided, as well as only a limited amount of water (11 wt.%) is necessary to obtain an optimized coating formulation, thereafter, satisfying the more relevant technological and physical properties for the coating manufacturing.

The aim of this research is to evaluate the possibility to realize alkali-activated materials exploiting biochar, a secondary raw material coming from pyrolysis/gasification processes, for environmental benefits, such as improvement of soil fertility and reduction of CO2 emissions into the atmosphere thanks to the carbon sink process where carbon dioxide is subtracted from the cycle of carbon. For the matrix of the geopolymers, a waste material derived from incinerator bottom ash was used and compared to pure metakaolin matrix. The materials obtained are lightweight and porous, with high water absorption capacity and moisture adsorption/desorption. BET analysis shows an increase in specific surface by increasing the biochar content and the biochar acts as a filler in the pores. From porosimetry analysis it is possible to follow the evolution of the curing process of the geopolymer prepared: specimens containing 70 wt% biochar after 28 and 90 days showed an increase in total Hg intrusion volume, pore area and total porosity but a decrease in the dimensions of pores. Due to the technical properties of materials containing biochar, they can be used in the future for a cleaner design of products in the field of sustainable construction for insulating panels or lightweight materials for houses and gardens in terraces and balconies.

The valorization of industrial waste is a hot topic toward circular economy and sustainability. Several wastes have been proposed as resources for different production processes; however, others are still disposed to landfill or waste-to-energy plants. For the first time, this work suggests a sustainable alternative to managing cork waste from bottle caps manufacturing; this is generated by a local company at about 220,000 m3/year. The powder waste has a 0.063–1 mm particle size and is mainly composed of cork, polyurethane adhesive, and paraffin. Its valorization is proposed as filler in construction materials such as lime-based mortar (1–4 wt%) and polyurethane (5–15 wt%). Thermal, spectroscopic, and physical characterizations are performed on the cork waste, and mainly result in a low apparent density (340 kg/m3) and high-water absorption (177%). Cork properties allow consideration of extra water in the mortar mix and improve lightness without significantly affecting compressive, bending strength, and thermal insulation. Cork waste in polyurethanes promotes a color change, slightly increases the density (up to 12.5%), and still results in producing a thermally insulating material (<0.06 W/mK). Considering the promising results, this study demonstrates the feasibility of using the manufacturing waste from cork bottle caps to produce green construction materials, thus upgrading it from waste to secondary raw material.

Background Over time, vaccination has been consolidated as one of the most cost effective and successful public health interventions and a right of every human being. This study aimed to assess the spatial dynamics of the vaccine coverage (VC) rate of children aged < 1 year per municipality in the Brazilian Northeast at 2016 and 2017. Methods This is a mixed-type ecological study that use a Public domain data Health Information. Vaccine doses were obtained from the Information System of the Brazilian National Immunization Program, and live births from the Brazilian Information System of Live Births of the Brazilian Unified Health System. Descriptive analysis of the coverage of all the vaccines for each year of the study was conducted, and Mann–Whitney U test was used to compare VC between the study years. Chi-squared test was used to evaluate the association between the years and VC, which was stratified into four ranges, very low, low, adequate, and high. Spatial distribution was analyzed according to both each study year and vaccine and presented as thematic maps. Spatial autocorrelation was analyzed using Moran’s Global and Local statistics. Results Compared with 2017, 2016 showed better VC ( p  < 0.05), except for Bacillus Calmette–Guérin. In the spatial analysis of the studied vaccines, the Global Moran’s Index did not show any spatial autocorrelation ( p  > 0.05), but the Local Moran’s Index showed some municipalities, particularly the Sertão Paraibano region, with high VC, high similarity, and a positive influence on neighboring municipalities ( p  < 0.05). In contrast, most municipalities with low VC were concentrated in the Mata Paraibano region, negatively influencing their neighbors ( p  < 0.05). Conclusion Uneven geographic regions and clusters of low VC for children aged < 1 year in the State of Paraíba were spatially visualized. Health policy makers and planners need to urgently devise and coordinate an action plan directed at each state’s regions to fulfill the vaccination calendar, thereby reversing the vulnerability of this age group, which is at a higher risk of diseases preventable by vaccination.

This study investigates the feasibility of using volcanic lapillus as a supplementary cementitious material (SCM) in mortar production to improve the sustainability of the cement industry. Cement production is one of the main sources of CO2 emissions, mainly due to clinker production. Replacing clinker with SCMs, such as volcanic lapillus, can reduce the environmental impact while maintaining adequate mechanical properties. Experiments were conducted to replace up to 20 wt% of limestone Portland cement with volcanic lapillus. Workability, compressive strength, microstructure, resistance to alkali-silica reaction (ASR), sulfate, and chloride penetration were analyzed. The results showed that up to 10% replacement had a minimal effect on mechanical properties, while higher percentages resulted in reduced strength but still improved some durability features. The control sample cured 28 days showed a compressive strength of 43.05 MPa compared with 36.89 MPa for the sample containing 10% lapillus. After 90 days the respective values for the above samples were 44.76 MPa and 44.57 MPa. Scanning electron microscopy (SEM) revealed good gel–aggregate adhesion, and thermogravimetric analysis (TGA) confirmed reduced calcium hydroxide content, indicating pozzolanic activity. Overall, volcanic lapillus shows promise as a sustainable SCM, offering CO2 reduction and durability benefits, although higher replacement rates require further optimization.

This study aims to optimize the conditions for “Genovese” basil (Ocimum Basilicum) germination and growth in an indoor environment suitable for horticulture through a synergic effect of light and fertilizers addition. In fact, several studies determined that specific light conditions are capable of enhancing basil growth, but this effect is highly dependent on the environmental conditions. In this study, the effect of different light sources was determined employing a soil with a negligible amount of fertilizer, demonstrating substantial improvement when light-emitting diode (LED) lights (hyper red and deep blue in different combinations) were applied with respect to daylight (Plants height: +30%, Total fresh mass: +50%). Thereafter, a design of experiment approach has been implemented to calculate the specific combination of LED lights and fertilizer useful to optimize the basil growth. A controlled-release fertilizer based on nitrogen, phosphorus, and potassium (NPK) derived from agro-residues was compared with a soil enriched in macronutrients. The results demonstrate significant improvements for the growth parameters with the employment of the controlled-release NPK with respect to enriched soil combined with a ratio of hyper red and deep blue LED light equal to 1:3 (Total fresh mass: +100%, Leaves number: +20%).

This study follows a circular economy approach through the preliminary implementation of a coated porous inorganic material (PIM), studied as sustainable controlled release fertilizer, and its application for lettuce Lactuca sativa L. cultivar Chiara growth. The PIM was made of pumice scraps that partially replaced clay as a natural raw material, spent coffee grounds as a porous agent, bovine bone ash and potassium carbonate to provide phosphorus (P) and potassium (K) nutrients, respectively. A coating made with defatted black soldier fly prepupae biomass was used as a nitrogen (N) source. Most of the ingredients used were industrial residues, with the aim of valorizing the raw waste materials present locally. The suitability of PIMs as a fertilizer was investigated with an interdisciplinary approach, which included the first chemical and physical characterization of the material, the evaluation of its antibacterial properties and of its use in horticulture through lettuce growth tests. As tests were carried out indoors, a specific LED lighting device was used to grow the lettuce. The release of nutrients into the soil was estimated by measuring the main elements in the fertilizers before and after their use in the soil. The first results from this characterization study support PIMs’ suitability for agronomic applications. The use of the PIMs suggested average higher dry weight (49%), fresh weight (112%), and leaf area (48%), compared to those with the use of a standard fertilizer soil, without the release of any dangerous element for the plant in the soil. These results are a promising beginning for the development of further studies already in progress on sustainable controlled-release fertilizers.

The horticulture sector has been directed by European guidelines to improve its practices related to environmental sustainability. Moreover, the practice of horticulture in urban areas is increasing since it provides fresh products that are locally produced. At the same time, horticulture needs to implement circular economy approaches and energy-efficient models. Therefore, to address these issues, this study investigated the effects of an integrated fertilizer-box-based cultivation system equipped with LED lights and coated porous inorganic materials (C-PIMs), which was applied as fertilizer, on Lactuca sativa L. growth. Two different types of lightweight aggregates were formulated considering agri-food and post-consumer waste, and they were enriched with potassium and phosphorus. Involving waste in the process was part of their valorization in the circular economy. Using PIMs as fertilizers enabled the controlled release of nutrients over time. The tests were carried out in controlled conditions using two LED lighting systems capable of changing their light spectrum according to the growth phases of the plants. The effects of two different lighting schemes on the growth of lettuce plants, in combination with different amounts of aggregates, were studied. The results showed that increasing the amount of C-PIMs statistically improved the lettuce growth in terms of dry biomass production (+60% and +34% for two different types of PIM application) when the plants were exposed to the first LED scheme (LED-1). Plant height and leaf areas significantly increased when exposed to the second LED scheme (LED-2), in combination with the presence of C-PIMs in the soil. The analysis of the heavy metal contents in the lettuce leaves and the soil at the end of the test revealed that these elements remained significantly below the legislated thresholds. The experimental achievements of this study identified a new approach to improve the environmental sustainability of horticulture, especially in an urban/domestic context.

This research reports results of eco-compatible building material obtained without natural raw materials. A mixture of sludge from a ceramic wastewater treatment plant and glass cullet from the urban collection was used to obtain high sintered products suitable to be used as covering floor/wall tiles in buildings. The fired samples were tested by water absorption, linear shrinkage, apparent density, and mechanical and chemical properties. Satisfactory results were achieved from densification properties and SEM/XRD analyses showed a compact polycrystalline microstructure with albite and wollastonite embedded in the glassy phase, similar to other commercial glass-ceramics. Besides, the products were obtained with a reduction of 200 °C with respect to the firing temperatures of commercial ones. Additionally, the realized materials were undergone to leaching test following Italian regulation to evaluate the mobility of hazardous ions present into the sludge. The data obtained verified that after thermal treatment the heavy metals were immobilized into the ceramic matrix without further environmental impact for the product use. The results of the research confirm that this valorization of matter using only residues produces glass ceramics high sintered suitable to be used as tile with technological properties similar or higher than commercial ones.