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Laser-induced grating spectroscopy (LIGS) is for the first time explored in a configuration based on the crossing of two focused femtosecond (fs) laser pulses (800-nm wavelength) and a focused continuous-wave (cw) laser beam (532-nm wavelength). A thermal grating was formed by multi-photon absorption of the fs-laser pulses by N 2 with a pulse energy around 700 μ J ( ∼ 45 TW/ cm 2 ). The feasibility of this LIGS configuration was investigated for thermometry in heated nitrogen gas flows. The temperature was varied from room temperature up to 750 K, producing strong single-shot LIGS signals. A model based on the solution of the linearized hydrodynamic equations was used to extract temperature information from single-shot experimental data, and the results show excellent agreement with the thermocouple measurements. Furthermore, the fluorescence produced by the fs-laser pulses was investigated. This study indicates an 8-photon absorption pathway for N 2 in order to reach the B 3 Π g state from the ground state, and 8 + 5 photon excitation to reach the B 2 Σ u + state of the N 2 + ion. At pulse energies higher than 1 mJ, the LIGS signal was disturbed due to the generation of plasma. Additionally, measurements in argon gas and air were performed, where the LIGS signal for argon shows lower intensity compared to air and N 2 .

In this study, Raman spectroscopy has been used to evaluate the evolution of the structural modification of soot during oxidation processes at various preset temperatures up to 700 °C. Two types of well-characterized mini-CAST soot, representing black soot and brown soot, were examined. The major difference between the signals from the two types of soot was the higher photoluminescence (PL) signal for brown soot compared with black soot, in addition to some variations in the first-order Raman signatures such as oxygenated groups and their evolutions during thermal oxidation treatment. An interesting observation was the increase in the PL signal for brown soot at increasing temperatures up to 150 °C probably due to the formation of small oxidized polycyclic aromatic hydrocarbon and defects, followed by a decrease in the PL signal until the soot was fully oxidized. We also demonstrated that brown soot is prone to oxidation in ex situ measurements, a factor that should be considered in the Raman analysis of soot.

High-speed imaging of fuel sprays and combustion is conducted on a light-duty optical engine to investigate the effects of injector aging, with a focus on soot. The spray behaviors of one new and one aged injector are compared using Mie-scattering. In addition to this, the combustion process of a baseline diesel fuel and a blend with TPGME (tripropylene glycol monomethyl ether) are compared using natural luminosity (NL) imaging. TPGME is an oxygenated additive which can be used to reduce soot emissions. X-ray tomography of the two injectors demonstrates that the aging does not lead to significant geometry differences, nor to formation of dense internal nozzle deposits. Both injectors show similar liquid penetration and spreading angle. However, the aged injector shows a prolonged injection and more fuel dribbling after the injection events, leading to a higher injection quantity. The fuel quantity difference shows a larger impact on the NL at low load than the TPGME additive, indicating that the in-cylinder temperature is more important for soot oxidation than oxygen concentration under these conditions. At medium load, the NL is much less sensitive to small temperature variations, while the TPGME is more effective for soot reduction.

The immersion freezing ability of soot particles has in previous studies been reported in the range of low/insignificant to very high. The aims of this study were to: (i) perform detailed physico-chemical characterisation of freshly produced soot particles with very different properties, (ii) investigate the immersion freezing ability of the same particles, and (iii) investigate the potential links between physico-chemical particle properties and ice-activity. A miniCAST soot generator was used to produce eight different soot samples representing a wide range of physico-chemical properties. A continuous flow diffusion chamber was used to study each sample online in immersion mode over the temperature (T) range from −41 to −32 °C, at a supersaturation of about 10% with respect to liquid water. All samples exhibited low to no heterogeneous immersion freezing. The most active sample reached ice-activated fractions (AF) of 10−3 and 10−4 at temperatures of 1.7 and 1.9 K , respectively, above the homogeneous freezing temperature. The samples were characterized online with respect to a wide range of physico-chemical properties including effective particle density, optical properties, particle surface oxidation and soot maturity. We did observe indications of increasing immersion freezing ice-activity with increasing effective particle density and increasing particulate PAH fraction. Hence, those properties, or other properties co-varying with those, could potentially enhance the immersion freezing ice-activity of the studied soot particle types. However, we found no significant correlation between the physico-chemical properties and the observed ice-nucleating ability when the particle ensemble was extended to include previously published results including more ice-active biomass combustion soot particles. We conclude that it does not appear possible in general and in any straightforward way to link observed soot particle physico-chemical properties to the ice-nucleating ability using the online instrumentation included in this study. Furthermore, our observations support that freshly produced soot particles with a wide range of physico-chemical properties have low to insignificant immersion freezing ice-nucleating ability.

Previous studies have shown that injector aging adversely affects the diesel engine spray formation and combustion. It has also been shown that the oxygenated fuel additive tripropylene glycol monomethyl ether (TPGME) can lower soot emissions. In this study, the effects of injector aging and TPGME on the late cycle oxidation of soot were investigated using laser diagnostic techniques in a light-duty optical diesel engine at two load conditions. The engine was equipped with a quartz piston with the same complex piston geometry as a production engine. Planar laser-induced incandescence (LII) was used to obtain semiquantitative in-cylinder two-dimensional (2D) soot volume fraction (fv ) distributions using extinction measurements. The soot oxidation rate was estimated from the decay rate of the in-cylinder soot concentration for differently aged injectors and for cases with and without TPGME in the fuel. The aged injector produced higher soot concentrations than the new injector at both load conditions. The aged injector also showed higher soot oxidation rates than the new injector at the low load condition. TPGME resulted in lower soot concentrations at both load conditions and faster oxidation rates, especially at mid load conditions.

The effects of injection pressure and swirl ratio on the in-cylinder soot oxidation are studied using simultaneous PLIF imaging of OH and LII imaging of soot in an optical diesel engine. Images are acquired after the end of injection in the recirculation zone between two adjacent diesel jets. Scalars are extracted from the images and compared with trends in engine-out soot emissions. The soot emissions decrease monotonically with increasing injection pressure but show a non-linear dependence on swirl ratio. The total amount of OH in the images is negatively correlated with the soot emissions, as is the spatial proximity between the OH and soot regions. This indicates that OH is an important soot oxidizer and that it needs to be located close to the soot to perform this function. The total amount of soot in the images shows no apparent correlation with the soot emissions, indicating that the amount of soot formed is a poor predictor of the emission trends.

Laser-Induced Incandescence (LII) has traditionally been considered a straightforward and reliable optical diagnostic technique for in-cylinder soot measurements. As a result, it is nowadays even possible to buy turn-key LII measurement systems. During recent years, however, attention has been drawn to a number of unresolved challenges with LII. Many of these are relevant mostly for particle sizing using time-resolved LII, but also two dimensional soot volume fraction measurements are affected, especially in regions with high soot concentrations typically found in combustion engines. In this work the focus is on the specific challenges involved in performing high-repetition rate measurements with LII in diesel engines. All the mentioned issues might not be possible to overcome but they should nevertheless be known and their potential impact should be considered. The measurements, which, to the authors’ knowledge, are the first in-cylinder high-speed LII published to date, were made using a Multi-YAG laser system, capable of producing a burst of eight high-power laser pulses during one combustion event. A high-speed framing camera was used as detector in order to match the high repetition rate of the laser. In an initial feasibility study, high-speed LII measurements were made in a laminar ethylene/air flame to test the characteristic features of high-speed LII. Excessive influence of soot sublimation was observed in the LII signals induced by later pulses in the pulse sequence for typical pulse separations of interest in the engine (139 μs). This is a result of that each laser pulse partly sublimates soot particles in the measurement volume, resulting in a lower signal yield. Analysis on the data from the in-cylinder measurements does not show signs of the same behavior. This is believed to be due to high mixing and/or very fast soot formation/oxidation in the measurement volume. This implies that time-resolved LII is a suitable technique to qualitatively follow the evolution of the soot distribution inside a reacting diesel jet.

We show that coherent anti-Stokes Raman lineshapes do not follow known spectral profiles if the time asymmetry of realistic laser pulses is taken into account. Examples are given for nanosecond and picosecond laser pulses commonly employed in frequency-resolved coherent anti-Stokes Raman scattering. More remarkably, the analysis suggests an effect of line narrowing in comparison to the customary approach, based primarily on the Voigt lineshape.

We introduce new lineshapes of coherent anti-Stokes Raman spectra of gases by considering realistic nanosecond laser pulses that deviate from the Gaussian representations of their time and spectral envelopes. The analysis suggests that the contribution to the linewidth caused by the interaction with such laser pulses could be erroneously attributed to the intrinsic Raman width if the customary CARS approach, based primarily on the Voigt lineshape, is assumed.

It is generally accepted that knocking combustion influences the heat transfer in SI engines. However, the effects of heat transfer on the onset of knock is still not clear due to lack of experimental data of the thermal boundary layer close to the combustion chamber wall. This paper presents measurements of the temperature in the thermal boundary layer under knocking and nonknocking conditions. The temperature was measured using dual-broadband rotational Coherent anti-Stokes Raman Spectroscopy (CARS). Simultaneous timeresolved measurements of the cylinder pressure, at three different locations, and the heat flux to the wall were carried out. Optical access to the region near the combustion chamber wall was achieved by using a horseshoe-shaped combustion chamber with windows installed in the rectangular part of the chamber. This arrangement made CARS temperature measurements close to the wall possible and results are presented in the range 0.1-5 mm from the wall. The engine was run with constant fuel flow under near stoichiometric conditions. Knocking and non-knocking conditions were achieved by using different mixtures of -heptane and iso-octane.