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Direct imaging studies have mainly used low-resolution spectroscopy (R ∼ 20–100) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g., carbon-to-oxygen ratio, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC (R ∼ 35,000 in the K band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS, we analyze the KPIC high-resolution spectrum (2.29–2.49 μm) and the archival low-resolution spectrum (1–2.2 μm) of the benchmark brown dwarf HD 4747 B (m = 67.2 ± 1.8 M Jup, a = 10.0 ± 0.2 au, T eff ≈ 1400 K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with those of its host star within 1σ–2σ. The retrieved parameters from the K-band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H2O, and CH4 (volume-mixing ratio of log(CH4) = −4.82 ± 0.23) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory.

The detection of satellites around extrasolar planets, so called exomoons, remains a largely unexplored territory. In this work, we study the potential of detecting these elusive objects from radial velocity monitoring of self-luminous, directly imaged planets. This technique is now possible thanks to the development of dedicated instruments combining the power of high-resolution spectroscopy and high-contrast imaging. First, we demonstrate a sensitivity to satellites with a mass ratio of 1%–4% at separations similar to the Galilean moons from observations of a brown-dwarf companion (HR 7672 B; K mag = 13; 0.″7 separation) with the Keck Planet Imager and Characterizer (R ∼ 35,000 in the K band) at the W. M. Keck Observatory. Current instrumentation is therefore already sensitive to large unresolved satellites that could be forming from gravitational instability akin to binary star formation. Using end-to-end simulations, we then estimate that future instruments such as the Multi-Object Diffraction-limited High-resolution Infrared Spectrograph, planned for the Thirty Meter Telescope, should be sensitive to satellites with mass ratios of ∼10−4. Such small moons would likely form in a circumplanetary disk similar to the Jovian satellites in the solar system. Looking for the Rossiter–McLaughlin effect could also be an interesting pathway to detecting the smallest moons on short orbital periods. Future exomoon discoveries will allow precise mass measurements of the substellar companions that they orbit and provide key insight into the formation of exoplanets. They would also help constrain the population of habitable Earth-sized moons orbiting gas giants in the habitable zone of their stars.

Using Keck Planet Imager and Characterizer high-resolution (R ∼ 35,000) spectroscopy from 2.29 to 2.49 μm, we present uniform atmospheric retrievals for eight young substellar companions with masses of ∼10–30 M Jup, orbital separations spanning ∼50–360 au, and T eff between ∼1500 and 2600 K. We find that all companions have solar C/O ratios and metallicities to within the 1σ–2σ level, with the measurements clustered around solar composition. Stars in the same stellar associations as our systems have near-solar abundances, so these results indicate that this population of companions is consistent with formation via direct gravitational collapse. Alternatively, core accretion outside the CO snowline would be compatible with our measurements, though the high mass ratios of most systems would require rapid core assembly and gas accretion in massive disks. On a population level, our findings can be contrasted with abundance measurements for directly imaged planets with m < 10 M Jup, which show tentative atmospheric metal enrichment compared to their host stars. In addition, the atmospheric compositions of our sample of companions are distinct from those of hot Jupiters, which most likely form via core accretion. For two companions with T eff ∼ 1700–2000 K (κ And b and GSC 6214–210 b), our best-fit models prefer a nongray cloud model with >3σ significance. The cloudy models yield 2σ−3σ lower T eff for these companions, though the C/O and [C/H] still agree between cloudy and clear models at the 1σ level. Finally, we constrain 12CO/13CO for three companions with the highest signal-to-noise ratio data (GQ Lup b, HIP 79098b, and DH Tau b) and report vsini and radial velocities for all companions.

We present Keck Planet Imager and Characterizer (KPIC) high-resolution (R ∼35,000) K-band thermal emission spectroscopy of the ultrahot Jupiter WASP-33b. The use of KPIC’s single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested-sampling pipeline, which fits for orbital parameters, the atmospheric pressure–temperature profile, and the molecular abundances. We strongly detect the thermally inverted dayside and measure mass-mixing ratios for CO ( logCOMMR=−1.1−0.6+0.4 ), H2O ( logH2OMMR=−4.1−0.9+0.7 ), and OH ( logOHMMR=−2.1−1.1+0.5 ), suggesting near-complete dayside photodissociation of H2O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of 0.8−0.2+0.1 , consistent with the accretion of high-metallicity gas near the CO2 snow line and post-disk migration or with accretion between the soot and H2O snow lines. We also find tentative evidence for 12CO/13CO ∼ 50, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2–15 × solar). These observations demonstrate KPIC’s ability to characterize close-in planets and the utility of KPIC’s improved instrumental stability for cross-correlation techniques.

We present high-resolution K-band emission spectra of the quintessential hot Jupiter HD 189733 b from the Keck Planet Imager and Characterizer. Using a Bayesian retrieval framework, we fit the dayside pressure–temperature profile, orbital kinematics, mass-mixing ratios of H2O, CO, CH4, NH3, HCN, and H2S, and the 13CO/12CO ratio. We measure mass fractions of logH2O=−2.0−0.4+0.4 and logCO=−2.2−0.5+0.5 , and place upper limits on the remaining species. Notably, we find logCH4 < −4.5 at 99% confidence, despite its anticipated presence at the equilibrium temperature of HD 189733 b assuming local thermal equilibrium. We make a tentative (∼3σ) detection of 13CO, and the retrieved posteriors suggest a 12C/13C ratio similar to or substantially less than the local interstellar value. The possible 13C enrichment would be consistent with accretion of fractionated material in ices or in the protoplanetary disk midplane. The retrieved abundances correspond to a substantially substellar atmospheric C/O = 0.3 ± 0.1, while the carbon and oxygen abundances are stellar to slightly superstellar, consistent with core-accretion models which predict an inverse correlation between C/O and metallicity. The specific combination of low C/O and high metallicity suggests significant accretion of solid material may have occurred late in the formation process of HD 189733 b.

The formation and evolution pathway for the directly imaged multiplanetary system HR 8799 remains mysterious. Accurate constraints on the chemical composition of the planetary atmosphere(s) are key to solving the mystery. We perform a detailed atmospheric retrieval on HR 8799 c to infer the chemical abundances and abundance ratios using a combination of photometric data along with low- and high-resolution spectroscopic data (R ∼ 20–35,000). We specifically retrieve [C/H], [O/H], and C/O and find them to be 0.55−0.39+0.36 , 0.47−0.32+0.31 , and 0.67−0.15+0.12 at 68% confidence. The superstellar C and O abundances, yet a stellar C/O ratio, reveal a potential formation pathway for HR 8799 c. Planet c, and likely the other gas giant planets in the system, formed early on (likely within ∼1 Myr), followed by further atmospheric enrichment in C and O through the accretion of solids beyond the CO ice line. The enrichment either preceded or took place during the early phase of the inward migration to the current planet locations.

We present the projected rotational velocity and molecular abundances for HD 33632 Ab obtained via Keck Planet Imager and Characterizer (KPIC) high-resolution spectroscopy. HD 33632 Ab is a nearby benchmark brown dwarf companion at a separation of ∼20 au that straddles the L–T transition. Using a forward-modeling framework with on-axis host star spectra, which provides self-consistent substellar atmospheric and retrieval models for HD 33632 Ab, we derive a projected rotational velocity of 53 ± 3 km s−1 and carbon monoxide and water mass fractions of logCO = −2.3 ± 0.3 and logH2O = −2.7 ± 0.2, respectively. The inferred carbon-to-oxygen ratio (C/O = 0.58 ± 0.14), molecular abundances, and metallicity ([C/H] = 0.0 ± 0.2 dex) of HD 33632 Ab are consistent with its host star. Although detectable methane opacities are expected in L–T transition objects, we did not recover methane in our KPIC spectra, partly due to the high v sin i and to disequilibrium chemistry at the pressures to which we are sensitive. We parameterize the spin as the ratio of rotation to the breakup velocity, and compare HD 33632 Ab to a compilation of >200 very low-mass objects (M ≲ 0.1 M ⊙) that have spin measurements in the literature. There appears to be no clear trend for the isolated low-mass field objects versus mass, but a tentative trend is identified for low-mass companions and directly imaged exoplanets, similar to previous findings. A larger sample of close-in gas giant exoplanets and brown dwarfs will critically examine our understanding of their formation and evolution through rotation and chemical abundance measurements.

Young, self-luminous super-Jovian companions discovered by direct imaging provide a challenging test for planet formation and evolution theories. By spectroscopically characterizing the atmospheric compositions of these super-Jupiters, we can constrain their formation histories. Here we present studies of the recently discovered HIP 99770 b, a 16 M Jup high-contrast companion on a 17 au orbit, using the fiber-fed high-resolution spectrograph KPIC ( R ∼ 35,000) on the Keck II telescope. Our K-band observations led to detections of H2O and CO in the atmosphere of HIP 99770 b. We carried out free retrieval analyses using petitRADTRANS to measure its chemical abundances, including the metallicity and C/O ratio, projected rotation velocity ( vsini ), and radial velocity (RV). We found that the companion’s atmosphere has C/O =0.55−0.04+0.06 and [M/H] =0.26−0.23+0.24 (1σ confidence intervals), values consistent with those of the Sun and with a companion formation via gravitational instability or core accretion. The projected rotation velocity vsin(i)<7.8 km s−1 is small relative to other directly imaged companions with similar masses and ages. This may imply a nearly pole-on orientation or effective magnetic braking by a circumplanetary disk. In addition, we added the companion-to-primary relative RV measurement to the orbital fitting and obtained updated constraints on orbital parameters. Detailed characterization of super-Jovian companions within 20 au like HIP 99770 b is critical for understanding the formation histories of this population.

We present atmospheric retrievals from Keck/KPIC Phase II observations of the ultrahot Jupiter (UHJ) KELT-20/MASCARA-2 b. Previous free retrievals of molecular abundances for UHJs have been impacted by significant model biases due to variations in vertical abundance profiles, which we address by including molecular dissociation into our retrieval framework as an additional free parameter. We measure the abundance of CO ( logCOMMR=−2.5−0.5+0.6 ) and obtain a lower limit on the abundance of H2O ( logH2OMMR=−1.5−1.0+0.8 , >−3.0 at 95% confidence) in the atmosphere of KELT-20 b. These abundances yield an atmospheric C/O=0.1−0.1+0.4 (C/O < 0.9 at 95% confidence) and suggest a metallicity approximately solar to 10 × solar. H2O is dissociated at pressures below logPH2O=−1.2−0.7+0.5 bar, roughly consistent with predictions from chemical equilibrium models, and suggesting that the retrieved composition is not a result of assumptions about the vertical mixing profiles. We also constrain the rotational velocity of KELT-20 b to vsini=7.5±0.7 km s−1, suggesting the presence of a jet comparable to the sound speed in the direction of the planet’s rotation, assuming the actual rotation of the planet is tidally locked.

We used the Keck Planet Imager and Characterizer to obtain high-resolution (R ∼ 35,000) K-band spectra of κ Andromedae b, a planetary-mass companion orbiting the B9V star, κ Andromedae A. We characterized its spin, radial velocity, and bulk atmospheric parameters through use of a forward-modeling framework to jointly fit planetary spectra and residual starlight speckles, obtaining likelihood-based posterior probabilities. We also detected H2O and CO in its atmosphere via cross correlation. We measured a vsin(i) value for κ Andromedae b of 38.42 ± 0.05 km s−1, allowing us to extend our understanding of the population of close-in bound companions at higher rotation rates. This rotation rate is one of the highest spins relative to breakup velocity measured to date, at close to 50% of breakup velocity. We identify a radial velocity −17.35−0.09+0.05 km s−1, which we use with existing astrometry and radial velocity measurements to update the orbital fit. We also measure an effective temperature of 1700 ± 100 K and a log(g) of 4.7 ± 0.5 cgs dex.