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Prepregs of a mixture of the tetrafunctional epoxy tetraglycidyl 4,4‐diaminodiphenyl methane (TGDDM) and the tetrafunctional amine 4,4'‐diaminodiphenylsulfone (DDS) were characterized with temperature‐modulated DSC (TMDSC) as well as dynamic mechanical analysis (DMA). The baseline shift of the glass transition was separated from the curing exotherm by using temperature‐modulated and step scan DSC temperature scans. Likewise, the baseline shift in heat capacity due to vitrification was isolated using TMDSC isotherms. Using the TMDSC glass transition temperature, degree of conversion, and vitrification results, combined with the gelation data generated from DMA, a time‐temperature‐transformation (TTT) diagram was constructed, providing information necessary for optimization of industrial processing of the epoxy prepreg. Thus, effects of storage, preprocessing, and postprocessing on the overall curing process are taken into account.

We present the Black Hole Explorer (BHEX), a mission that will produce the sharpest images in the history of astronomy by extending submillimeter Very-Long-Baseline Interferometry (VLBI) to space. BHEX will discover and measure the bright and narrow \"photon ring\" that is predicted to exist in images of black holes, produced from light that has orbited the black hole before escaping. This discovery will expose universal features of a black hole's spacetime that are distinct from the complex astrophysics of the emitting plasma, allowing the first direct measurements of a supermassive black hole's spin. In addition to studying the properties of the nearby supermassive black holes M87* and Sgr A*, BHEX will measure the properties of dozens of additional supermassive black holes, providing crucial insights into the processes that drive their creation and growth. BHEX will also connect these supermassive black holes to their relativistic jets, elucidating the power source for the brightest and most efficient engines in the universe. BHEX will address fundamental open questions in the physics and astrophysics of black holes that cannot be answered without submillimeter space VLBI. The mission is enabled by recent technological breakthroughs, including the development of ultra-high-speed downlink using laser communications, and it leverages billions of dollars of existing ground infrastructure. We present the motivation for BHEX, its science goals and associated requirements, and the pathway to launch within the next decade.

Kinetic equation parameters for the curing reaction of a commercial glass fiber reinforced high performance epoxy prepreg composed of the tetrafunctional epoxy tetraglycidyl 4,4-diaminodiphenyl methane (TGDDM), the tetrafunctional amine curing agent 4,4′-diaminodiphenylsulfone (DDS) and an ionic initiator/accelerator, are determined by various thermal analysis techniques and the results compared. The reaction is monitored by heat generated determined by differential scanning calorimetry (DSC) and by high speed DSC when the reaction rate is high. The changes in physical properties indicating increasing conversion are followed by shifts in glass transition temperature determined by DSC, temperature-modulated DSC (TMDSC), step scan DSC and high speed DSC, thermomechanical (TMA) and dynamic mechanical (DMA) analysis and thermally stimulated depolarization (TSD). Changes in viscosity, also indicative of degree of conversion, are monitored by DMA. Thermal stability as a function of degree of cure is monitored by thermogravimetric analysis (TGA). The parameters of the general kinetic equations, including activation energy and rate constant, are explained and used to compare results of various techniques. The utilities of the kinetic descriptions are demonstrated in the construction of a useful time-temperature-transformation (TTT) diagram and a continuous heating transformation (CHT) diagram for rapid determination of processing parameters in the processing of prepregs. Shrinkage due to both resin consolidation and fiber rearrangement is measured as the linear expansion of the piston on a quartz dilatometry cell using TMA. The shrinkage of prepregs was determined to depend on the curing temperature, pressure applied and the fiber orientation. Chemical modification of an epoxy was done by mixing a fluorinated aromatic amine (aniline) with a standard aliphatic amine as a curing agent for a commercial Diglycidylether of Bisphenol-A (DGEBA) epoxy. The resulting cured network was tested for wear resistance using tribological techniques. Of the six anilines, 3-fluoroaniline and 4-fluoroaniline were determined to have lower wear than the unmodified epoxy, while the others showed much higher wear rates.

The Black Hole Explorer (BHEX) is a mission concept that can dramatically improve state-of-the-art astronomical very long baseline interferometry (VLBI) imaging resolution by extending baseline distances to space. To support these scientific goals, a high data rate downlink is required from space to ground. Laser communications is a promising option for realizing these high data rate, long-distance space-to-ground downlinks with smaller space/ground apertures. Here, we present a scalable laser communications downlink design and current lasercom mission results.

This paper describes specification and early design of back end signal processing subsystems for the Black Hole Explorer (BHEX) Very Long Baseline Interferometry (VLBI) space telescope. The \"back end\" consists of two subsystems. First, the block downconverter (BDC) is a heterodyne system that performs a frequency translation of the analog signal from IF to baseband and amplifies and filters it for digitization. Second, the digital back end (DBE) samples the analog signal with an analog-to-digital converters (ADC) and digitally processes the data stream formatting them to the VLBI \"VDIF\" standard and converting to Ethernet packets for 100 gigabit-per-second (Gb/s) Ethernet transport to the optical downlink system. Both the BDC and the DBE for BHEX support eight channels of 4.096 GHz bandwidth each, for a total processed bandwidth of 32.768 GHz. The BHEX back end benefits from mature terrestrial back end heritage, described in some detail. The BHEX back end itself is in the early stages of design, with requirements, interface specifications, and component trade studies well advanced. The aim is to build a prototype using terrestrial grade parts which are available in functionally identical space grade equivalents, and to use this prototype to advance the back end Technology Readiness Level (TRL) preparing for a Small Explorer (SMEX) proposal in 2025.

The Black Hole Explorer (BHEX) is a space very-long-baseline interferometry (VLBI) mission concept that is currently under development. BHEX will study supermassive black holes at unprecedented resolution, isolating the signature of the \"photon ring\" - light that has orbited the black hole before escaping - to probe physics at the edge of the observable universe. It will also measure black hole spins, study the energy extraction and acceleration mechanisms for black hole jets, and characterize the black hole mass distribution. BHEX achieves high angular resolution by joining with ground-based millimeter-wavelength VLBI arrays, extending the size, and therefore improving the angular resolution of the earthbound telescopes. Here we discuss the science instrument concept for BHEX. The science instrument for BHEX is a dual-band, coherent receiver system for 80-320 GHz, coupled to a 3.5-meter antenna. BHEX receiver front end will observe simultaneously with dual polarizations in two bands, one sampling 80-106 GHz and one sampling 240-320 GHz. An ultra-stable quartz oscillator provides the master frequency reference and ensures coherence for tens of seconds. To achieve the required sensitivity, the front end will instantaneously receive 32 GHz of frequency bandwidth, which will be digitized to 64 Gbits/sec of incompressible raw data. These data will be buffered and transmitted to the ground via laser data link, for correlation with data recorded simultaneously at radio telescopes on the ground. We describe the challenges associated with the instrument concept and the solutions that have been incorporated into the baseline design.

Kinetic equation parameters for the curing reaction of a commercial glass fiber reinforced high performance epoxy prepreg composed of the tetrafunctional epoxy tetraglycidyl 4,4-diaminodiphenyl methane (TGDDM), the tetrafunctional amine curing agent 4,4′diaminodiphenylsulfone (DDS) and an ionic initiator/accelerator, are determined by various thermal analysis techniques and the results compared. The reaction is monitored by heat generated determined by differential scanning calorimetry (DSC). The changes in physical properties indicating increasing conversion are followed by shifts in glass transition temperature determined by DSC and temperature-modulated DSC (TMDSC), thermomechanical (TMA) and dynamic mechanical (DMA) analysis and thermally stimulated depolarization (TSD). Changes in viscosity, also indicative of degree of conversion, are monitored by DMA. Thermal stability as a function of degree of cure is monitored by thermogravimetric analysis (TGA). The parameters of the general kinetic equations, including activation energy and rate constant, are explained and used to compare results of various techniques. The utilities of the kinetic descriptions are demonstrated in the construction of a useful time-temperature-transformation (TTT) diagram for rapid determination of processing parameters in the processing of prepregs.