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Observations of transiting gas giant exoplanets have revealed a pervasive depletion of methane 1 – 4 , which has only recently been identified atmospherically 5 , 6 . The depletion is thought to be maintained by disequilibrium processes such as photochemistry or mixing from a hotter interior 7 – 9 . However, the interiors are largely unconstrained along with the vertical mixing strength and only upper limits on the CH 4 depletion have been available. The warm Neptune WASP-107b stands out among exoplanets with an unusually low density, reported low core mass 10 , and temperatures amenable to CH 4 , though previous observations have yet to find the molecule 2 , 4 . Here we present a JWST-NIRSpec transmission spectrum of WASP-107b that shows features from both SO 2 and CH 4 along with H 2 O, CO 2 , and CO. We detect methane with 4.2 σ significance at an abundance of 1.0 ± 0.5 ppm, which is depleted by 3 orders of magnitude relative to equilibrium expectations. Our results are highly constraining for the atmosphere and interior, which indicate the envelope has a super-solar metallicity of 43 ± 8 × solar, a hot interior with an intrinsic temperature of T int  = 460 ± 40 K, and vigorous vertical mixing which depletes CH 4 with a diffusion coefficient of K zz  = 10 11.6±0.1  cm 2  s −1 . Photochemistry has a negligible effect on the CH 4 abundance but is needed to account for the SO 2 . We infer a core mass of 11.5 − 3.6 + 3.0 M ⊕ , which is much higher than previous upper limits 10 , releasing a tension with core-accretion models 11 . Observations of the warm Neptune WASP-107b show that the planet has a hot interior with an intrinsic temperature of about 460 K.

Detecting atmospheres around planets with a radius below 1.6 R ⊕, commonly referred to as rocky planets, has proven to be challenging. However, rocky planets orbiting M dwarfs are ideal candidates due to their favorable planet-to-star radius ratio. Here, we present one transit observation of the Super-Earth L98-59 d (1.58 R ⊕ and 2.31 M ⊕), at the limit of rocky/gas-rich, using the JWST NIRSpec G395H mode covering the 2.8–5.1 μm wavelength range. The extracted transit spectrum from a single transit observation deviates from a flat line by 2.6σ–5.6σ, depending on the data reduction and retrieval setup. The hints of an atmospheric detection are driven by a large absorption feature between 3.3 and 4.8 μm. A stellar contamination retrieval analysis rejected the source of this feature as being due to stellar inhomogeneities, making the best fit an atmospheric model including sulfur-bearing species, suggesting that the atmosphere of L98-59 d may not be at equilibrium. This result will need to be confirmed by the analysis of the second NIRSpec G395H visit in addition to the NIRISS SOSS transit observation.

L 98-59 d is a Super-Earth planet orbiting an M-type star. We performed retrievals on the transmission spectrum of L 98-59 d obtained using NIRSpec G395H during a single transit, from JWST Cycle 1 GTO 1224. The wavelength range of this spectrum allows us to detect the presence of several atmospheric species. We found that the spectrum is consistent with a high mean molecular weight atmosphere. The atmospheric spectrum indicates the possible presence of the sulfur-bearing species H2S and SO2, which could hint at active volcanism on this planet if verified by future observations. We also tested for signs of stellar contamination in the spectrum and found signs of unocculted faculae on the star. The tentative signs of an atmosphere on L 98-59 d presented in this work from just one transit bodes well for possible molecular detections in the future, particularly as it is one of the best targets among small exoplanets for atmospheric characterization using JWST.

We report on James Webb Space Telescope (JWST) commissioning observations of the transiting exoplanet HAT-P-14 b, obtained using the Bright Object Time Series (BOTS) mode of the NIRSpec instrument with the G395H/F290LP grating/filter combination (3–5 μ m). While the data were used primarily to verify that the NIRSpec BOTS mode is working as expected, and to enable it for general scientific use, they yield a precise transmission spectrum which we find is featureless down to the precision level of the instrument, consistent with expectations given HAT-P-14 b’s small scale-height and hence expected atmospheric features. The exquisite quality and stability of the JWST/NIRSpec transit spectrum—almost devoid of any systematic effects—allowed us to obtain median uncertainties of 50–60 ppm in this wavelength range at a resolution of R = 100 in a single exposure, which is in excellent agreement with pre-flight expectations and close to the (or at the) photon-noise limit for a J = 9.094, F-type star like HAT-P-14. These observations showcase the ability of NIRSpec/BOTS to perform cutting-edge transiting exoplanet atmospheric science, setting the stage for observations and discoveries to be made in Cycle 1 and beyond.

We present two-dimensional near-infrared temperature maps of the canonical hot Jupiter WASP-43b using a phase-curve observation with JWST NIRSpec/G395H. From the white-light planetary transit, we improve constraints on the planet’s orbital parameters and measure a planet-to-star radius ratio of 0.15883−0.00053+0.00056 . Using the white-light phase curve, we measure a longitude of maximum brightness of 6.9−0.°5+0.°5 east of the substellar point and a phase-curve offset of 10.0−0.°8+0.°8 . We also find a ≈4σ detection of a latitudinal hotspot offset of −13.4−1.°7+3.°2 , the first significant detection of a nonequatorial hotspot in an exoplanet atmosphere. We show that this detection is robust to variations within planetary parameter uncertainties, but only if the transit is used to improve constraints, showing the importance of transit observations to eclipse mapping. Maps retrieved from the NRS1 and NRS2 detectors are similar, with hotspot locations consistent between the two detectors at the 1σ level. Our JWST data show brighter (hotter) nightsides and a dimmer (colder) dayside at the shorter wavelengths relative to fits to Spitzer 3.6 and 4.5 μm phase curves. Through comparison between our phase curves and a set of general circulation models, we find evidence for clouds on the nightside and atmospheric drag or high metallicity reducing the eastward hotspot offset.

Cassiopeia A is the youngest supernova remnant known in the Milky Way and a unique laboratory for supernova physics. We present an optical spectrum of the Cassiopeia A supernova near maximum brightness, obtained from observations of a scattered light echo more than three centuries after the direct light of the explosion swept past Earth. The spectrum shows that Cassiopeia A was a type IIb supernova and originated from the collapse of the helium core of a red supergiant that had lost most of its hydrogen envelope before exploding. Our finding concludes a long-standing debate on the Cassiopeia A progenitor and provides new insight into supernova physics by linking the properties of the explosion to the wealth of knowledge about its remnant.

Two images of Cassiopeia A obtained at 24 micrometers with the Spitzer Space Telescope over a 1-year time interval show moving structures outside the shell of the supernova remnant to a distance of more than 20 arc minutes. Individual features exhibit apparent motions of 10 to 20 arc seconds per year, independently confirmed by near-infrared observations. The observed tangential velocities are at roughly the speed of light. It is likely that the moving structures are infrared echoes, in which interstellar dust is heated by the explosion and by flares from the compact object near the center of the remnant.

A large amount (about three solar masses) of cold (18 K) dust in the prototypical type II supernova remnant Cassiopeia A was recently reported 1 . It was concluded that dust production in type II supernovae can explain how the large quantities (∼ 10 8 solar masses) of dust observed 2 in the most distant quasars could have been produced within only 700 million years after the Big Bang. Foreground clouds of interstellar material, however, complicate the interpretation of the earlier submillimetre observations of Cas A. Here we report far-infrared and molecular line observations that demonstrate that most of the detected submillimetre emission originates from interstellar dust in a molecular cloud complex located in the line of sight between the Earth and Cas A, and is therefore not associated with the remnant. The argument that type II supernovae produce copious amounts of dust is not supported by the case of Cas A, which previously appeared to provide the best evidence for this possibility.

Carbon dioxide (CO 2 ) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO 2 is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’) 1 – 3 , and thus the formation processes of the primary atmospheres of hot gas giants 4 – 6 . It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets 7 – 9 . Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO 2 , but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification 10 – 12 . Here we present the detection of CO 2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme 13 , 14 . The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO 2 absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO 2 , but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models. Transmission spectroscopy observations from the James Webb Space Telescope show the detection of carbon dioxide in the atmosphere of the gas giant exoplanet WASP-39b.

The James Webb Space Telescope (JWST) will likely revolutionize transiting exoplanet atmospheric science, due to a combination of its capability for continuous, long duration observations and its larger collecting area, spectral coverage, and spectral resolution compared to existing space-based facilities. However, it is unclear precisely how well JWST will perform and which of its myriad instruments and observing modes will be best suited for transiting exoplanet studies. In this article, we describe a prefatory JWST Early Release Science (ERS) Cycle 1 program that focuses on testing specific observing modes to quickly give the community the data and experience it needs to plan more efficient and successful transiting exoplanet characterization programs in later cycles. We propose a multi-pronged approach wherein one aspect of the program focuses on observing transits of a single target with all of the recommended observing modes to identify and understand potential systematics, compare transmission spectra at overlapping and neighboring wavelength regions, confirm throughputs, and determine overall performances. In our search for transiting exoplanets that are well suited to achieving these goals, we identify 12 objects (dubbed \"community targets\") that meet our defined criteria. Currently, the most favorable target is WASP-62b because of its large predicted signal size, relatively bright host star, and location in JWST's continuous viewing zone. Since most of the community targets do not have well-characterized atmospheres, we recommend initiating preparatory observing programs to determine the presence of obscuring clouds/hazes within their atmospheres. Measurable spectroscopic features are needed to establish the optimal resolution and wavelength regions for exoplanet characterization. Other initiatives from our proposed ERS program include testing the instrument brightness limits and performing phase-curve observations. The latter are a unique challenge compared to transit observations because of their significantly longer durations. Using only a single mode, we propose to observe a full-orbit phase curve of one of the previously characterized, short-orbital-period planets to evaluate the facility-level aspects of long, uninterrupted time-series observations.