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This chapter reviews the estimates of the dust-to-gas and refractory-to-ice mass ratios derived from Rosetta measurements in the lost materials and the nucleus of 67P/Churyumov-Gerasimenko, respectively. First, the measurements by Rosetta instruments are described, as well as relevant characteristics of 67P. The complex picture of the activity of 67P, with its extreme North-South seasonal asymmetry, is presented. Individual estimates of the dust-to-gas and refractory-to-ice mass ratios are then presented and compared, showing wide ranges of plausible values. Rosetta ’s wealth of information suggests that estimates of the dust-to-gas mass ratio made in cometary comae at a single point in time may not be fully representative of the refractory-to-ice mass ratio within the cometary nuclei being observed.

A drop in the ocean Earth's bulk composition is similar to that of a group of oxygen-poor meteorites called enstatite chondrites, thought to have formed in the early solar nebula. This leads to the suggestion that proto-Earth was dry, and that volatiles including water were delivered by asteroid and comet impacts. The deuterium-to-hydrogen (D/H) ratios measured in six Oort cloud comets are much higher than on Earth, however, apparently ruling out a dominant role for such bodies. Now the Herschel Space Telescope has been used to determine the D/H ratio in the Kuiper belt comet 103P/Hartley 2. The ratio is Earth-like, suggesting that this population of comets may have contributed to Earth's ocean waters. For decades, the source of Earth's volatiles, especially water with a deuterium-to-hydrogen ratio (D/H) of (1.558 ± 0.001) × 10 −4 , has been a subject of debate. The similarity of Earth’s bulk composition to that of meteorites known as enstatite chondrites 1 suggests a dry proto-Earth 2 with subsequent delivery of volatiles 3 by local accretion 4 or impacts of asteroids or comets 5 , 6 . Previous measurements in six comets from the Oort cloud yielded a mean D/H ratio of (2.96 ± 0.25) × 10 −4 . The D/H value in carbonaceous chondrites, (1.4 ± 0.1) × 10 −4 , together with dynamical simulations, led to models in which asteroids were the main source of Earth's water 7 , with ≤10 per cent being delivered by comets. Here we report that the D/H ratio in the Jupiter-family comet 103P/Hartley 2, which originated in the Kuiper belt, is (1.61 ± 0.24) × 10 −4 . This result substantially expands the reservoir of Earth ocean-like water to include some comets, and is consistent with the emerging picture of a complex dynamical evolution of the early Solar System 8 , 9 .

A fundamental question in cometary science is whether the different dynamical classes of comets have different chemical compositions, which would reflect different initial conditions. From the ground or Earth orbit, radio and infrared spectroscopic observations of a now significant sample of comets indeed reveal deep differences in the relative abundances of cometary ices. However, no obvious correlation with dynamical classes is found. Further results come, or are expected, from space exploration. Such investigations, by nature limited to a small number of objects, are unfortunately focussed on short-period comets (mainly Jupiter-family). But these in situ studies provide “ground truth” for remote sensing. We discuss the chemical differences in comets from our database of spectroscopic radio observations, which has been recently enriched by several Jupiter-family and Halley-type comets.

Deuterated water (HDO) was detected in comet C/1995 O1 (Hale-Bopp) with the use of the James Clerk Maxwell Telescope on Mauna Kea, Hawaii. The inferred D/H ratio in Hale-Bopp's water is (3.3 +/- 0.8) x 10(-4). This result is consistent with in situ measurements of comet P/Halley and the value found in C/1996 B2 (Hyakutake). This D/H ratio, higher than that in terrestrial water and more than 10 times the value for protosolar H2, implies that comets cannot be the only source for the oceans on Earth.

Heat transport and ice sublimation in comets are interrelated processes reflecting properties acquired at the time of formation and during subsequent evolution. The Microwave Instrument on the Rosetta Orbiter (MIRO) acquired maps of the subsurface temperature of comet 67P/Churyumov-Gerasimenko, at 1.6 mm and 0.5 mm wavelengths, and spectra of water vapor. The total H 2 O production rate varied from 0.3 kg s –1 in early June 2014 to 1.2 kg s –1 in late August and showed periodic variations related to nucleus rotation and shape. Water outgassing was localized to the “neck” region of the comet. Subsurface temperatures showed seasonal and diurnal variations, which indicated that the submillimeter radiation originated at depths comparable to the diurnal thermal skin depth. A low thermal inertia (~10 to 50 J K –1 m –2 s –0.5 ), consistent with a thermally insulating powdered surface, is inferred.

This paper is the result of the International Cometary Workshop, held in Toulouse, France in April 2014, where the participants came together to assess our knowledge of comets prior to the ESA Rosetta Mission. In this paper, we look at the composition of the gas and dust from the comae of comets. With the gas, we cover the various taxonomic studies that have broken comets into groups and compare what is seen at all wavelengths. We also discuss what has been learned from mass spectrometers during flybys. A few caveats for our interpretation are discussed. With dust, much of our information comes from flybys. They include in situ analyses as well as samples returned to Earth for laboratory measurements. Remote sensing IR observations and polarimetry are also discussed. For both gas and dust, we discuss what instruments the Rosetta spacecraft and Philae lander will bring to bear to improve our understanding of comet 67P/Churyumov-Gerasimenko as “ground-truth” for our previous comprehensive studies. Finally, we summarize some of the initial Rosetta Mission findings.

We present a comparative study on molecular abundances in comets basedon millimetre/submillimetre observations made with the IRAM 30-m,JCMT, CSO and SEST telescopes. This study concerns a sample of 24comets (6 Jupiter-family, 3 Halley-family, 15 long-period) observedfrom 1986 to 2001 and 8 molecular species (HCN, HNC, CH3CN,CH3OH, H2CO, CO, CS, H2S). HCN was detected in all comets,while at least 2 molecules were detected in 19 comets.From the sub-sample of comets for which contemporary H2O productionrates are available, we infer that the HCN abundance relative to water variesfrom 0.08% to 0.25%. With respect to other species, HCN is the moleculewhich exhibits the lowest abundance variation from comet to comet. Therefore,production rates relative to that of HCN can be used for a comparative study ofmolecular abundances in the 19 comets. It is found that: CH3OH/HCN varies from ≤ 9 to 64; CO/HCN varies from ≤ 24 to 180; H2CO/HCN varies between 1.6 and 10; and H2S/HCN varies between 1.5 and 7.6.This study does not show any clear correlation between the relative abundancesand the dynamical origins of the comets, or their dust-to-gas ratios.

Deuterated hydrogen cyanide (DCN) was detected in a comet, C/1995 O1 (Hale-Bopp), with the use of the James Clerk Maxwell Telescope on Mauna Kea, Hawaii. The inferred deuterium/hydrogen (D/H) ratio in hydrogen cyanide (HCN) is (D/H)$_{HCN}$ = (2.3 ± 0.4) × 10$^{-3}$. This ratio is higher than the D/H ratio found in cometary water and supports the interstellar origin of cometary ices. The observed values of D/H in water and HCN imply a kinetic temperature ≥30 ± 10 K in the fragment of interstellar cloud that formed the solar system.

On 12 November 2014, the Philae lander descended towards comet 67P/Churyumov–Gerasimenko, bounced twice off the surface, then arrived under an overhanging cliff in the Abydos region. The landing process provided insights into the properties of a cometary nucleus 1 – 3 . Here we report an investigation of the previously undiscovered site of the second touchdown, where Philae spent almost two minutes of its cross-comet journey, producing four distinct surface contacts on two adjoining cometary boulders. It exposed primitive water ice—that is, water ice from the time of the comet’s formation 4.5 billion years ago—in their interiors while travelling through a crevice between the boulders. Our multi-instrument observations made 19 months later found that this water ice, mixed with ubiquitous dark organic-rich material, has a local dust/ice mass ratio of 2.3 − 0.16 + 0.2 : 1 , matching values previously observed in freshly exposed water ice from outbursts 4 and water ice in shadow 5 , 6 . At the end of the crevice, Philae made a 0.25-metre-deep impression in the boulder ice, providing in situ measurements confirming that primitive ice has a very low compressive strength (less than 12 pascals, softer than freshly fallen light snow) and allowing a key estimation to be made of the porosity (75 ± 7 per cent) of the boulders’ icy interiors. Our results provide constraints for cometary landers seeking access to a volatile-rich ice sample. When the Philae lander bounced on the surface of comet 67P/Churyumov–Gerasimenko, it exposed primitive icy-dust material within cometary boulders; the intrinsic strength and porosity of this material is reported.

The overarching theme of the Orbiting Astronomical Satellite for Investigating Stellar Systems (OASIS) , an Astrophysics MIDEX-class mission concept, is Following water from galaxies, through protostellar systems, to Earth’s oceans . The OASIS science objectives address fundamental questions raised in “Pathways to Discovery in Astronomy and Astrophysics for the 2020s (National Academies of Sciences and Medicine, Pathways to Discovery in Astronomy and Astrophysics for the 2020s, 2021 , https://doi.org/10.17226/26141 , https://www.nap.edu/catalog/26141/pathways-to-discovery-in-astronomy-and-astrophysics-for-the-2020s )” and in “Enduring Quests and Daring Visions” (Kouveliotou et al. in Enduring quests-daring visions (NASA astrophysics in the next three decades), 2014 , arXiv:1401.3741 ), in the areas of: 1) the Interstellar Medium and Planet Formation, 2) Exoplanets, Astrobiology, and the Solar System, and 3) Galaxies. The OASIS science objectives require space-borne observations of galaxies, molecular clouds, protoplanetary disks, and solar system objects utilizing a telescope with a collecting area that is only achievable by large apertures coupled with cryogenic heterodyne receivers. OASIS will deploy an innovative 14-meter inflatable reflector that enables >16× the sensitivity and >4× the angular resolution of Herschel , and complements the short wavelength capabilities of James Webb Space Telescope . The OASIS state-of-the-art cryogenic heterodyne receivers will enable high spectral resolution (resolving power > 10 6 ) observations at terahertz (THz) frequencies. These frequencies encompass far-IR transitions of water and its isotopologues, HD, and other molecular species, from 660 to 63 μm that are otherwise obscured by Earth’s atmosphere. From observations of the ground state HD line, OASIS will directly measure gas mass in a wide variety of astrophysical objects. Over its one-year baseline mission, OASIS will find water sources as close as the Moon, to galaxies ∼4 billion light years away. This paper reviews the solar system science achievable and planned with OASIS .