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The current infrastructure is crucial to metropolitan improvement. Natural factors, aging, and overuse cause these structures to deteriorate, introducing dangers to public well-being. Timely detection of infrastructure failures requires an effective solution. A YOLOv11-based deep learning model has been proposed which analyzes infrastructure and detects faults in civil architecture. The focus of this study is on an image-based approach to infrastructure assessment, which is an alternative to manual visual inspections. Despite not explicitly modeling infrastructure deterioration, the proposed method is designed to automate defect identification based on visual cues. A customized dataset was created with 9116 images collected from various platforms. The dataset was pre-processed, i.e., annotated, and after pre-processing, the proposed model was trained. After training, our proposed model finds defects with greater precision and speed than conventional defect detection techniques. It achieves high performance with precision, recall, F1 score, and mAP in 100 epochs, and is therefore reliable for applications in civil engineering and urban infrastructure monitoring. Finally, the detection results show that the proposed YOLOv11 model works better than other baseline algorithms (YOLOv8, YOLOv9, and YOLOv10) and is more accurate at finding infrastructure problems in real-world scenarios.

We present a 1 H NMR investigation of spin dynamics in two finite integer spin molecular nanomagnetic rings, namely V 7 Zn and V 7 Ni. This study could be put in correlation with the problem of Haldane gap in infinite integer spin chains. While V 7 Zn is an approximation of a homometallic broken chain due to the presence of s  = 0 Zn 2+ ion uncoupled from nearest neighbor V 2+ s  = 1 ions, the V 7 Ni compound constitutes an example of a closed periodical s  = 1 heterometallic chain. From preliminary susceptibility measurements on single crystals and data analysis, the exchange coupling constant J / k B results in the order of few kelvin. At room temperature, the frequency behavior of the 1 H NMR spin–lattice relaxation rate 1/ T 1 allowed to conclude that the spin–spin correlation function is similar to the one observed in semi-integer spin molecules, but with a smaller cutoff frequency. Thus, the high-T data can be interpreted in terms of, e.g., a Heisenberg model including spin diffusion. On the other hand, the behavior of 1/ T 1 vs temperature at different constant fields reveals a clear peak at temperature of the order of J / k B , qualitatively in agreement with the well-known Bloembergen–Purcell–Pound model and with previous results on semi-integer molecular spin systems. Consequently, one can suggest that for a small number N of interacting s  = 1 ions ( N  = 8), the Haldane conjecture does not play a key role on spin dynamics, and the investigated rings still keep the quantum nature imposed mainly by the low number of magnetic centers, with no clear topological effect due to integer spins.

This prospective, multicentre study was conducted between September and October 2003 in 38 French departments of internal medicine, infectious disease and hepatogastroenterology and included 406 consecutive HBV-infected patients (positive HBsAg), half of whom were HIV-infected (53%). The aim was to outline the main characteristics of hepatitis B virus (HBV)-human immunodeficiency virus (HIV) co-infected patients in French hospitals. HBV-HIV co-infected patients (85% were receiving HAART; mean CD4 count 447±245/μl, HIV RNA load <400 copies/ml, 67% of patients), compared to HIV-negative patients, were more often male, injecting drug users, HBeAg-positive and HCV-HIV co-infected (P<10−4). They underwent liver biopsy less often (31% vs. 51%, P<10−4), particularly those with severe immunodeficiency. They received anti-HBV treatment more often (75% vs. 45·7%, P<10−4), mainly lamivudine and tenofovir. Significant improvements in the management of such patients are awaited mainly in the appraisal of liver disease by either liver biopsy or non-invasive alternatives to liver biopsy.

Among protease inhibitors, atazanavir has not been associated with urolithiasis in clinical studies. We describe 11 cases of atazanavir-associated urolithiasis in patients with human immunodeficiency virus (HIV) infection. Patients with low water intake, high urinary pH, and a prior history of urinary stones may have a higher risk of atazanavir-associated urine crystallization.

Fourteen human immunodeficiency virus (HIV)-infected patients receiving an atazanavir (ATV)-based antiretroviral regimen developed complicated cholelithiasis. ATV was found in biliary calculi in 8 of 11 cases: infrared spectrometry analysis of calculi revealed that ATV made up a median of 89% (range, 10%-100%) of the total calculus composition. Development and management of ATV-associated cholelithiasis are discussed.

Nuclear quadrupole resonance (NQR)139La and63Cu spin-lattice relaxation rateT1t-1 measurements in a La1.94Sr0.06CuO4 single crystal are described. Slowing-down of Cu2+ spin fluctuations is evidenced through a dramatic increase of139T1−1 on cooling. While the onset of diamagnetism occurs atTc = 8 K,139T1−1 has a peak atTg ≅ 5 K, when the characteristic frequency of magnetic fluctuations reaches the NQR frequencyvQ ≅ 9 MHz. In agreement with a number of previous studies, these results show that the so-called “cluster spin-glass” phase persists in the superconducting regime. Issues concerning the coexistence of the two phases are discussed.

Background Unlike their younger counterparts, some of today’s older HIV patients were diagnosed before the advent of highly active antiretroviral therapy (HAART). The psychosocial and behavioral outcomes of people living with HIV (PLWH) have been widely studied, and associated factors are well known. However, their evolution both in terms of age and diagnosis-specific cohort effects is not well understood. Methods Data from the ANRS-VESPA2 cross-sectional survey, representative of French PLWH, were used to investigate whether psychosocial and behavioral outcomes such as quality of life, need for support and HIV status disclosure, evolve under both the influence of patients’ age and diagnosis-specific cohort effects. A semi-parametric generalized additive model (GAM) was employed. The physical and mental components of health-related quality of life, the need for material and moral support, and HIV-status disclosure, constituted our outcomes. Results Non-linear diagnosis-specific cohort effects were found for physical and mental QoL and HIV-status disclosure. Overall, physical QoL was better in recently diagnosed patients than in those diagnosed in the early 1980s. An increasing influence of diagnosis-specific cohort effects between 1983 and 1995 was observed. No cohort effects were noticeable between 1996 and 2000, while an increasing influence was apparent for patients diagnosed with HIV from 2000 to 2011 (year of study). For mental QoL, the only increase was observed in participants diagnosed with HIV between 1983 and 2000. The relationship between diagnosis-specific cohort effects and HIV status disclosure was negative overall: participants diagnosed after 2000 were much less likely to disclose than those diagnosed before 1995. The effect of age was significantly associated with all outcomes, with a non-linear influence on mental QoL and with the need for material/moral support. Conclusions Psychosocial and behavioral outcomes are complex processes which can be explained in different ways by a combination of the clinical and social contexts which PLWH are exposed to at the time of diagnosis, and by developmental characteristics. A greater understanding of these processes could inform healthcare policy-making for specific HIV generations and different HIV age groups.

We leverage Gaia DR2 parallactic distances to deliver new or revised estimates of planetary parameters and X-ray irradiation for a distance-limited (\\(\\lesssim 100\\) pc) sample of 27 gaseous planets (from super-Earths to hot Jupiters) with publicly available Chandra and/or XMM observations, for which we carry out a homogeneous data reduction. For 20 planets with X-ray detected host stars we make use of the photoionization hydrodynamics code ATES to derive updated atmospheric mass outflow rates. The newly derived masses/radii are not consistent with the exoplanet.eu values for five systems; HD 149026b and WASP-38, for mass; and Au Mic b, HAT-P-20 and HAT-P-2 for radii. Notably, the lower mass implies a (Saturn-like) density of \\(0.86\\pm 0.09\\) g cm\\(^{-3}\\) for HD 149026 b. This independent estimate is consistent with the lowest values reported in the literature. Separately, we report on the X-ray detection of GJ 9827, HD 219134 and LHS 1140 for the first time. The inferred stellar X-ray luminosity of LHS 1140 (\\(1.34^{+0.19}_{-0.21} \\times 10^{26}\\) erg sec\\(^{-1}\\)) implies that LHS 1140 b is the least irradiated transiting super-Earth known to orbit within the habitable zone of a nearby M-dwarf.

We report an investigation of the magnetic core of the biomolecule ferritin by means of proton nuclear magnetic resonance (NMR) and relaxation, magnetic susceptibility and scanning electron microscope (SEM) measurements. SEM images show that the outer protein shell is taken out completely by an appropriate chemical treatment and indicate particle sizes ranging from 102 to 104 nm. Susceptibility measurements show a maximum in the zero-field-cooled data which is strongly field-dependent and can be ascribed to superparamagnetic behavior, whereas the hysteresis curve is different from normal ferritin. Proton NMR and spin-lattice relaxation data as a function of temperature at 4.7 T suggest the presence of an antiferromagnetic transition around 100 K.

We model the atmosphere of the ultra-hot Jupiter (UHJ) WASP-178b accounting for NLTE effects and compare synthetic transmission spectra with NUV and optical observations. We use the HELIOS code (LTE) in the lower and the Cloudy code (LTE or NLTE) in the middle and upper atmosphere to compute the temperature-pressure (TP) and abundance profiles. We further use Cloudy to compute the theoretical planetary transmission spectrum both in LTE and NLTE for comparison with observations. We find an isothermal TP profile at pressures higher than 10 mbar and lower than 10\\(^{-8}\\) bar, with an almost linear increase from about 2200 K to about 8100 K in between. The temperature structure is driven by NLTE effects, particularly in the form of increased heating resulting from the overpopulation of long-lived FeII levels with strong transitions in the NUV band, where the stellar emission is strong, and of decreased cooling due to the underpopulation of MgI and MgII levels that dominate the cooling. The planetary atmosphere is hydrostatic up to pressures of about 1 nbar, and thus accurately modelling spectral lines forming at pressures lower than about 1 nbar requires accounting for both hydrodynamics and NLTE effects. The NLTE synthetic transmission spectrum overestimates the observed H\\(\\alpha\\) and H\\(\\beta\\) absorption, while the LTE model is in good agreement, which is surprising as the opposite has been found for the other UHJs for which NLTE modelling has been performed. Instead, in the NUV we find an excellent match between the NLTE transmission spectrum and the HST/UVIS data, contrary to the LTE model. This contrasts previous LTE results requiring SiO absorption to fit the observations. The accurate characterisation of the atmosphere of UHJs is possible only accounting for NLTE effects, and particularly for the level population of Fe and Mg, which dominate heating and cooling, respectively.