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Recent developments of carbon capture and storage and geothermal subsurface prospects in the Middle Jurassic limestone of the central part of the Paris Basin have rejuvenated interest in the world class outcrops of the Bathonian Oolithe Blanche Formation on the southeastern edge of the Basin. Here, ooid-bioclast grainstones occur as large-scale (10–15 m high) clinoforms in the upper part of the Oolithe Blanche, which remain enigmatic and variously interpreted. High-resolution sequence stratigraphic correlations, constrained by biostratigraphic markers and integrated with regional palaeogeography, indicate that the clinoforms are giant dunes developed during the early part of the regressive phase of a third-order transgressive–regressive sequence (Bt3), in the northern part of the Burgundy Bathonian carbonate ramp. Carbonate sand bodies up to 15 m high with intervening troughs, formed subaqueous giant dune field(s) with calculated wavelengths of about 500–800 m. Using dune height as a proxy for calculating the palaeobathymetry of deposition, it is concluded that the dunes formed under a minimum water depth of about 60 m. A detailed facies analysis of the sediments underlying the dunes, which include beds rich in brachiopods in living position corresponding to the MFS of the third-order transgressive–regressive sequence (Bt3), supports such a water depth. The constitutive facies of the dunes themselves also reflect a significant water depth, despite the presence of ooids that are definitely transported away from their main production zone. This new interpretation of the large-scale clinoforms in the upper Oolithe Blanche and the associated revised palaeobathymetry have implications for the interpretations of Bathonian carbonates across the Paris Basin, which are relevant to ongoing projects of reservoir characterization of subsurface prospects.

The difficulty of correlating continental deposits hinders predicting lacustrine and palustrine carbonate facies variations in time and space. This study aims to understand better the factors governing these facies heterogeneities by measuring carbonate isotopes and conducting facies, petrographic and sequence stratigraphic analyses of the Lutetian–Aquitanian deposits of the Paris Basin, that record the transition from marine to lacustrine environments. Large‐scale correlations enabled the definition of two lacustrine–palustrine carbonate facies models. (1) The coastal lacustrine system (Bartonian to Rupelian), consists of fine‐grained brackish carbonate exhibiting episodic marine inputs during short‐term relative sea‐level maxima and evaporite sedimentation during relative sea‐level minima. Lacustrine sediments differ notably from marine ones with more negative δ13C and δ18O compositions that co‐vary and a biota adapted to low salinity conditions. In the associated palustrine environment, depositional sequences evolve upwards from micritic lacustrine deposits to nodular and then laminar calcretes. Microbial‐coated grains and rhizoliths indicate biological processes during repeated subaerial exposure phases in sub‐tropical to arid climates. (2) The inland lacustrine system (Rupelian and Aquitanian) was disconnected from the marine domain and showed evidence of microbial activity with microbial crusts and oncoidal rudstones. Facies rich in micritic intraclasts composed of palustrine and lacustrine facies indicate the reworking of already lithified sediments along the margins. In the palustrine domain, the calcrete facies are less abundant than breccias formed in‐situ by desiccation, limestones with root traces, or organic‐rich wackestones and marls. This system reflects a more temperate climate with more developed microbial structures and less exposed carbonates than the coastal lacustrine system. The southward migration of the depocentre and the transition from marine environments to (1) coastal and then (2) inland systems are controlled by uplift phases induced by Pyrenean and Alpine orogenesis. Third‐order relative sea‐level variations appear to control only short‐term cycles in coastal systems. In this work focussing on the Cenozoic continental carbonates of the Paris Basin, new information is brought to light on the spatialisation of continental carbonates facies thanks to correlations between coastal and palustrine environments. It presents arguments for distinguishing between marine (lagoon‐type) and continental (lake‐type) deposits based on facies, microfacies, large‐scale correlation, palaeontology and isotope data. By providing two new facies models for lacustrine and palustrine carbonates, this manuscript illustrates the coupled impact of tectonics, climate and episodic connections to the marine domain on facies distribution and type.

We provide new constraints for the fluid flow system at the origin of two F-Ba deposits located at the unconformity between the south of the Paris Basin and the northern edge of the French Massif Central. We used microthermometry and bulk crush-leach analyses to determine isotope ratios of mineralizing fluids (δ18O, δD, δ37Cl), together with cation and anion composition of fluid inclusions hosted by fluorite. Chlorinity and Cl/Br molar ratios (212–521) indicate the involvement of a brine, whose origin likely corresponds to Triassic evaporated seawater compatible with supratidal dolomitic facies preserved nearby. Microthermometry reveals high Ca/Na ratios, suggesting that the brine composition evolved from hydrothermal alteration of the Variscan basement and partial dissolution and replacement of the host sedimentary rocks. δ37Cl values are lower than the expected value of evaporated seawater, suggesting Cl isotope fractionation by ion filtration in clay-rich horizons. Fluorite crystallized at minimum temperatures of 70 to 110 °C, 10–40 °C warmer than the host Triassic sedimentary rocks. Ascending brines were expelled during the Early Cretaceous and experienced a drop in pressure and temperature, together with possible mixing with the SO4-rich pore water of the sedimentary rocks, causing precipitation of silica, followed by fluorite and barite, forming a stratabound deposit similar to those found in many areas in Western Europe.

Jurassic carbonate strata in the eastern Paris Basin exhibit several generations of faults, tension gashes and stylolites. Although their relative chronology can sometimes be determined according to cross-cutting relationships, the duration of major deformation phases and their influence on fluid flow and carbonate cementation are still uncertain. This contribution aims to clarify the timing of brittle deformation and associated calcite cementation. Tension gashes filled by calcite in Jurassic carbonates were sampled in outcrops and boreholes and dated through U–Pb geochronology. Almost all the sampled fractures were cemented during the Cenozoic period. Continuous deformation spread from c. 50 to 30 Ma. Tension gashes oriented N10° to N20° dated at 48–43 Ma show the main Pyrenean contractional stage. A second set of calcites were dated at c. 35–33 Ma and document a Late Eocene – Oligocene extension. A transition from the compressional to the extensional regime is expressed by tension gashes dated between 43 and 35 Ma. Finally, tension gashes oriented N150° to N175°, dated between 32 and 18 Ma, may result from the propagation of the horizontal stress generated by the Alpine orogen or by late Pyrenean deformation. Clumped isotope thermometry on five samples revealed both low crystallization temperatures (from 27 to 53 °C) and the meteoric origin of calcite-precipitating fluids. Our research therefore documents a continuous fracturing from Ypresian to Rupelian times, and less expressed brittle deformation during the Miocene period.

Global climate carbon cycle modeling Brief glacial episodes of the Mesozoic Jurassic ice sheet The Mesozoic, perhaps the longest period of warmth during the Phanerozoic Earth history, has been repeatedly affected by short-lived cold interludes lasting about one million years. While the origin of these cold snaps has been classically attributed to a temporary atmospheric CO2 drawdown, quantified mechanisms explaining these instabilities of the carbon cycle are still lacking. Based on a climate carbon cycle model, we show that the general demise of carbonate platforms accompanying these short-lived cold interludes is a powerful mechanism capable of generating a fast atmospheric CO2 decrease and a moderate sea level drop associated with ice sheet buildup. The temporary nature of the carbonate production decline explains the relative short time of these cold events but makes it possible to account for ice sheet waxing and waning.

In the Western Alps, the Penninic frontal thrust (PFT) is the main crustal-scale tectonic structure of the belt. This thrust transported the high-pressure metamorphosed internal units over the non-metamorphosed European margin during the Oligocene (34–29 Ma). Following the propagation of the compression toward the European foreland, the PFT was later reactivated as an extensional detachment associated with the development of the High Durance extensional fault system (HDFS). This inversion of tectonic displacement along a major tectonic structure has been widely emphasized as an example of extensional collapse of a thickened collisional orogen. However, the inception age of the extensional inversion remains unconstrained. Here, for the first time, we provide chronological constraints on the extensional motion of an exhumed zone of the PFT by applying U–Pb dating on secondary calcites from a fault zone cataclasite. The calcite cement and veins of the cataclasite formed after the main fault slip event, at 3.6 ± 0.4–3.4 ± 0.6 Ma. Cross-cutting calcite veins featuring the last fault activity are dated at 2.6 ± 0.3–2.3 ± 0.3 Ma. δ13C and δ18O fluid signatures derived from these secondary calcites suggest fluid percolation from deep-seated reservoir at the scale of the Western Alps. Our data provide evidence that the PFT extensional reactivation initiated at least ∼ 3.5 Myr ago with a reactivation phase at ∼ 2.5 Ma. This reactivation may result from the westward propagation of the compressional deformation toward the external Alps, combined with the exhumation of external crystalline massifs. In this context, the exhumation of the dated normal faults is linked to the eastward translation of the HDFS seismogenic zone, in agreement with the present-day seismic activity.

Malgré l'utilisation généralisée de l'imagerie sismique 3D voire 4D pour la caractérisation de réservoirs géologiques, certaines particularités des réservoirs carbonatés sont encore mal comprises d'un point de vue sismique. En particulier, les effets diagénétiques ne sont pas toujours bien pris en compte dans l'interprétation des réflecteurs observés dans ces réservoirs. Nous proposons ici une étude de terrain centrée sur un affleurement typique d'une formation carbonatée bien connue, l’ « Oolithe Blanche » du Bassin Parisien. Cette formation est actuellement l'une des cibles privilégiées pour l'exploitation géothermique à moyenne enthalpie dans le bassin, avec de nombreux doublets implantés dans les métropoles d’Ile-de-France. Le site d’étude se situe en Bourgogne, dans une carrière près de la ville de Massangis. Un maillage de résolution décimétrique a été dessiné sur un des fronts de taille abandonnés de la carrière. Chaque cellule de la grille est caractérisée d'un point de vue sédimentologique et se voit attribuer un faciès dominant. A l'aide d'un oscilloscope portatif, la coupe 2D a été étudiée acoustiquement en mesurant les vitesses horizontales et verticales des ondes P et S. Une sismique synthétique est ensuite calculée à partir des vitesses des ondes P et en utilisant une ondelette de fréquence centrale adaptée aux dimensions de la coupe. Trois résultats majeurs ont émergé de la comparaison entre la description des faciès et le profil sismique. Premièrement, notre étude a permis de caractériser le rôle acoustique des cross-beds visibles dans deux faciès carbonatés du site. Ces structures apparaissent comme des zones de vitesses rapides des ondes acoustiques, donc potentiellement des zones moins poreuses et moins perméables. D'autre part, les réflecteurs sismiques observés sur la coupe correspondent aux limites d'un faciès particulier, celui à rudstone. Le contraste lithologique initial induisant un réflecteur sismique est renforcé par la présence d'un sol induré interprété au sommet de la structure sous-jacente. Cette surface indurée permettrait d'augmenter localement les impédances acoustiques et donc de créer un contraste encore plus fort que le simple changement de faciès. Enfin, des structures karstiques à petite échelle ont été décrites et semblent générer un faciès sismique chaotique à l'échelle de l'affleurement.

World-class stratabound fluorite deposits are spatially associated with the basement/sediment unconformity of the intracratonic Paris Basin and the Morvan Massif in Burgundy (France). The reserves are estimated to be about 5.5 Mt of fluorite within six fluorite deposits. In this study, we aim to determine the age of the major fluorite mineralization event of the Pierre-Perthuis deposit (1.4 Mt fluorite) by a combined study of the paragenetic mineral sequence and Sm-Nd dating on fluorite crystals. Fluorite occurs as isolated cubes or filling geodes in a Triassic, silicified, dolomitic formation. Three fluorite stages associated with sphalerite, pyrite, galena, barite, and quartz have been distinguished using optical, cathodoluminescence, and scanning electron microscopes. Seven crystals of the geodic fluorite stage were analyzed for their rare earth element (REE) contents and their 147 Sm/ 144 Nd and 143 Nd/ 144 Nd isotopic compositions. The normalized REE distribution displays homogeneous bell-shaped patterns for all the geodic fluorite samples with a Mid-REE enrichment over the Light-REE and Heavy-REE. The 147 Sm/ 144 Nd varies from 0.3108 to 0.5504 and the 143 Nd/ 144 Nd from 0.512313 to 0.512518. A six-point Sm-Nd isochron defines an age of 130 ± 15 Ma (initial 143 Nd/ 144 Nd = 0.512054, MSWD = 0.21). This Sm-Nd isochron provides the first age for the stratabound fluorite sediment-hosted deposit, related to an unconformity in the Paris Basin, and highlights a major Early Cretaceous fluid circulation event mainly above the basement/sediment unconformity during a flexural deformation of the Paris Basin, which relates to the rifting of the Bay of Biscay and the formation of the Ligurian Sea in the Western Europe domain.

The age of ore deposits constitutes a decisive element in understanding their formation. Deciphering their precise chronology may be a challenge in the absence of mineral phases that can be dated by conventional geochronometers. Fluorite is very common either as the major or accessory mineral in a wide variety of ores and may provide information regarding the origin and timing of mineralizing fluid flows. In this contribution, we explore U–Pb dating on fluorite crystals from the world-class carbonate strata-bound fluorite ore of Pierre-Perthuis in Burgundy (Morvan massif, France). The uranium distribution within fluorite is mapped using induced fission-track and synchrotron radiation X-ray fluorescence nano-imaging, showing that higher U content is measured in an overgrowth of fluorite (Flog) as a discrete band. Preservation of a micrometer-thick zonation in U, associated with other substituted elements such as Sr, Y, Fe and Zr, implies that neither solid-state diffusion nor dissolution–recrystallization occurred. These U-bearing external fluorite overgrowths contain solid inclusions of about 30 µm globular pyrite crystals with a mean δ34S of −23.6 ± 0.4 ‰V-CDT. We propose that the U incorporation in the fluorite lattice results from the development of a redox front during bacterial sulfate reduction. Flog generation sampled and analyzed by laser ablation–inductively coupled plasma mass spectrometry (LA-ICP-MS) on four different crystals provides identical U–Pb ages within the limits of analytical uncertainty. Considered altogether, these four crystals yield an age estimate of 40.0 ± 1.7 Ma, not corrected for matrix-related elemental fractionation. Our results show that fluorite LA-ICP-MS U–Pb geochronology has potential for dating distinct crystal growth stages, although further research should be conducted to evaluate its accuracy.

The aim of this study is to explore the use of lichens as biomonitors of the impact of nickel mining and ore treatment on the atmosphere in the New Caledonian archipelago (South Pacific Ocean); both activities emitting also Co, Cr and possibly Fe. Metal contents were analysed in thirty-four epiphytic lichens, collected in the vicinity of the potential sources, and in places free from known historical mining. The highest Ni, Co, and Cr concentrations were, as expected, observed in lichens collected near ore deposits or treatment areas. The elemental composition in the lichens was explored by multivariate analysis, after appropriately transforming the variables (i.e. using compositional data analysis). The sample score of the first principal component (PC1) makes the largest (positive) multiplicative contribution to the log-ratios of metals originating from mining activities (Ni, Cr, Co) divided by Ti. The PC1 scores are used here as a surrogate of pollution levels related to mining and metallurgical activity. They can be viewed as synthetic indicators mapped to provide valuable information for the management and protection of ecosystems or, as a first step, to select locations where air filtration units could be installed, in the future, for air quality monitoring. However, as this approach drastically simplifies the problem, supplying a broadly efficient picture but little detail, recognizing the different sources of contamination may be difficult, more particularly when their chemical differences are subtle. It conveys only relative information: about ratios, not levels, and is therefore recommended as a preliminary step, in combination with close examination of raw concentration levels of lichens. Further validation using conventional air-monitoring by filter units should also prove beneficial.