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The origin of the late preindustrial Holocene (LPIH) increase in atmospheric methane concentrations has been much debated. Hypotheses invoking changes in solely anthropogenic sources or solely natural sources have been proposed to explain the increase in concentrations. Here two high-resolution, high-precision ice core methane concentration records from Greenland and Antarctica are presented and are used to construct a high-resolution record of the methane inter-polar difference (IPD). The IPD record constrains the latitudinal distribution of emissions and shows that LPIH emissions increased primarily in the tropics, with secondary increases in the subtropical Northern Hemisphere. Anthropogenic and natural sources have different latitudinal characteristics, which are exploited to demonstrate that both anthropogenic and natural sources are needed to explain LPIH changes in methane concentration.

Here, we present direct measurements of atmospheric composition and Antarctic climate from the mid-Pleistocene (∼1 Ma) from ice cores drilled in the Allan Hills blue ice area, Antarctica. The 1-Ma ice is dated from the deficit in ⁴⁰Ar relative to the modern atmosphere and is present as a stratigraphically disturbed 12-m section at the base of a 126-m ice core. The 1-Ma ice appears to represent most of the amplitude of contemporaneous climate cycles and CO ₂ and CH ₄ concentrations in the ice range from 221 to 277 ppm and 411 to 569 parts per billion (ppb), respectively. These concentrations, together with measured δD of the ice, are at the warm end of the field for glacial–interglacial cycles of the last 800 ky and span only about one-half of the range. The highest CO ₂ values in the 1-Ma ice fall within the range of interglacial values of the last 400 ka but are up to 7 ppm higher than any interglacial values between 450 and 800 ka. The lowest CO ₂ values are 30 ppm higher than during any glacial period between 450 and 800 ka. This study shows that the coupling of Antarctic temperature and atmospheric CO ₂ extended into the mid-Pleistocene and demonstrates the feasibility of discontinuously extending the current ice core record beyond 800 ka by shallow coring in Antarctic blue ice areas. Significance Bubbles of ancient air trapped in ice cores permit the direct reconstruction of atmospheric composition and allow us to link greenhouse gases and global climate over the last 800 ky. Here, we present new ice core records of atmospheric composition roughly 1 Ma from a shallow ice core drilled in the Allan Hills blue ice area, Antarctica. These records confirm that interglacial CO ₂ concentrations decreased by 800 ka. They also show that the link between CO ₂ and Antarctic temperature extended into the warmer world of the mid-Pleistocene.

Holocene temperature evolution remains poorly understood. Proxies in the early and mid‐Holocene suggest a Holocene Thermal Maximum (HTM) where temperatures exceed the pre‐industrial, whereas climate models generally simulate monotonic warming. This discrepancy may reflect proxy seasonality biases or errors in climate model internal feedbacks or dynamics. Using seasonally unbiased ice core reconstructions at NEEM, NGRIP, and Greenland Ice Sheet Project 2, we identify a Greenland HTM of ∼2°C above pre‐industrial, in agreement with other Northern Hemisphere proxy reconstructions. The firn‐based reconstructions are verified through borehole thermometry, producing a multi‐core, multi‐proxy reconstruction of Greenland climate from the last glacial to pre‐industrial. HTM timing across Greenland is heterogenous, occurring earlier at high elevations. Total air content measurements suggest a temperature contribution from elevation changes; regional oceanographic conditions, a weakened polar lapse rate, or variable near‐surface inversions may also be important sensitivities. Our reconstructions support climate simulations with dynamic Holocene vegetation, highlighting the importance of vegetation feedbacks. Plain Language Summary Climate change during the Holocene, the current geological time period, is important to understand. This period began ∼11.7 thousand years ago and contains the transition from the last ice age to today. Simulations of this transition suggest that global climate continued to warm across this whole period. Proxy evidence, however, tends to suggest that warmer‐than‐modern temperatures were reached at the start of the Holocene, followed by gradual cooling. Resolving this dispute in our recent climatological past is important to verify climate model behavior, and understand nuances in proxy records. Using ice core reconstructions of Greenland climate, which broadly follows northern high‐latitude climate, we lend further support to a warm period in the early Holocene. These new records are spread across Greenland, allowing for the spatial fingerprint of this warm period to be identified. Key Points We identify a Holocene Thermal Maximum (HTM) across three Greenland ice cores of 1.6–2.6°C above pre‐industrial The HTM has a south‐to‐north difference in timing, beginning earlier at Greenland Ice Sheet Project 2 in the south (9.9 ka) and later at NEEM in the north (6.85 ka) Total air content suggests that deglacial elevation change contributes to this timing difference, but cannot fully explain observed trends

Nitrous oxide (N2O) is an important greenhouse gas which destroys the ozone in the stratosphere. Primary sources of atmospheric N2O are nitrification and denitrification in terrestrial soils and the ocean, and the main sink is photolysis in the stratosphere. Studies have mostly focused on the climate‐related response of N2O during glacial‐interglacial periods. However, its mechanism of variation during the Holocene remains unclear. We present a high‐resolution N2O record from the South Pole Ice (SPICE) core covering the Holocene epoch. The millennial‐scale N2O trend agrees with existing records. We constructed a Holocene composite consisting of the new N2O measurements in SPICE and existing records from other ice core sites. The N2O composite reveals four distinct periods of N2O variation during 11.5–10.0 ka, 10.0–6.2 ka, 6.2–2.2 ka, and 2.2–1.4 ka, including two maxima in 11.0–10.0 ka and 3.0–2.2 ka and minima in 8.8–6.2 ka and approximately 1.4 ka. Apart from these, our new high‐resolution record from SPICE shows a short‐term N2O decrease around 2.8 ka which is not observed in other records possibly due to lower sample resolution and/or higher age smoothing. Comparison of our new Holocene N2O composite with the paleo‐proxy records suggests the plausible linkage of major monsoon (Asian, North African, South and North American, and Australian‐Indonesian monsoon) and upwelling (Arabian Sea and Eastern Tropical South Pacific) regions in regulating the atmospheric N2O during the Holocene. Plain Language Summary Nitrous oxide (N2O) is an important greenhouse and ozone‐depleting gas. The growing level of N2O in the atmosphere is of global concern, and records of past N2O variations can provide an essential context for understanding the links between N2O and climate change. In this study, we report a new, high‐quality N2O record covering the Holocene epoch using an ice core obtained from the South Pole. Our record shows four important periods of N2O variation during 11.5–10.0 ka, 10.0–6.2 ka, 6.2–2.2 ka, and 2.2–1.4 ka. These include two local N2O maxima in 11.0–10.0 ka and 3.0–2.2 ka and minima in 8.8–6.2 ka and approximately 1.4 ka. Comparison with climate records suggests that the variation in monsoon precipitation and ocean productivity contributed to centennial‐ to millennial‐scale N2O variations during the Holocene. Key Points High‐resolution N2O record from the South Pole Ice core covering the Holocene epoch is investigated for N2O variation Insight into the key drivers of atmospheric N2O on millennial time scales during the Holocene is provided N2O exhibits two local maxima during 11.0–10.0 ka and 3.0–2.2 ka, and two local minima during 8.8–6.2 ka and at around 1.4 ka

Data laboriously extracted from an Antarctic ice core provide an unprecedented view of temperature, and levels of atmospheric carbon dioxide and methane, over the past 800,000 years of Earth's history. Cover caption The air bubbles trapped in the Antarctic Vostok and EPICA Dome C ice cores provide composite records of levels of atmospheric carbon dioxide and methane covering the past 650,000 years. Now the record of atmospheric carbon dioxide and methane concentrations has been extended by two more complete glacial cycles to 800,000 years ago. The new data are from the lowest 200 metres of the Dome C core. This ice core went down to just a few metres above bedrock at a depth of 3,260 metres. Two papers report analyses of this deep ice, including the lowest carbon dioxide concentration so far measured in an ice core. Atmospheric carbon dioxide is strongly correlated with Antarctic temperature throughout the eight glacial cycles, but with significantly lower concentrations between 650,000 and 750,000 years before present. The cover shows a strip of ice core from an Antarctic ice core from Berkner Island, this slice from a depth of 120 metres. Photo by Chris Gilbert, British Antarctic Survey. Elsewhere in this issue, we move from climates past to future plans for climate prediction.

We present a 2700-year annually resolved chronology and snow accumulation history for the Roosevelt Island Climate Evolution (RICE) ice core, Ross Ice Shelf, West Antarctica. The core adds information on past accumulation changes in an otherwise poorly constrained sector of Antarctica. The timescale was constructed by identifying annual cycles in high-resolution impurity records, and it constitutes the top part of the Roosevelt Island Ice Core Chronology 2017 (RICE17). Validation by volcanic and methane matching to the WD2014 chronology from the WAIS Divide ice core shows that the two timescales are in excellent agreement. In a companion paper, gas matching to WAIS Divide is used to extend the timescale for the deeper part of the core in which annual layers cannot be identified. Based on the annually resolved timescale, we produced a record of past snow accumulation at Roosevelt Island. The accumulation history shows that Roosevelt Island experienced slightly increasing accumulation rates between 700 BCE and 1300 CE, with an average accumulation of 0.25±0.02 m water equivalent (w.e.) per year. Since 1300 CE, trends in the accumulation rate have been consistently negative, with an acceleration in the rate of decline after the mid-17th century. The current accumulation rate at Roosevelt Island is 0.210±0.002 m w.e. yr−1 (average since 1965 CE, ±2σ), and it is rapidly declining with a trend corresponding to 0.8 mm yr−2. The decline observed since the mid-1960s is 8 times faster than the long-term decreasing trend taking place over the previous centuries, with decadal mean accumulation rates consistently being below average. Previous research has shown a strong link between Roosevelt Island accumulation rates and the location and intensity of the Amundsen Sea Low, which has a significant impact on regional sea-ice extent. The decrease in accumulation rates at Roosevelt Island may therefore be explained in terms of a recent strengthening of the ASL and the expansion of sea ice in the eastern Ross Sea. The start of the rapid decrease in RICE accumulation rates observed in 1965 CE may thus mark the onset of significant increases in regional sea-ice extent.

The Holocene portion of the Siple Dome (Antarctica) ice core was dated by interpreting the electrical, visual and chemical properties of the core. The data were interpreted manually and with a computer algorithm. The algorithm interpretation was adjusted to be consistent with atmospheric methane stratigraphic ties to the GISP2 (Greenland Ice Sheet Project 2) ice core, 10Be stratigraphic ties to the dendrochronology 14 C record and the dated volcanic stratigraphy. The algorithm interpretation is more consistent and better quantified than the tedious and subjective manual interpretation.