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result(s) for
"Buchs, David M."
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Ocean freshening near the end of the Mesozoic
2025
Paleogeographic changes have significantly shaped ocean circulation and climate dynamics throughout Earth’s history. This study integrates geological proxies with climate simulations to assess how ocean gateway evolution influenced ocean salinity near the end of the Mesozoic (~66 Ma). Our modeling results demonstrate that 1) Central American Seaway shoaling reorganizes ocean currents, and 2) Arctic marine gateway restrictions, confining Arctic–Global Ocean exchange exclusively to the Greenland–Norwegian Seaway, drive Arctic Ocean surface freshening and southward outflow of buoyant, low-salinity waters. However, only the combined effect of these two factors leads to both Arctic freshening and increased water mass stratification in the Greenland–Norwegian Seaway, proto-North Atlantic, and the Western Tethys. This scenario aligns with Maastrichtian palynological, micropaleontological, and geochemical records from high- and low-latitude sites. Our findings highlight the profound impact of these latest Cretaceous paleogeographic reconfigurations in altering global salinity patterns, underscoring their role as key drivers of global climate dynamics.
This study shows that changes in ocean gateways near the end of the Mesozoic (~66 Ma) altered global ocean salinity and circulation, reshaping climate patterns through combined reconfigurations in the Arctic and Central American regions.
Journal Article
Late Cretaceous arc development on the SW margin of the Caribbean Plate: Insights from the Golfito, Costa Rica, and Azuero, Panama, complexes
by
Buchs, David M.
,
Baumgartner-Mora, Claudia
,
Arculus, Richard J.
in
Accretion
,
arc initiation
,
Caribbean
2010
The processes of arc initiation at the margin of an oceanic plateau are remarkably well preserved along the southern coastline of eastern Costa Rica and western Panama. We present new results of a combined tectonostratigraphic and petrologic study with which protoarc initiation (75–73 Ma) at the margin of an oceanic plateau (89–85 Ma) is documented. Dykes of protoarc igneous rocks within the plateau and occurrences of protoarc igneous rocks are widely distributed. These types of field observations, geochemical data, and paleontologic ages for Late Cretaceous to Eocene fore‐arc rocks of the Golfito Complex and Azuero Marginal Complex (southern Costa Rica and western Panama) provide the first direct evidence that a Coniacian–early Santonian oceanic plateau forms the arc basement. Stratigraphic and geochemical constraints from Golfito and Azuero indicate subduction initiation in south Central America, associated with geochemically distinctive suprasubduction igneous rocks, occurred in the late Campanian along the margin of the newly defined Azuero Plateau. Overall, the Golfito Complex and Azuero Marginal Complex provide a significant opportunity for exploration of petrologic mechanisms linking some oceanic plateaus to the growth of continents. The Azuero Plateau may extend further toward the Colombian Basin and forms thickened Caribbean crust. It served as a nucleus for accretion of additional oceanic plateaus, seamounts, and oceanic islands of Pacific origins.
Journal Article
Volcanic contribution to emergence of Central Panama in the Early Miocene
2019
Formation of the Panama Isthmus, that had global oceanographic and biotic effects in the Neogene, is generally associated with tectonic uplift during collision of the Panama volcanic arc with South America. However, new field, geochemical and geochronological data from the Culebra Cut of the Panama Canal suggest that volcanism also contributed to the Isthmus emergence in the Early Miocene. This volcanism is recorded in a newly-recognised Central Panama volcanic field that includes several phases of development. Early activity of this field along the Panama Canal was associated with proximal effusive to explosive felsic products during formation of subaerial stratovolcanoes and possible domes ca. 21 Ma. This was followed by a period of marine transgression ca. 21–18 Ma, with more distal volcanism documented by tuffs that deposited in marine to terrestrial environments. Finally, proximal mafic volcanism formed tephra cones in a monogenetic field ca. 18(-?) Ma. This was associated with phreatomagmatic processes in a coastal environment, with remarkable kilometre-wide subvolcanic peperitic intrusions. We propose based on these observations that formation of the Central Panama volcanic field was critical in shaping regional topography, and that this could have actively contributed to obstruction and closure of an interoceanic strait in Central Panama.
Journal Article
Paleozoic ocean plate stratigraphy unraveled by calcite U-Pb dating of basalt and biostratigraphy
2022
Oceanic mafic volcanic rocks preserve unique information regarding the nature and evolution of tectonic plates. However, constraining their age is commonly challenging because of their lack of datable minerals and high degrees of alteration. We present in situ laser ablation–inductively coupled plasma–mass spectrometry U-Pb dating of calcite phases in altered basalts in a Paleozoic subduction complex (eastern Australia). Calcite enclosed in amygdules and filled in fractures yielded two distinctive ages with contrasting geochemical signatures. These results, combined with new biostratigraphic and whole-rock geochemical data, suggest that oceanic islands formed in the Panthalassa Ocean at about 365 million years ago, accreted to eastern Gondwana at about 330 million years ago, and underwent brittle deformation at about 305 million years ago. Calcite U-Pb geochronology is valuable to help constrain minimum formation ages of volcanic rocks and their deformation history, ultimately improving ability to unravel the geological record of accretionary complexes, and more generally ancient underwater volcanic systems.
Journal Article
Present-day principal horizontal stress orientations in the Kumano forearc basin of the southwest Japan subduction zone determined from IODP NanTroSEIZE drilling Site C0009
2010
A 1.6 km riser borehole was drilled at site C0009 of the NanTroSEIZE, in the center of the Kumano forearc basin, as a landward extension of previous drilling in the southwest Japan Nankai subduction zone. We determined principal horizontal stress orientations from analyses of borehole breakouts and drilling‐induced tensile fractures by using wireline logging formation microresistivity images and caliper data. The maximum horizontal stress orientation at C0009 is approximately parallel to the convergence vector between the Philippine Sea plate and Japan, showing a slight difference with the stress orientation which is perpendicular to the plate boundary at previous NanTroSEIZE sites C0001, C0004 and C0006 but orthogonal to the stress orientation at site C0002, which is also in the Kumano forearc basin. These data show that horizontal stress orientations are not uniform in the forearc basin within the surveyed depth range and suggest that oblique plate motion is being partitioned into strike‐slip and thrusting. In addition, the stress orientations at site C0009 rotate clockwise from basin sediments into the underlying accretionary prism.
Journal Article
Surface textures of detrital pyroxenes in coastal dune sands (western Gulf of Mexico, Mexico): Implications for their preservation and geoenvironmental processes
by
Martínez‐Serrano, Raymundo Gerardo
,
Buchs, David M.
,
Kasper‐Zubillaga, Juan J.
in
Abrasion
,
clinopyroxene
,
coastal dune sands
2023
This work investigates how the surface textures and morphology of pyroxene grains evolve during their source‐to‐sink history. This study applies to detrital clinopyroxenes concentrated in coastal dune sands of the Gulf of Mexico which were sourced in the Trans Mexican Volcanic Belt then transported and deposited in environments subject to limited chemical weathering. The composition and morphology of the pyroxenes was characterised using single‐grain geochemical analysis and surface texture imagery with a novel approach based on the compactness property to assess the shape of minerals. This reveals heterogenous diopside‐augite populations, displaying mineral morphologies dominantly controlled by impact breakage along cleavages, little physical abrasion along their edges and with limited evidence for chemical weathering. Mechanical surface textures dominate over mechanical/chemical and chemical surface textures. These mechanical surface textures are preserved primarily as flat cleavage surfaces and rounded edges inherited from fluvial‐intertidal and aeolian transport, respectively. Mechanically/chemically induced surface textures are preserved as elongated depressions. Chemical surface textures are sparse and mostly represented by mammillated textures that suggest local dissolution under subaqueous conditions. The scarcity of chemical surface textures is attributed to frequent fragmentation of the clinopyroxenes along cleavages and limited chemical weathering during transport of the observed populations. Clinopyroxene grains in the coastal dune sands primarily retain surface characteristics from fluvial transport. Although the breakage of minerals along cleavages can obscure their original morphology under a weathering‐limited erosion regime, this study shows how surface textures and morphology of pyroxene grains is used to determine episodes of transport and deposition close to volcanic environments. The use of the compactness property as a shape descriptor measurement of particles provides an alternative approach to observe how clinopyroxene remains unaltered despite the high energy conditions of the coastal area.
Journal Article
Climatic and edaphic controls over tropical forest diversity and vegetation carbon storage
by
Dullinger, Stefan
,
Silla, Fernando
,
Morera-Beita, Albert
in
631/158/2454
,
704/158/670
,
704/47/4113
2020
Tropical rainforests harbor exceptionally high biodiversity and store large amounts of carbon in vegetation biomass. However, regional variation in plant species richness and vegetation carbon stock can be substantial, and may be related to the heterogeneity of topoedaphic properties. Therefore, aboveground vegetation carbon storage typically differs between geographic forest regions in association with the locally dominant plant functional group. A better understanding of the underlying factors controlling tropical forest diversity and vegetation carbon storage could be critical for predicting tropical carbon sink strength in response to projected climate change. Based on regionally replicated 1-ha forest inventory plots established in a region of high geomorphological heterogeneity we investigated how climatic and edaphic factors affect tropical forest diversity and vegetation carbon storage. Plant species richness (of all living stems >10 cm in diameter) ranged from 69 to 127 ha
−1
and vegetation carbon storage ranged from 114 to 200 t ha
−1
. While plant species richness was controlled by climate and soil water availability, vegetation carbon storage was strongly related to wood density and soil phosphorus availability. Results suggest that local heterogeneity in resource availability and plant functional composition should be considered to improve projections of tropical forest ecosystem functioning under future scenarios.
Journal Article
Submarine volcanic activity and giant amygdale formation along the Panama island arc as a precursor to 6000-year-old agate exploitation on Pedro González Island
by
Redwood, Stewart D
,
Buchs, David M
,
Cavell, David Edward
in
agate
,
andesites
,
archaeological sites
2022
An extensive deposit of agate occurs in Pedro González Island in the Gulf of Panama. Previous archaeological research showed that the agate was exploited between 6200 and 5600 cal BP to make stone tools found at the oldest known Preceramic human settlement in the Pearl Island archipelago. We constrain here the origin and geological context of the agate through a geological and geochemical study of the island. We show that it includes primary volcanic breccias, lavas, and tuffaceous marine deposits with sedimentary conglomerates and debris flow deposits, which we define as the Pedro González Formation. This formation records submarine to subaerial volcanic activity along an island arc during the Oligo-Miocene, confirming previous regional models that favour progressive emergence of the isthmus in the early Miocene. The igneous rocks have an extreme tholeiitic character that is interpreted to reflect magmatic cessation in eastern Panama during the early Miocene. The agate is hosted in andesitic lavas in unusually large amygdales up to 20–40 cm in diameter, as well as small amygdales (0.1–1.0 cm) in a bimodal distribution, and in veins. The large size of the agates made them suitable for tool manufacture. Field evidence suggests that the formation of large amygdales resulted from subaqueous lava–sediment interaction, in which water released from unconsolidated tuffaceous deposits at the base of lava flows rose through the lavas, coalesced, and accumulated below the chilled lava top, with subsequent hydrothermal mineralization. These amygdales could therefore be regarded as an unusual result of combined peperitic and hydrothermal processes.
Journal Article
Mineralogical characterization of rejuvenated magmatism at Burton Guyot, Louisville Seamount trail
2019
Volcaniclastic sequences drilled during IODP Expedition 330 on top of Burton Guyot preserve a unique record of rejuvenated magmatic activity along the Louisville Seamount trail. Geochemical analysis of clinopyroxenes in primary volcaniclastic deposits of this rejuvenated phase allows the reconstruction of magmatic evolution from the shield to post-erosional phases of a Louisville seamount, and to compare this evolution to that of Hawaiian volcanoes. Our results reveal the occurrence of three main types of clinopyroxenes in the rejuvenated volcaniclastic deposits at Burton Guyot, with a Na (and Al)-poor phenocrystic clinopyroxene and two types of Na-rich clinopyroxenes from disaggregated ultramafic xenoliths. The rejuvenated Na-poor phenocrysts have the same compositional range as clinopyroxenes associated with the shield stage of the volcano, indicating an overlap in shield and rejuvenated magma compositions. The dominant type of Na-rich clinopyroxene (Type 1) is very similar to clinopyroxenes in Hawaiian pyroxenitic xenoliths thought to represent high pressure cumulates. Their relatively low Mg/(Mg + Fe), Cr, and Sc contents, similar trace element abundances and high Al(vi):Al(iv) to Hawaiian cumulates indicates that they too are cumulates. This contrasts with lower Al(vi):Al(iv) of the Na-poor phenocrysts that crystallized between 6–7 kbars and 1150–1200 °C. Type 2 clinopyroxenes are Mg-rich, and have major and trace element compositions very similar to clinopyroxenes in Hawaiian peridotites. These clinopyroxenes are interpreted as fragments of mantle xenoliths. They show intermediate amounts of incompatible element depletion, between more enriched Hawaiian peridotites and strongly depleted abyssal peridotites. Some grains exhibit the effects of mantle metasomatism, having spoon-shaped, chondrite-normalized REE patterns like those of Hawaiian peridotite xenoliths. The occurrence of disaggregated pyroxenitic cumulates and metasomatized mantle xenoliths in rejuvenated magmas of both Burton Guyot and Hawaiian islands suggests that the plumbing system of these volcanic systems share significant similarities. However, consistently with previous geochemical studies of the Louisville seamounts, geochemical consistency of shield and rejuvenated clinopyroxenes at Burton Guyot show that this volcano experienced similar alkaline magmatism from shield to rejuvenated stages. This is an important difference with the evolution of Hawaiian volcanoes that includes a dominantly tholeiitic shield stages and alkaline post-shield and rejuvenated stages, which suggests that the model of Hawaiian island formation may not be fully applicable to Louisville seamounts.
Journal Article
Clinopyroxene diversity and magma plumbing system processes in an accreted Pacific ocean island, Panama
2022
Characterising equilibrium and disequilibrium crystal-melt processes is critical in determining the extent of magma mixing and crystallization conditions in the roots of volcanoes. However, these processes remain poorly investigated in most Pacific intraplate ocean settings that are difficult to access and study. To help address this issue, we investigated crystallization conditions of clinopyroxene phenocrysts in an accreted Palaeogene oceanic island in Panama. Petrographic and geochemical observations, petrological modelling of major and trace elements, and liquid-mineral multicomponent equilibrium tests were carried out using basalts, picrites, and hawaiites of the transitional tholeiitic shield to alkaline post-shield volcanic stages of the island. Five types of clinopyroxene crystals were identified, including (1) microphenocrysts with micron-scale oscillatory zoning, (2) primitive, yet resorbed picrite-hosted phenocrysts, (3) chemically homogeneous, anhedral crystals found in the remaining basalts, (4) Ti–rich euhedral hawaiite-hosted phenocrysts, and (5) evolved sector-zoned phenocrysts. Liquid-clinopyroxene multicomponent equilibrium tests in combination with textural analysis show that ~ 74% of the studied clinopyroxenes are in possible major element equilibrium with one of the available whole rock magma compositions, of which only 21% are equilibrated with their carrier liquid. To deconvolute clinopyroxene-melt pairings and determine plumbing system conditions, we combine rhyolite-MELTS modelling, geothermobarometry, and major- and trace-element equilibrium evaluations, limiting crystallization conditions to crustal levels (< 23 km depth). No migration of magmatic reservoirs to deeper levels is observed during the shield- to post-shield transition. These results suggest the occurrence of an extensive crystal mush system during the late shield to post-shield volcanic stages of this intraplate volcanic system, with both primitive and evolved crystallization domains sampled during eruptions.
Journal Article