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In the era of the James Webb Space Telescope (JWST), it is now possible to examine substellar mass atmospheres in unparalleled detail and precision. However, unraveling the complicated thermodynamics and chemistry in these atmospheres remains a challenge. Atmospheric retrievals are a leading data-driven technique capable of recovering an object’s fundamental parameters such as mass, radius, effective temperature, gravity, cloud structure and composition and chemical abundances. However, in directly imaged or isolated worlds, constraining and/or interpreting these fundamental parameters can be difficult, particularly as retrieval models try to parameterize the overall impact of clouds.For my dissertation, I turned to main sequence star – brown dwarf companion systems where the main sequence host can anchor metallicity, age, and abundance measurements for its substellar companion. I present results from conducting theoretical chemical analyses on a sample of benchmark companion brown dwarfs as well as solar neighborhood F, G, K-type stars to provide a global overview of the types of chemistry expected in nearby objects. Via mass balance and stoichiometric calculations, I predict the amount of oxygen that is being sequestered into refractory condensates in substellar atmospheres based on examined abundances of Mg, Si, Ca, Al, Ti, V and O. Additionally, I use solar neighborhood Mg/Si ratios to predict silicate condensation species (i.e. enstatite (MgSiO3), forsterite (Mg2SiO4), and/or quartz (SiO2) in a given companion. I extend this work beyond the brown dwarf regime to aid our understanding of giant exoplanet atmospheric chemistry by grounding models with their host star data. This work is crucial to link theory with observational data in order to test and calibrate evolutionary models and clarify our understanding of substellar formation.

At the lowest masses, the distinction between brown dwarfs and giant exoplanets is often blurred and literature classifications rarely reflect the deuterium burning boundary. Atmospheric characterisation may reveal the extent to which planetary formation pathways contribute to the population of very-low mass brown dwarfs, by revealing if their abundance distributions differ from those of the local field population or, in the case of companions, their primary stars. The T8 dwarf Ross 458c is a possible planetary mass companion to a pair of M dwarfs, and previous work suggests that it is cloudy. We here present the results of the retrieval analysis of Ross 458c, using archival spectroscopic data in the 1.0 to 2.4 micron range. We test a cloud free model as well as a variety of cloudy models and find that the atmosphere of Ross 458c is best described by a cloudy model (strongly preferred). The CH4/H2O is higher than expected at 1.97 +0.13 -0.14. This value is challenging to understand in terms of equilibrium chemistry and plausible C/O ratios. Comparisons to thermochemical grid models suggest a C/O of ~ 1.35, if CH4 and H2O are quenched at 2000 K, requiring vigorous mixing. We find a [C/H] ratio of +0.18, which matches the metallicity of the primary system, suggesting that oxygen is missing from the atmosphere. Even with extreme mixing, the implied C/O is well beyond the typical stellar regime, suggesting a either non-stellar formation pathway, or the sequestration of substantial quantities of oxygen via hitherto unmodeled chemistry or condensation processes.

We present results from an atmospheric retrieval analysis of Gl 229B using the BREWSTER retrieval code. We find the best fit model to be cloud-free, consistent with the T dwarf retrieval work of Line et al. 2017, Zalesky et al. 2022 and Gonzales et al. 2020. Fundamental parameters (mass, radius, log(L_{Bol}/L_{Sun}), log(g)) determined from our model agree within 1\\sigma to SED-derived values except for T_{eff} where our retrieved T_{eff} is approximately 100 K cooler than the evolutionary model-based SED value. We find a retrieved mass of 50^{+12}_{-9} M_{Jup}, however, we also find that the observables of Gl 229B can be explained by a cloud-free model with a prior on mass at the dynamical value, 70 M_{Jup}. We are able to constrain abundances for H_2O, CO, CH_4, NH_3, Na and K and find a supersolar C/O ratio as compared to its primary, Gl 229A. We report an overall subsolar metallicity due to atmospheric oxygen depletion but find a solar [C/H], which matches that of the primary. We find that this work contributes to a growing trend in retrieval-based studies, particularly for brown dwarfs, toward supersolar C/O ratios and discuss the implications of this result on formation mechanisms, internal physical processes as well as model biases.

We present an atmospheric retrieval analysis of a pair of highly variable, \\(\\sim200~\\)Myr old, early-T type planetary-mass exoplanet analogs SIMP J01365662+0933473 and 2MASS J21392676+0220226 using the Brewster retrieval framework. Our analysis, which makes use of archival \\(1-15~\\mu\\)m spectra, finds almost identical atmospheres for both objects. For both targets, we find that the data is best described by a patchy, high-altitude forsterite (Mg\\(_2\\)SiO\\(_4\\)) cloud above a deeper, optically thick iron (Fe) cloud. Our model constrains the cloud properties well, including the cloud locations and cloud particle sizes. We find that the patchy forsterite slab cloud inferred from our retrieval may be responsible for the spectral behavior of the observed variability. Our retrieved cloud structure is consistent with the atmospheric structure previously inferred from spectroscopic variability measurements, but clarifies this picture significantly. We find consistent C/O ratios for both objects which supports their formation within the same molecular cloud in the Carina-Near Moving Group. Finally, we note some differences in the constrained abundances of H\\(_2\\)O and CO which may be caused by data quality and/or astrophysical processes such as auroral activity and their differing rotation rates. The results presented in this work provide a promising preview of the detail with which we will characterize extrasolar atmospheres with JWST, which will yield higher quality spectra across a wider wavelength range.

We present results from conducting a theoretical chemical analysis of a sample of benchmark companion brown dwarfs whose primary star is of type F, G or K. We summarize the entire known sample of these types of companion systems, termed \"compositional benchmarks\", that are present in the literature or recently published as key systems of study in order to best understand brown dwarf chemistry and condensate formation. Via mass balance and stoichiometric calculations, we predict a median brown dwarf atmospheric oxygen sink of \\(17.8^{+1.7}_{-2.3}\\%\\) by utilizing published stellar abundances in the local solar neighborhood. Additionally, we predict a silicate condensation sequence such that atmospheres with bulk Mg/Si \\(\\lesssim\\) 0.9 will form enstatite (MgSiO\\(_3\\)) and quartz (SiO\\(_2\\)) clouds and atmospheres with bulk Mg/Si \\(\\gtrsim\\) 0.9 will form enstatite and forsterite (Mg\\(_2\\)SiO\\(_4\\)) clouds. Implications of these results on C/O ratio trends in substellar mass objects and utility of these predictions in future modeling work are discussed.

High-energy neutrinos are a promising tool for identifying astrophysical sources of high and ultra-high energy cosmic rays (UHECR). Prospects of detecting neutrinos at high energies (\\(\\gtrsim\\)TeV) from blazars have been boosted after the recent association of IceCube-170922A and TXS 0506+056. We investigate the high-energy neutrino, IceCube-190331A, a high-energy starting event (HESE) with a high likelihood of being astrophysical in origin. We initiated a Swift/XRT and UVOT tiling mosaic of the neutrino localisation, and followed up with ATCA radio observations, compiling a multiwavelength SED for the most likely source of origin. NuSTAR observations of the neutrino location and a nearby X-ray source were also performed. We find two promising counterpart in the 90% confidence localisation region and identify the brightest as the most likely counterpart. However, no Fermi/LAT \\(\\gamma\\)-ray source and no prompt Swift/BAT source is consistent with the neutrino event. At this point it is unclear whether any of the counterparts produced IceCube-190331A. We note that the Helix Nebula is also consistent with the position of the neutrino event, and we calculate that associated particle acceleration processes cannot produce the required energies to generate a high-energy HESE neutrino.

We present the discovery of 34 comoving systems containing an ultra-cool dwarf found by means of the NOIRLab Source Catalog (NSC) DR2. NSC's angular resolution of \\(\\sim\\)1\" allows for the detection of small separation binaries with significant proper motions. We used the catalog's accurate proper motion measurements to identify the companions by cross-matching a previously compiled list of brown dwarf candidates with NSC DR2. The comoving pairs consist of either a very low-mass star and an ultra-cool companion, or a white dwarf and an ultra-cool companion. The estimated spectral types of the primaries are in the K and M dwarf regimes, those of the secondaries in the M, L and T dwarf regimes. We calculated angular separations between \\(\\sim\\)2 and \\(\\sim\\)56\", parallactic distances between \\(\\sim\\)43 and \\(\\sim\\)261 pc and projected physical separations between \\(\\sim\\)169 and \\(\\sim\\)8487 AU. The lowest measured total proper motion is 97 mas yr\\(^{-1}\\), the highest 314 mas yr\\(^{-1}\\). Tangential velocities range from \\(\\sim\\)23 to \\(\\sim\\)187 km s\\(^{-1}\\). We also determined comoving probabilities, estimated mass ratios and calculated binding energies for each system. We found no indication of possible binarity for any component of the 34 systems in the published literature. The discovered systems can contribute to the further study of the formation and evolution of low-mass systems as well as to the characterization of cool substellar objects.

We have used data from the UKIRT Hemisphere Survey (UHS) to search for substellar members of the Hyades cluster. Our search recovered several known substellar Hyades members, and two known brown dwarfs that we suggest may be members based on a new kinematic analysis. We uncovered thirteen new substellar Hyades candidates, and obtained near-infrared follow-up spectroscopy of each with IRTF/SpeX. Six candidates with spectral types between M7 and L0 are ruled out as potential members based on their photometric distances (\\(\\gtrsim\\)100 pc). The remaining seven candidates, with spectral types between L5 and T4, are all potential Hyades members, with five showing strong membership probabilities based on BANYAN \\(\\Sigma\\) and a convergent point analysis. Distances and radial velocities are still needed to confirm Hyades membership. If confirmed, these would be some of the lowest mass free-floating members of the Hyades yet known, with masses as low as \\(\\sim\\)30 \\(M_{\\rm Jup}\\). An analysis of all known substellar Hyades candidates shows evidence that the full extent of the Hyades has yet to be probed for low-mass members, and more would likely be recovered with deeper photometric and astrometric investigations.

We present an atmospheric retrieval analysis on a set of young, cloudy, red L-dwarfs -- CWISER J124332.12+600126.2 and WISEP J004701.06+680352.1 -- using the \\textit{Brewster} retrieval framework. We also present the first elemental abundance measurements of the young K-dwarf (K0) host star, BD+60 1417 using high resolution~(R = 50,000) spectra taken with PEPSI/LBT. In the complex cloudy L-dwarf regime the emergence of condensate cloud species complicates retrieval analysis when only near-infrared data is available. We find that for both L dwarfs in this work, despite testing three different thermal profile parameterizations we are unable to constrain reliable abundance measurements and thus the C/O ratio. While we can not conclude what the abundances are, we can conclude that the data strongly favor a cloud model over a cloudless model. We note that the difficulty in retrieval constraints persists regardless of the signal to noise of the data examined (S/N \\(\\sim\\) 10 for CWISER J124332.12+600126.2 and~40 for WISEP J004701.06+680352.1). The results presented in this work provide valuable lessons about retrieving young, low-surface gravity, cloudy L-dwarfs. This work provides continued evidence of missing information in models and the crucial need for JWST to guide and inform retrieval analysis in this regime.

Isolated planetary-mass objects share their mass range with planets but do not orbit a star. They lack the necessary mass to support fusion in their cores and thermally radiate their heat from formation as they cool, primarily at infrared wavelengths. Many isolated planetary-mass objects show variations in their infrared brightness consistent with non-uniform atmospheric features modulated by their rotation. SIMP J013656.5+093347.3 is a rapidly rotating isolated planetary-mass object, and previous infrared monitoring suggests complex atmospheric features rotating in and out of view. The physical nature of these features is not well understood, with clouds, temperature variations, thermochemical instabilities, and infrared-emitting aurora all proposed as contributing mechanisms. Here we report JWST time-resolved low-resolution spectroscopy from 0.8 - 11 micron of SIMP J013656.5+093347.3 which supports the presence of three specific features in the atmosphere: clouds, hot spots, and changing carbon chemistry. We show that no single mechanism can explain the variations in the time-resolved spectra. When combined with previous studies of this object indicating patchy clouds and aurorae, these measurements reveal the rich complexity of the atmosphere of SIMP J013656.5+093347.3. Gas giant planets in the solar system, specifically Jupiter and Saturn, also have multiple cloud layers and high-altitude hot spots, suggesting these phenomena are also present in worlds both within and beyond our solar-system.