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The European Rosetta mission has been following comet 67P/Churyumov-Gerasimenko for 2 years, studying the nucleus and coma in great detail. For most of these 2 years the Rosetta Orbiter Sensor for Ion and Neutral Analysis (ROSINA) has analysed the volatile part of the coma. With its high mass resolution and sensitivity it was able to not only detect deuterated water HDO, but also doubly deuterated water, D₂O and deuterated hydrogen sulfide HDS. The ratios for [HDO]/[H₂O], [D₂O]/[HDO] and [HDS]/[H₂S] derived from our measurements are (1.05 ± 0.14) × 10⁻³, (1.80 ± 0.9) × 10⁻² and (1.2 ± 0.3) × 10⁻³, respectively. These results yield a very high ratio of 17 for [D₂O]/[HDO] relative to [HDO]/[H₂O]. Statistically one would expect just 1/4. Such a high value can be explained by cometary water coming unprocessed from the presolar cloud, where water is formed on grains, leading to high deuterium fractionation. The high [HDS]/[H₂S] ratio is compatible with upper limits determined in low-mass star-forming regions and also points to a direct correlation of cometary H₂S with presolar grain surface chemistry. This article is part of the themed issue 'Cometary science after Rosetta'.

The origin of cometary matter and the potential contribution of comets to inner-planet atmospheres are long-standing problems. During a series of dedicated low-altitude orbits, the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) on the Rosetta spacecraft analyzed the isotopes of xenon in the coma of comet 67P/Churyumov-Gerasimenko. The xenon isotopic composition shows deficits in heavy xenon isotopes and matches that of a primordial atmospheric component. The present-day Earth atmosphere contains 22 ± 5% cometary xenon, in addition to chondritic (or solar) xenon.

Comets contain the best-preserved material from the beginning of our planetary system. Their nuclei and comae composition reveal clues about physical and chemical conditions during the early solar system when comets formed. ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) onboard the Rosetta spacecraft has measured the coma composition of comet 67P/Churyumov-Gerasimenko with well-sampled time resolution per rotation. Measurements were made over many comet rotation periods and a wide range of latitudes. These measurements show large fluctuations in composition in a heterogeneous coma that has diurnal and possibly seasonal variations in the major outgassing species: water, carbon monoxide, and carbon dioxide. These results indicate a complex coma-nucleus relationship where seasonal variations may be driven by temperature differences just below the comet surface.

Molecular nitrogen (N2) is thought to have been the most abundant form of nitrogen in the protosolar nebula. It is the main N-bearing molecule in the atmospheres of Pluto and Triton and probably the main nitrogen reservoir from which the giant planets formed. Yet in comets, often considered the most primitive bodies in the solar system, N2 has not been detected. Here we report the direct in situ measurement of N2 in the Jupiter family comet 67P/Churyumov-Gerasimenko, made by the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis mass spectrometer aboard the Rosetta spacecraft. A N2/CO ratio of (5.70 ± 0.66) × 10–3 (2σ standard deviation of the sampled mean) corresponds to depletion by a factor of ∼25.4 ± 8.9 as compared to the protosolar value. This depletion suggests that cometary grains formed at low-temperature conditions below ∼30 kelvin.

The European Rosetta mission has been following comet 67P/Churyumov–Gerasimenko for 2 years, studying the nucleus and coma in great detail. For most of these 2 years the Rosetta Orbiter Sensor for Ion and Neutral Analysis (ROSINA) has analysed the volatile part of the coma. With its high mass resolution and sensitivity it was able to not only detect deuterated water HDO, but also doubly deuterated water, D 2 O and deuterated hydrogen sulfide HDS. The ratios for [HDO]/[H 2 O], [D 2 O]/[HDO] and [HDS]/[H 2 S] derived from our measurements are (1.05 ± 0.14) × 10 −3 , (1.80 ± 0.9) × 10 −2 and (1.2 ± 0.3) × 10 −3 , respectively. These results yield a very high ratio of 17 for [D 2 O]/[HDO] relative to [HDO]/[H 2 O]. Statistically one would expect just 1/4. Such a high value can be explained by cometary water coming unprocessed from the presolar cloud, where water is formed on grains, leading to high deuterium fractionation. The high [HDS]/[H 2 S] ratio is compatible with upper limits determined in low-mass star-forming regions and also points to a direct correlation of cometary H 2 S with presolar grain surface chemistry. This article is part of the themed issue ‘Cometary science after Rosetta’.

The provenance of water and organic compounds on Earth and other terrestrial planets has been discussed for a long time without reaching a consensus. One of the best means to distinguish between different scenarios is by determining the deuterium-to-hydrogen (D/H) ratios in the reservoirs for comets and Earth’s oceans. Here, we report the direct in situ measurement of the D/H ratio in the Jupiter family comet 67P/Churyumov-Gerasimenko by the ROSINA mass spectrometer aboard the European Space Agency’s Rosetta spacecraft, which is found to be (5.3 ± 0.7) × 10 −4 —that is, approximately three times the terrestrial value. Previous cometary measurements and our new finding suggest a wide range of D/H ratios in the water within Jupiter family objects and preclude the idea that this reservoir is solely composed of Earth ocean–like water.

In situ measurement of O 2 in the coma of comet 67P/Churyumov–Gerasimenko shows local abundances ranging from one per cent to ten per cent relative to H 2 O; the spatial and temporal uniformity of the O 2 /H 2 O ratio suggests that primordial O 2 was incorporated into the nucleus during the comet’s formation. Molecular oxygen on comet 67P Molecular oxygen (O 2 ) has been detected on icy bodies in the Solar System, including the moons of Jupiter and Saturn, but until now it has not been detected in a comet. Andre Bieler et al . report the detection and in situ measurement of O 2 in the coma of 67P/Churyumov–Gerasimenko, made by the Rosetta spacecraft's ROSINA instrument between September 2014 and March 2015. The data reveal local abundances of O 2 between 1% to 10% relative to H 2 O. The O 2 /H 2 O ratio is consistent throughout the coma and does not change systematically with distance from the Sun, suggesting that primordial O 2 was incorporated into the nucleus during the comet's formation. Current Solar System formation models do not predict conditions that would allow this to occur. The composition of the neutral gas comas of most comets is dominated by H 2 O, CO and CO 2 , typically comprising as much as 95 per cent of the total gas density 1 . In addition, cometary comas have been found to contain a rich array of other molecules, including sulfuric compounds and complex hydrocarbons. Molecular oxygen (O 2 ), however, despite its detection on other icy bodies such as the moons of Jupiter and Saturn 2 , 3 , has remained undetected in cometary comas. Here we report in situ measurement of O 2 in the coma of comet 67P/Churyumov–Gerasimenko, with local abundances ranging from one per cent to ten per cent relative to H 2 O and with a mean value of 3.80 ± 0.85 per cent. Our observations indicate that the O 2 /H 2 O ratio is isotropic in the coma and does not change systematically with heliocentric distance. This suggests that primordial O 2 was incorporated into the nucleus during the comet’s formation, which is unexpected given the low upper limits from remote sensing observations 4 . Current Solar System formation models do not predict conditions that would allow this to occur.

Isotopic ratios in comets provide keys for the understanding of the origin of cometary material, and the physical and chemical conditions in the early Solar Nebula. We review here measurements acquired on the D/H, 14 N/ 15 N, 16 O/ 18 O, 12 C/ 13 C, and 32 S/ 34 S ratios in cometary grains and gases, and discuss their cosmogonic implications. The review includes analyses of potential cometary material available in collections on Earth, recent measurements achieved with the Herschel Space Observatory, large optical telescopes, and Rosetta, as well as recent results obtained from models of chemical-dynamical deuterium fractionation in the early solar nebula. Prospects for future measurements are presented.

Comets contain the best-preserved material from the beginning of our planetary system. Their nuclei and comae composition reveal clues about physical and chemical conditions during the early solar system when comets formed. ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) onboard the Rosetta spacecraft has measured the coma composition of comet 67P/Churyumov-Gerasimenko with well-sampled time resolution per rotation. Measurements were made over many comet rotation periods and a wide range of latitudes. These measurements show large fluctuations in composition in a heterogeneous coma that has diurnal and possibly seasonal variations in the major outgassing species: water, carbon monoxide, and carbon dioxide. These results indicate a complex coma-nucleus relationship where seasonal variations may be driven by temperature differences just below the comet surface.

The provenance of water and organic compounds on Earth and other terrestrial planets has been discussed for a long time without reaching a consensus. One of the best means to distinguish between different scenarios is by determining the deuterium-to-hydrogen (D/H) ratios in the reservoirs for comets and Earth's oceans. Here, we report the direct in situ measurement of the D/H ratio in the Jupiter family comet 67P/Churyumov-Gerasimenko by the ROSINA mass spectrometer aboard the European Space Agency's Rosetta spacecraft, which is found to be (5.3 ± 0.7) × 10(-4)—that is, approximately three times the terrestrial value. Previous cometary measurements and our new finding suggest a wide range of D/H ratios in the water within Jupiter family objects and preclude the idea that this reservoir is solely composed of Earth ocean-like water.