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Hybrid solar cells based on 1,2 methanofullerene (C61) capped CdSe and poly (3-hexylthiophene) (P3HT) were been investigated through a range of techniques. High resolution transmission electron microscopy (HRTEM) was used to characterize size, morphology and crystal structure of as-grown and C61-capped CdSe quantum dots. Cross sectional lamellar specimens were prepared from full photovoltaic devices using a focused ion beam milling approach. The sections were analysed by high angle annular dark field imaging in scanning TEM mode to determine the morphology of the device, in particular the intermixing of P3HT and capped quantum dots.

Hybrid solar cells based on 1,2 methanofullerene (C sub(61)) capped CdSe and poly (3-hexylthiophene) (P3HT) were been investigated through a range of techniques. High resolution transmission electron microscopy (HRTEM) was used to characterize size, morphology and crystal structure of as-grown and C sub(61)-capped CdSe quantum dots. Cross sectional lamellar specimens were prepared from full photovoltaic devices using a focused ion beam milling approach. The sections were analysed by high angle annular dark field imaging in scanning TEM mode to determine the morphology of the device, in particular the intermixing of P3HT and capped quantmn dots.

High-resolution near-infrared observations of the Occator bright areas on the dwarf planet Ceres suggest that the bright material is mostly made up of endogenous sodium carbonate. Ceres carbonates catch the eye NASA's Dawn orbiter probe has revealed localized bright areas on the surface of the dwarf asteroid-belt planet Ceres, most prominently in the Occator crater. These features were tentatively interpreted as containing a large amount of hydrated magnesium sulfates. Now Maria Cristina De Sanctis et al . present high-resolution near-infrared spectra of the Occator bright areas that suggest that the bright material consists mostly of endogenous sodium carbonate, mixed with a dark component and small amounts of phyllosilicates, as well as ammonium carbonate or ammonium chloride. The authors propose that these compounds are residues from the crystallization of brines, following upwelling through nearby fracture systems, together with entrained altered solids that reached the surface from below. Such a model requires a heat source, which may have been transient, triggered by impact heating for instance. Alternatively, internal temperatures may be above the eutectic temperature of subsurface brines, in which case fluids may exist at depth on Ceres today. The typically dark surface of the dwarf planet Ceres is punctuated by areas of much higher albedo, most prominently in the Occator crater 1 . These small bright areas have been tentatively interpreted as containing a large amount of hydrated magnesium sulfate 1 , in contrast to the average surface, which is a mixture of low-albedo materials and magnesium phyllosilicates, ammoniated phyllosilicates and carbonates 2 , 3 , 4 . Here we report high spatial and spectral resolution near-infrared observations of the bright areas in the Occator crater on Ceres. Spectra of these bright areas are consistent with a large amount of sodium carbonate, constituting the most concentrated known extraterrestrial occurrence of carbonate on kilometre-wide scales in the Solar System. The carbonates are mixed with a dark component and small amounts of phyllosilicates, as well as ammonium carbonate or ammonium chloride. Some of these compounds have also been detected in the plume of Saturn’s sixth-largest moon Enceladus 5 . The compounds are endogenous and we propose that they are the solid residue of crystallization of brines and entrained altered solids that reached the surface from below. The heat source may have been transient (triggered by impact heating). Alternatively, internal temperatures may be above the eutectic temperature of subsurface brines, in which case fluids may exist at depth on Ceres today.

Infrared spectra of (1) Ceres acquired at distances of 82,000 to 4,300 kilometres from the surface indicate widespread ammoniated phyllosilicates; the presence of ammonia suggests that material from the outer Solar System was incorporated into Ceres. Ammonia compounds on the surface of Ceres The VIR spectrometer onboard NASA's Dawn spacecraft has obtained infrared spectra of the dwarf planet Ceres at distances of 82,000 to 4,300 kilometres and at wavelengths of 0.4–5 μm, including the 2.6–2.9 μm spectral region not accessible to Earth-bound telescopes due to atmospheric absorption. The data indicate the widespread presence of ammoniated phyllosilicates across the asteroid's surface. No water ice could be detected, though small localized occurrences of water ice cannot be excluded. The discovery of ammonia implies that material from the outer Solar System was incorporated into Ceres, either during its formation at great heliocentric distance or by incorporation of material transported into the main asteroid belt. Studies of the dwarf planet (1) Ceres using ground-based and orbiting telescopes have concluded that its closest meteoritic analogues are the volatile-rich CI and CM carbonaceous chondrites 1 , 2 . Water in clay minerals 3 , ammoniated phyllosilicates 4 , or a mixture of Mg(OH) 2 (brucite), Mg 2 CO 3 and iron-rich serpentine 5 , 6 have all been proposed to exist on the surface. In particular, brucite has been suggested from analysis of the mid-infrared spectrum of Ceres 6 . But the lack of spectral data across telluric absorption bands in the wavelength region 2.5 to 2.9 micrometres—where the OH stretching vibration and the H 2 O bending overtone are found—has precluded definitive identifications. In addition, water vapour around Ceres has recently been reported 7 , possibly originating from localized sources. Here we report spectra of Ceres from 0.4 to 5 micrometres acquired at distances from ~82,000 to 4,300 kilometres from the surface. Our measurements indicate widespread ammoniated phyllosilicates across the surface, but no detectable water ice. Ammonia, accreted either as organic matter or as ice, may have reacted with phyllosilicates on Ceres during differentiation. This suggests that material from the outer Solar System was incorporated into Ceres, either during its formation at great heliocentric distance or by incorporation of material transported into the main asteroid belt.

Organic compounds occur in some chondritic meteorites, and their signatures on solar system bodies have been sought for decades. Spectral signatures of organics have not been unambiguously identified on the surfaces of asteroids, whereas they have been detected on cometary nuclei. Data returned by the Visible and InfraRed Mapping Spectrometer on board the Dawn spacecraft show a clear detection of an organic absorption feature at 3.4 micrometers on dwarf planet Ceres. This signature is characteristic of aliphatic organic matter and is mainly localized on a broad region of ~1000 square kilometers close to the ~50-kilometer Ernutet crater. The combined presence on Ceres of ammonia-bearing hydrated minerals, water ice, carbonates, salts, and organic material indicates a very complex chemical environment, suggesting favorable environments to prebiotic chemistry.

Credit: [Mary E. Capria], Pompano Beach {TOPIC} LETTERS TO THE EDITOR

Although olivine was expected to occur within the deep, south-pole basins of asteroid Vesta, which are thought to be excavated mantle rocks, spectral data from NASA’s Dawn spacecraft show that it instead occurs as near-surface materials in Vesta’s northern hemisphere. Surprises in store on Vesta Between July 2011 and September 2012, NASA's Dawn spacecraft was in orbit around the asteroid Vesta. In this paper, Dawn's Visible and Infrared Mapping Spectrometer (VIR) team presents a surprising finding — the signature of olivine on the asteroid's surface. Olivine is a major component of the mantle of differentiated bodies, including Earth. Vesta is a large asteroid, large enough to have differentiated into an Earth-like layered structure and the expectation was that olivine would be found within Vesta's deep, south-pole basins, thought to be excavated mantle rocks. Yet the spectroscopic data reveal olivine-rich material close to the surface in the northern hemisphere. An understanding of the differentiation processes that have occurred on Vesta will be invaluable as a window on the primordial Solar System, but these latest findings show that Vesta's evolutionary history is more complicated than was thought. Olivine is a major component of the mantle of differentiated bodies, including Earth. Howardite, eucrite and diogenite (HED) meteorites represent regolith, basaltic-crust, lower-crust and possibly ultramafic-mantle samples of asteroid Vesta, which is the lone surviving, large, differentiated, basaltic rocky protoplanet in the Solar System 1 . Only a few of these meteorites, the orthopyroxene-rich diogenites, contain olivine, typically with a concentration of less than 25 per cent by volume 2 . Olivine was tentatively identified on Vesta 3 , 4 , on the basis of spectral and colour data, but other observations did not confirm its presence 5 . Here we report that olivine is indeed present locally on Vesta’s surface but that, unexpectedly, it has not been found within the deep, south-pole basins, which are thought to be excavated mantle rocks 6 , 7 , 8 . Instead, it occurs as near-surface materials in the northern hemisphere. Unlike the meteorites, the olivine-rich (more than 50 per cent by volume) material is not associated with diogenite but seems to be mixed with howardite, the most common 7 , 9 surface material. Olivine is exposed in crater walls and in ejecta scattered diffusely over a broad area. The size of the olivine exposures and the absence of associated diogenite favour a mantle source, but the exposures are located far from the deep impact basins. The amount and distribution of observed olivine-rich material suggest a complex evolutionary history for Vesta.

The mineralogy of Vesta, based on data obtained by the Dawn spacecraft's visible and infrared spectrometer, is consistent with howardite-eucrite-diogenite meteorites. There are considerable regional and local variations across the asteroid: Spectrally distinct regions include the south-polar Rheasilvia basin, which displays a higher diogenitic component, and equatorial regions, which show a higher eucritic component. The lithologic distribution indicates a deeper diogenitic crust, exposed after excavation by the impact that formed Rheasilvia, and an upper eucritic crust. Evidence for mineralogical stratigraphic layering is observed on crater walls and in ejecta. This is broadly consistent with magma-ocean models, but spectral variability highlights local variations, which suggests that the crust can be a complex assemblage of eucritic basalts and pyroxene cumulates. Overall, Vesta mineralogy indicates a complex magmatic evolution that led to a differentiated crust and mantle.

The VIRTIS (Visible, Infrared and Thermal Imaging Spectrometer) instrument on board the Rosetta spacecraft has provided evidence of carbon-bearing compounds on the nucleus of the comet 67P/Churyumov-Gerasimenko. The very low reflectance of the nucleus (normal albedo of 0.060 ± 0.003 at 0.55 micrometers), the spectral slopes in visible and infrared ranges (5 to 25 and 1.5 to 5% kÅ −1 ), and the broad absorption feature in the 2.9-to-3.6–micrometer range present across the entire illuminated surface are compatible with opaque minerals associated with nonvolatile organic macromolecular materials: a complex mixture of various types of carbon-hydrogen and/or oxygen-hydrogen chemical groups, with little contribution of nitrogen-hydrogen groups. In active areas, the changes in spectral slope and absorption feature width may suggest small amounts of water-ice. However, no ice-rich patches are observed, indicating a generally dehydrated nature for the surface currently illuminated by the Sun.