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"Chen, Lie"
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Enormous-stiffness-changing polymer networks by glass transition mediated microphase separation
The rapid development of flexible electronics and soft robotics has an urgent demand for materials with wide-range switchable stiffness. Here, we report a polymer network that can isochorically and reversibly switch between soft ionogel and rigid plastic accompanied by a gigantic stiffness change from about 600 Pa to 85 MPa. This transition is realized by introducing polymer vitrification to regulate the liquid–liquid phase separation, namely the Berghmans’ point in the phase diagram of binary gel systems. Regulating the Lewis acid-base interactions between polymer and ionic liquids, the stiffness-changing ratio of polymer network can be tuned from 10 to more than 10
5
. These wide-range stiffness-changing ionogels show excellent shape adaptability and reconfigurability, which can enhance the interfacial adhesion between ionogel and electrode by an order of magnitude and reduce interfacial impedance by 75%.
The development of flexible electronics and soft robotics demands materials with wide-range switchable stiffness. Here, the authors report a polymer network that can isochorically and reversibly switch between a soft ionogel and a rigid plastic accompanied by a large stiffness change.
Journal Article
Recent Progress on the Long‐Term Stability of Perovskite Solar Cells
As rapid progress has been achieved in emerging thin film solar cell technology, organic–inorganic hybrid perovskite solar cells (PVSCs) have aroused many concerns with several desired properties for photovoltaic applications, including large absorption coefficients, excellent carrier mobility, long charge carrier diffusion lengths, low‐cost, and unbelievable progress. Power conversion efficiencies increased from 3.8% in 2009 up to the current world record of 22.1%. However, poor long‐term stability of PVSCs limits the future commercial application. Here, the degradation mechanisms for unstable perovskite materials and their corresponding solar cells are discussed. The strategies for enhancing the stability of perovskite materials and PVSCs are also summarized. This review is expected to provide helpful insights for further enhancing the stability of perovskite materials and PVSCs in this exciting field. Perovskite solar cells have attracted much attention due to their low‐cost fabrication and high efficiency, with a recently recorded power conversion efficiency of 22.1%. However, a crucial challenge for perovskite solar cells is stability. The various external causes of failure, such as moisture, heat, light, etc., and associated mechanisms of perovskite solar cells degradation from two aspects of perovskite layer and device structure are reviewed.
Journal Article
Combined Single‐Cell and Spatial Transcriptomics Reveal the Metabolic Evolvement of Breast Cancer during Early Dissemination
Breast cancer is now the most frequently diagnosed malignancy, and metastasis remains the leading cause of death in breast cancer. However, little is known about the dynamic changes during the evolvement of dissemination. In this study, 65 968 cells from four patients with breast cancer and paired metastatic axillary lymph nodes are profiled using single‐cell RNA sequencing (scRNA‐seq) and spatial transcriptomics. A disseminated cancer cell cluster with high levels of oxidative phosphorylation (OXPHOS), including the upregulation of cytochrome C oxidase subunit 6C and dehydrogenase/reductase 2, is identified. The transition between glycolysis and OXPHOS when dissemination initiates is noticed. Furthermore, this distinct cell cluster is distributed along the tumor's leading edge. The findings here are verified in three different cohorts of breast cancer patients and an external scRNA‐seq dataset, which includes eight patients with breast cancer and paired metastatic axillary lymph nodes. This work describes the dynamic metabolic evolvement of early disseminated breast cancer and reveals a switch between glycolysis and OXPHOS in breast cancer cells as the early event during lymph node metastasis. By single‐cell RNA sequencing and spatial transcriptomics, the early early‐disseminated breast cancer cells are found to travel from the border of primary tumor to axillary lymph nodes. During this metastasis, a switch between glycolysis and oxidative phosphorylation occurs in early disseminated breast cancer cells, indicating an interesting dynamic metabolic evolvement.
Journal Article
Adaptive and freeze-tolerant heteronetwork organohydrogels with enhanced mechanical stability over a wide temperature range
Many biological organisms with exceptional freezing tolerance can resist the damages to cells from extra-/intracellular ice crystals and thus maintain their mechanical stability at subzero temperatures. Inspired by the freezing tolerance mechanisms found in nature, here we report a strategy of combining hydrophilic/oleophilic heteronetworks to produce self-adaptive, freeze-tolerant and mechanically stable organohydrogels. The organohydrogels can simultaneously use water and oil as a dispersion medium, and quickly switch between hydrogel- and organogel-like behaviours in response to the nature of the surrounding phase. Accordingly, their surfaces display unusual adaptive dual superlyophobic in oil/water system (that is, they are superhydrophobic under oil and superoleophobic under water). Moreover, the organogel component can inhibit the ice crystallization of the hydrogel component, thus enhancing the mechanical stability of organohydrogel over a wide temperature range (−78 to 80 °C). The organohydrogels may have promising applications in complex and harsh environments.
Several living organisms can survive subzero temperatures without cell damage. Here, the authors show a heteronetwork organohydrogel with improved elasticity and mechanical features in a wide range of temperatures.
Journal Article
Atmospheric antideuteron flux within a dynamical coalescence approach
A
bstract
Cosmic antideuterons are considered as one of the most promising tools for the indirect detection of dark matter due to their ultra-low astrophysical backgrounds. Currently only upper limits on the antideuteron flux exist, but advancements in experimental detection technology may soon lead to positive signals. A major source of background is the production of secondary antideuterons through collisions of cosmic rays with the surrounding medium. In this study, antideuteron production is modeled using a multiphase transport model (AMPT) coupled with a dynamical coalescence model. By applying a widely used leaky box model and incorporating specific processes, we present a new theoretical baseline for atmospheric secondary antideuteron flux, including a tertiary contribution, from primary cosmic rays interacting with Earth’s atmosphere. Our results indicate that the atmospheric antideuteron flux are within the range of various existing calculations and remain well below the upper limits set by the Balloon-borne Experiment with a Superconducting Spectrometer (BESS). The atmospheric antideuteron is found to dominate the antideuteron background at kinetic energies below 0
.
26 GeV/n.
Journal Article
Oral Contraceptives and Multiple Sclerosis/Clinically Isolated Syndrome Susceptibility
The incidence of multiple sclerosis (MS) is rising in women.
To determine whether the use of combined oral contraceptives (COCs) are associated with MS risk and whether this varies by progestin content.
We conducted a nested case-control study of females ages 14-48 years with incident MS or clinically isolated syndrome (CIS) 2008-2011 from the membership of Kaiser Permanente Southern California. Controls were matched on age, race/ethnicity and membership characteristics. COC use up to ten years prior to symptom onset was obtained from the complete electronic health record.
We identified 400 women with incident MS/CIS and 3904 matched controls. Forty- percent of cases and 32% of controls had used COCs prior to symptom onset. The use of COCs was associated with a slightly increased risk of MS/CIS (adjusted OR = 1.52, 95%CI = 1.21-1.91; p<0.001). This risk did not vary by duration of COC use. The association varied by progestin content being more pronounced for levenorgestrol (adjusted OR = 1.75, 95%CI = 1.29-2.37; p<0.001) than norethindrone (adjusted OR = 1.57, 95%CI = 1.16-2.12; p = 0.003) and absent for the newest progestin, drospirenone (p = 0.95).
Our findings should be interpreted cautiously. While the use of some combination oral contraceptives may contribute to the rising incidence of MS in women, an unmeasured confounder associated with the modern woman's lifestyle is a more likely explanation for this weak association.
Journal Article
Hierarchical structures hydrogel evaporator and superhydrophilic water collect device for efficient solar steam evaporation
Efficient light absorption and trapping are of vital importance for the solar water evaporation by hydrogel-based photothermal conversion materials. Conventional strategies are focused on the development of the composition and structure of the hydrogel's internal network. In our point of view, the importance of the surface structure of hydrogel has usually been underestimated or ignored. Here inspired by the excellent absorbance and water transportation ability of biological surface structure, the hierarchical structured hydrogel evaporators (HSEs) increased the light absorption, trapping, water transportation and water-air interface, which is the beneficial photothermal conversion and water evaporation. The HSEs showed a rapid evaporation rate of 1.77 kg·m
-2
·h
-1
at about 92% energy efficiency under one sun (1 kW·m
-2
). Furthermore, the superhydrophilic window device was used in this work to collect the condensed water, which avoids the light-blocking caused by the water mist formed by the small droplets and the problem of the droplets stick on the device dropping back to the bulk water. Integrated with the excellent photothermal conversion hydrogel and superhydrophilic window equipment, this work provides efficient evaporation and desalination of hydrogel-based solar evaporators in practical large-scale applications.
Journal Article
Petrogenetic relationship between plutonic and subvolcanic rocks in the Jurassic Shuikoushan complex, South China
There has been a longstanding debate on whether plutonic and subvolcanic rocks have a petrogenetic connection, and the Jurassic Shuikoushan caldera complex in South China serves as an ideal case study for unraveling this geological puzzle. SIMS U–Pb dating of zircon indicates the formation age of plutonic (granodiorite) and subvolcanic rocks (dacite porphyry and rhyolite porphyry) from the Shuikoushan caldera complex at
159 Ma. In terms of geochemical composition, granodiorite and dacite porphyry exhibit higher levels of MgO (1.98–3.63%), MnO (0.07–0.11%), FeO
(5.12–6.15%), Sr (342–547 ppm), and Ba (754–1200 ppm) compared to the rhyolite porphyry. Conversely, they show lower concentrations of Rb (2.04–27.1 ppm), as well as lower ratios of Rb/Sr (0.004–0.055) and Rb/Ba (0.004–0.023). The distinct but complementary geochemical characteristics between these rock types are evident in the Shuikoushan caldera complex. Overall, zircon grains from all three rock types exhibit similar negative
) values (–8.1 to –12.4) with high
O values (8.3–9.7‰), suggesting a common source region. Based on lithological and geochemical evidence, it is proposed that the rhyolite porphyry represents extracted melt from the mush reservoir. In contrast, the granodiorite and dacite porphyry are residual melts enriched in cumulates. This interpretation supports the idea that crystal–melt segregation processes were crucial in connecting the late Jurassic subvolcanic and plutonic rocks within the Shuikoushan complex.
Journal Article
Symmetry energy systematics and its high density behavior
We explore the systematics of the density dependence of nuclear matter symmetry energy in the ambit of microscopic calculations with various energy density functionals, and find that the symmetry energy from subsaturation density to supra-saturation density can be well determined by three characteristic parameters of the symmetry energy at saturation density ρ0, i.e., the magnitude Esym(ρ0), the density slope L and the density curvature Ksym. This finding opens a new window to constrain the supra-saturation density behavior of the symmetry energy from its (sub-)saturation density behavior. In particular, we obtain L = 46.7 ± 12.8 MeV and Ksym = −166.9 ± 168.3 MeV as well as Esym(2ρ0) ≈ 40.2 ± 12.8 MeV and L(2ρ0) ≈ 8.9±108.7 MeV based on the present knowledge of Esym(ρ0) = 32.5 ± 0.5 MeV, Esym(ρc) = 26.65±0.2 MeV and L(ρc) = 46.0±4.5 MeV at ρc = 0.11 fm−3 extracted from nuclear mass and the neutron skin thickness of Sn isotopes. Our results indicate that the symmetry energy cannot be stiffer than a linear density dependence. In addition, we also discuss the quark matter symmetry energy since the deconfined quarks could be the right degree of freedom in dense matter at high baryon densities.
Journal Article