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Iron cobalt oxides, such as typical FeCo2O4 and CoFe2O4, are two spinel structured transitional metal oxide materials with excellent electrochemical performance. As the electrodes, they have been widely applied in the current energy storage and conversion processes such as supercapacitors, Lithium-ion batteries and fuel cells. Based on synthesis approaches and controlled conditions, these two materials exhibited broad morphologies and nanostructures and thus distinct electrochemical performance. Some of them have shown promising applications as electrodes in energy storage and conversion. The incorporation with other materials to form composites further improved their performance. This review briefly summarized the recent applications of FeCo2O4 and CoFe2O4 in energy storage and conversion, current understandings on mechanisms and especially the relevance of morphologies and structures and composites to electrochemical performance. Some recommendations were finally put forward addressing current issues and future prospects on electrodes of FeCo2O4 and CoFe2O4 based materials in energy storage and conversion, implying there was still space to further optimize their performance.

A bstract Studies of dark matter lie at the interface of collider physics, astrophysics and cosmology. Constraining models featuring dark matter candidates entails the capability to provide accurate predictions for large sets of observables and compare them to a wide spectrum of data. We present a framework which, starting from a model Lagrangian, allows one to consistently and systematically make predictions, as well as to confront those predictions with a multitude of experimental results. As an application, we consider a class of simplified dark matter models where a scalar mediator couples only to the top quark and a fermionic dark sector (i.e. the simplified top-philic dark matter model). We study in detail the complementarity of relic density, direct/indirect detection and collider searches in constraining the multi-dimensional model parameter space, and efficiently identify regions where individual approaches to dark matter detection provide the most stringent bounds. In the context of collider studies of dark matter, we point out the complementarity of LHC searches in probing different regions of the model parameter space with final states involving top quarks, photons, jets and/or missing energy. Our study of dark matter production at the LHC goes beyond the tree-level approximation and we show examples of how higher-order corrections to dark matter production processes can affect the interpretation of the experimental results.

Increased demand for animal protein is met by increased food animal production resulting in large quantities of manure. Animal producers, therefore, need sustainable agricultural practices to protect environmental health. Large quantities of antimicrobials are used in commercial food animal production. Consequently, antimicrobial-resistant bacteria and the resistance genes emerge and are excreted through feces. Manure management is essential for the safe disposal of animal waste. Lagoons, with or without covers, and anaerobic digesters, with the primary purpose of methane production, and composting, with the primary purpose of producing organic fertilizer, are widely used methods of manure treatment. We reviewed manure management practices and their impact on tetracycline resistance genes. Lagoons are maintained at ambient temperatures; especially uncovered lagoons are the least effective in removing tetracycline resistance genes. However, some modifications can improve the performance of lagoons: sequential use of uncovered lagoons and the use of covered lagoons resulted in a one-log reduction, while post-treatments such as biofiltration following covered lagoon treatment resulted in 3.4 log reduction. Mesophilic digestion of animal manure did not have any significant effect; only a 0.7 log reduction in tet(A) was observed in one study. While thermophilic anaerobic digesters are effective, if properly operated, they are expensive for animal producers. Aerobic thermophilic composting is a promising technology if optimized with its economic benefits. Composting of raw animal manure can result in up to a 2.5 log reduction, and postdigestion composting can reduce tetracycline resistance gene concentration by >80%. In general, manure management was not designed to mitigate antimicrobial resistance; future research is needed to optimize the economic benefits of biogas or organic fertilizer on the one hand and for the mitigation of foodborne pathogens and antimicrobial resistance on the other.

Background Traditional Polynesian medicine for children has been poorly documented, and few data are available on their efficacy and safety. In this context, the aim of this study was to identify traditional practices used for treating children and then assess the efficacy and safety of the most cited remedies by reviewing the literature. Methods In 2022, a semi-structured survey was carried out on five islands from the Society archipelago (Bora Bora, Huahine, Moorea, Raiatea, and Tahiti). A total of 86 participants were interviewed including 19 experts in herbalism. A thorough literature review was performed on the most cited plant species to gather the relevant ethnobotanical, pharmacological, and clinical data of each remedy. Results Participants mentioned using 469 remedies to treat 69 health disorders. The most represented health categories were digestive system, skin disorders, infectious diseases, and respiratory system. A total of 67 plant species (representing 731 use-reports) were mentioned and Annona muricata , Gardenia taitensis , and Hibiscus rosa-sinensis were the main plants reported. Regarding the safety of cited remedies, one plant ( Microsorum grossum ) showed high risk of toxicity, and its use should be avoided in infants and children. Conclusion Our survey confirms the importance of traditional medical practices for children in the Society Islands. A lack of data in children for most cited remedies demonstrate the need for more pharmacological and toxicological research on Polynesian medicinal plants. Finally, the potential risk of toxicity for some cited plant species reported calls for a better information of traditional medicine users and healers.

An increase in the number of independent breweries and distilleries has led to an increase in the amount of spent grains with inadequate means of disposal. One option for disposal is as feedstock for anaerobic digestion if digester stability is ensured. In this study, brewers’ spent grain and distillers’ spent grain were used as substrate for anaerobic digestion for 32 weeks. The digestate was treated by recirculation through a silicone hose located in an external tank filled with saline solution. The hose served as a permeable membrane allowing for the passage of gases. The recirculation tanks were fitted with check valves to maintain three pressure/gas regimes: 26 mm Hg N2, 26 mm Hg aeration or 100 mm Hg aeration. A fourth digester was operated with no recirculation as the control. These treatments were chosen to determine if differences in digester stability, wastewater treatment efficiency, and biogas production could be detected. A combination of dairy and swine manure was used as seeding to provide a methanogenic consortium and bicarbonate buffering. However, despite trying to provide for adequate initial bicarbonate buffering, all four digesters had low initial buffering and consequently low pH as short-chain fatty acids accumulated. After six weeks, bicarbonate buffering and pH increased as methane production increased, and short-chain fatty acids decreased. Later, despite the fluxes of O2 and N2 across the silicone membrane being very low, differences between the various treatments were noted. The pH of the digestate treated by N2 recirculation was lower than the other digesters and decreased further after distillers’ spent grain was substituted for brewers’ spent grain. Aeration at a pressure of 26 mm Hg and 100 mg Hg increased biogas production compared to other treatments but only significantly so at 100 mm Hg. These results suggest that partial purging of dissolved gases in anaerobic digestate by the small fluxes of N2 or O2 across a permeable membrane may affect digester performance.

We discuss the phenomenology associated with a resonant monotop collider signal, i.e. a signal in which a single top quark is resonantly produced in association with missing energy through an s-channel scalar exchange. We study both the bounds originating from dedicated monotop searches performed by the ATLAS and CMS experiments, and the constraints associated with other processes that could be induced by a new physics context favouring monotop production at colliders. The latter class of constraints includes, in particular, the recasting of analyses from the LHC and the TeVatron. All theoretical calculations are performed at the next-to-leading order accuracy in QCD, and we finally combine all results to establish the present limits on the parameter space and test the relevance of the monotop signal at the LHC Run 2.

In the context of prospective studies for searches of new physics at the LHC Run 3, this paper investigates the relevance of using top quarks produced from new long-lived particles, and detected in the tracker volume of the ATLAS and CMS experiments. Such a signature, referred to as displaced top quarks , leads to final states containing displaced vertices and a high multiplicity of displaced jets and tracks, thanks to the top quark decays. Therefore, it is a possible powerful tool for searching for new long-lived particles. Three simplified models based on supersymmetry are explicitly designed for the study of this signature. They differ according to the nature of the long-lived heavy particle which produces at least one top quark: electrically neutral or charged, coloured or non-coloured long-lived particle. For each model, a wide region of parameter space, consistent with a reasonable number of displaced top quarks decaying in a typical tracker volume has been probed. From this study, promising benchmarks are defined and experimental guidelines are suggested.

We present an extension of the expert mode of the MadAnalysis  5 program dedicated to the design or reinterpretation of high-energy physics collider analyses. We detail the predefined classes, functions and methods available to the user and emphasize the most recent developments. The latter include the possible definition of multiple sub-analyses and a novel user-friendly treatment for the selection criteria. We illustrate this approach by two concrete examples: a CMS search for supersymmetric partners of the top quark and a phenomenological analysis targeting hadronically decaying monotop systems.

We measured the perception of competition in the market for essential and orphan drugs. The inflation rate for original products was 0.002 annually, whereas that for generic drugs was 0.005. The province of Panama, containing 46.5 % of private pharmacies, has the lowest index in the perception of competition; 18 % of the respondents to the out-of-pocket expenditure survey did not have drugs available, and 55 % could not afford them. The Gini coefficients were 0.40 (2014) and 0.76 (2017). The increase in prices, the relative independence of retailers to establish prices, and low access to social/private insurance increase the out-of-pocket expenses.

The Atiahara site is the first and only excavated site on Tubuai Island (Austral archipelago, French Polynesia). It was accidently discovered in 1994 and has been excavated on several occasions since then, over a surface of 197 m². This paper aims to present a compilation of the data available from the excavations, with a specific focus on stratigraphy, a spatial analysis of preserved occupations and new radiocarbon dates. We report a short dating sequence running from 1215 to 1390 CE, which makes the Atiahara site one of the earliest settlements in the Austral Islands. Finally, we mention the potential for tackling important topics in Polynesian archaeology through this key site, including the evolution of material culture and fishing strategies, socio-economic dynamics within a central Polynesian domestic context and possible climate variability in the region. Le site d'Atiahara est le premier, et à ce jour le seul, fouillé sur l'île de Tubuai (Archipel des Australes, Polynésie française). Découvert fortuitement en 1994, il a fait l'objet de plusieurs opérations archéologiques, et ce sur 197 m². L'objectif de cet article est de présenter une synthèse des données spatiales et stratigraphiques récoltées au cours des différents terrains, ainsi que les datations radiocarbones effectuées sur des charbons issus des différents niveaux archéologiques. La séquence chronostratigraphique mise en évidence est relativement courte, avec des occupations domestiques datant entre 1215 et 1390 CE, ce qui fait d'Atiahara l'un des plus anciens sites de peuplement connu dans l'archipel des Australes. Nous évoquons les différents aspects qui devront être abordés prochainement à travers l'étude de cet habitat côtier, et notamment les activités artisanales, les stratégies de subsistance, et éventuellement les perturbations du climat au cours de la première moitié du second millénaire de notre ère.