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Surface temperature is a fundamental parameter of Earth’s climate. Its evolution through time is commonly reconstructed using the oxygen isotope and the clumped isotope compositions of carbonate archives. However, reaction kinetics involved in the precipitation of carbonates can introduce inaccuracies in the derived temperatures. Here, we show that dual clumped isotope analyses, i.e., simultaneous ∆ 47 and ∆ 48 measurements on the single carbonate phase, can identify the origin and quantify the extent of these kinetic biases. Our results verify theoretical predictions and evidence that the isotopic disequilibrium commonly observed in speleothems and scleractinian coral skeletons is inherited from the dissolved inorganic carbon pool of their parent solutions. Further, we show that dual clumped isotope thermometry can achieve reliable palaeotemperature reconstructions, devoid of kinetic bias. Analysis of a belemnite rostrum implies that it precipitated near isotopic equilibrium and confirms the warmer-than-present temperatures during the Early Cretaceous at southern high latitudes. Some palaeotemperature proxies suffer from inaccuracies related to kinetic fractionations occurring during carbonate mineral growth. Here, the authors show that dual clumped isotope thermometry can identify the origin of these kinetic biases and allows for the reconstruction of accurate environmental temperatures.

Since the early 1950s, the number of international measurement standards for anchoring stable isotope delta scales has mushroomed from 3 to more than 30, expanding to more than 25 chemical elements. With the development of new instrumentation, along with new and improved measurement procedures for studying naturally occurring isotopic abundance variations in natural and technical samples, the number of internationally distributed, secondary isotopic reference materials has blossomed in the last six decades to more than 150 materials. More than half of these isotopic reference materials were produced for isotope-delta measurements of seven elements: H, Li, B, C, N, O, and S. The number of isotopic reference materials for other, heavier elements has grown considerably over the last decade. Nevertheless, even primary international measurement standards for isotope-delta measurements are still needed for some elements, including Mg, Fe, Te, Sb, Mo, and Ge. It is recommended that authors publish the delta values of internationally distributed, secondary isotopic reference materials that were used for anchoring their measurement results to the respective primary stable isotope scale.

The Commission on Isotopic Abundances and Atomic Weights (ciaaw.org) of the International Union of Pure and Applied Chemistry (iupac.org) has revised the Table of Isotopic Compositions of the Elements (TICE). The update involved a critical evaluation of the recent published literature. The new TICE 2013 includes evaluated data from the “best measurement” of the isotopic abundances in a single sample, along with a set of representative isotopic abundances and uncertainties that accommodate known variations in normal terrestrial materials.

The biennial review of atomic-weight determinations and other cognate data has resulted in changes for the standard atomic weights of 19 elements. The standard atomic weights of four elements have been revised based on recent determinations of isotopic abundances in natural terrestrial materials: cadmium to 112.414(4) from 112.411(8), molybdenum to 95.95(1) from 95.96(2), selenium to 78.971(8) from 78.96(3), and thorium to 232.0377(4) from 232.038 06(2). The Commission on Isotopic Abundances and Atomic Weights (ciaaw.org) also revised the standard atomic weights of fifteen elements based on the 2012 Atomic Mass Evaluation: aluminium (aluminum) to 26.981 5385(7) from 26.981 5386(8), arsenic to 74.921 595(6) from 74.921 60(2), beryllium to 9.012 1831(5) from 9.012 182(3), caesium (cesium) to 132.905 451 96(6) from 132.905 4519(2), cobalt to 58.933 194(4) from 58.933 195(5), fluorine to 18.998 403 163(6) from 18.998 4032(5), gold to 196.966 569(5) from 196.966 569(4), holmium to 164.930 33(2) from 164.930 32(2), manganese to 54.938 044(3) from 54.938 045(5), niobium to 92.906 37(2) from 92.906 38(2), phosphorus to 30.973 761 998(5) from 30.973 762(2), praseodymium to 140.907 66(2) from 140.907 65(2), scandium to 44.955 908(5) from 44.955 912(6), thulium to 168.934 22(2) from 168.934 21(2), and yttrium to 88.905 84(2) from 88.905 85(2). The Commission also recommends the standard value for the natural terrestrial uranium isotope ratio, N(²³⁸U)/N(²³⁵U)=137.8(1).

There are 63 chemical elements that have two or more isotopes that are used to determine their standard atomic weights. The isotopic abundances and atomic weights of these elements can vary in normal materials due to physical and chemical fractionation processes (not due to radioactive decay). These variations are well known for 12 elements (hydrogen, lithium, boron, carbon, nitrogen, oxygen, magnesium, silicon, sulfur, chlorine, bromine, and thallium), and the standard atomic weight of each of these elements is given by IUPAC as an interval with lower and upper bounds. Graphical plots of selected materials and compounds of each of these elements have been published previously. Herein and at the URL , we provide isotopic abundances, isotope-delta values, and atomic weights for each of the upper and lower bounds of these materials and compounds.

The biennial review of atomic-weight determinations and other cognate data has resulted in changes for the standard atomic weights of five elements. The atomic weight of bromine has changed from 79.904(1) to the interval [79.901, 79.907], germanium from 72.63(1) to 72.630(8), indium from 114.818(3) to 114.818(1), magnesium from 24.3050(6) to the interval [24.304, 24.307], and mercury from 200.59(2) to 200.592(3). For bromine and magnesium, assignment of intervals for the new standard atomic weights reflects the common occurrence of variations in the atomic weights of those elements in normal terrestrial materials. © 2013 IUPAC.

Carbonate clumped isotope geochemistry has primarily focused on mass spectrometric determination of m/z 47 CO2 for geothermometry, but theoretical calculations and recent experiments indicate paired analysis of the m/z 47 (13C18O16O) and m/z 48 (12C18O18O) isotopologues (referred to as Δ47 and Δ48) can be used to study non‐equilibrium isotope fractionations and refine temperature estimates. We utilize 5,448 Δ47 and 3,400 Δ48 replicate measurements of carbonate samples and standards, and 183 Δ47 and 195 Δ48 replicate measurements of gas standards from 2015 to 2021 from a multi‐year and multi‐instrument data set to constrain Δ47 and Δ48 values for 27 samples and standards, including Devils Hole cave calcite, and study equilibrium Δ47‐Δ48, Δ47‐temperature, and Δ48‐temperature relationships. We compare results to previously published findings and calculate equilibrium regressions based on data from multiple laboratories. We report acid digestion fractionation factors, Δ*63‐47 and Δ*64‐48, and account for their dependence on the initial clumped isotope values of the mineral. Plain Language Summary A powerful tool for reconstructing past temperatures is based on the extent of carbonate ions in carbonate minerals with more than one heavy isotope substitution, termed carbonate clumped isotope thermometry. The use of the clumped isotope thermometer assumes that the mineral formed under isotopic equilibrium conditions, however, some carbonate minerals do not form at equilibrium. When carbonate minerals do not form at isotopic equilibrium, they are typically not useful for temperature reconstructions. It is now possible to simultaneously determine the extent of heavy isotope substitution in mass 47 and mass 48 CO2 isotopologues from carbonate minerals precipitated at equilibrium. This relationship is useful to identify kinetic effects in sample measurements and recover formation temperature. Here, we use experimental measurements and theory to constrain the equilibrium relationships between heavy isotope substitution in mass 47 and mass 48 CO2 isotopologues, and their relationships to formation temperature. Key Points Reproducible Δ47 and Δ48 values were determined for 27 samples and standards Equilibrium dual clumped isotope relationships and compositionally dependent acid fractionation factors were determined

The IUPAC (International Union of Pure and Applied Chemistry) Periodic Table of the Elements and Isotopes (IPTEI) was created to familiarize students, teachers, and non-professionals with the existence and importance of isotopes of the chemical elements. The IPTEI is modeled on the familiar Periodic Table of the Chemical Elements. The IPTEI is intended to hang on the walls of chemistry laboratories and classrooms. Each cell of the IPTEI provides the chemical name, symbol, atomic number, and standard atomic weight of an element. Color-coded pie charts in each element cell display the stable isotopes and the relatively long-lived radioactive isotopes having characteristic terrestrial isotopic compositions that determine the standard atomic weight of each element. The background color scheme of cells categorizes the 118 elements into four groups: (1) white indicates the element has no standard atomic weight, (2) blue indicates the element has only one isotope that is used to determine its standard atomic weight, which is given as a single value with an uncertainty, (3) yellow indicates the element has two or more isotopes that are used to determine its standard atomic weight, which is given as a single value with an uncertainty, and (4) pink indicates the element has a well-documented variation in its atomic weight, and the standard atomic weight is expressed as an interval. An element-by-element review accompanies the IPTEI and includes a chart of all known stable and radioactive isotopes for each element. Practical applications of isotopic measurements and technologies are included for the following fields: forensic science, geochronology, Earth-system sciences, environmental science, and human health sciences, including medical diagnosis and treatment.

The standard atomic weights of the elements apply to normal materials. Since 1984, the Commission on Isotopic Abundances and Atomic Weights (Commission) has defined a normal material as: The term “a geologically brief period” in this definition is confusing, and confusion can be reduced by revising this definition to the following, which was accepted by the Commission on Isotopic Abundances and Atomic Weights at its meeting in Groningen, Netherlands in September 2017:

During landfall of extratropical cyclones between 2005 and 2011, nearly 1400 precipitation samples were collected at intervals of 30-min time resolution with novel automated collectors at four NOAA sites in northern California [Alta (ATA), Bodega Bay (BBY), Cazadero (CZD) and Shasta Dam (STD)] during 43 events. Substantial decreases were commonly followed hours later by substantial increases in hydrogen isotopic composition (δ 2 H VSMOW where VSMOW is Vienna Standard Mean Ocean Water) and oxygen isotopic composition (δ 18 O VSMOW ) of precipitation. These variations likely occur as pre-cold frontal precipitation generation transitions from marine vapour masses having low rainout to cold cloud layers having much higher rainout (with concomitant brightband signatures measured by an S-band profiling radar and lower δ 2 H VSMOW values of precipitation), and finally to shallower, warmer precipitating clouds having lower rainout (with non-brightband signatures and higher δ 2 H VSMOW values of precipitation), in accord with 'seeder-feeder' precipitation. Of 82 intervals identified, a remarkable 100.5 ‰ decrease in δ 2 H VSMOW value was observed for a 21 January 2010 event at BBY. Of the 61 intervals identified with increases in δ 2 H VSMOW values as precipitation transitioned to shallower, warmer clouds having substantially less rainout (the feeder part of the seeder-feeder mechanism), a remarkable increase in δ 2 H VSMOW value of precipitation of 82.3 ‰ was observed for a 10 February 2007 event at CZD. All CZD and ATA events having δ 2 H VSMOW values of precipitation below −105 ‰ were atmospheric rivers (ARs), and of the 13 events having δ 2 H VSMOW values of precipitation below −80 ‰, 77 % were ARs. Cloud echo-top heights (a proxy for atmospheric temperature) were available for 23 events. The mean echo-top height is greater for higher rainout periods than that for lower rainout periods in 22 of the 23 events. The lowest δ 2 H VSMOW of precipitation of 28 CZD events was −137.9 ‰ on 16 February 2009 during an AR with cold precipitating clouds and very high rainout with tops >6.5 km altitude. An altitude effect of −2.5 ‰ per 100 m was measured from BBY and CZD δ 2 H VSMOW data and of −1.8 ‰ per 100 m for CZD and ATA δ 2 H VSMOW data. We present a new approach to categorise rainfall intervals using δ 2 H VSMOW values of precipitation and rainfall rates. We term this approach the algorithmic-isotopic categorisation of rainfall, and we were able to identify higher rainout and/or lower rainout periods during all events in this study. We conclude that algorithmic-isotopic categorisation of rainfall can enable users to distinguish between tropospheric vapour masses having relatively high rainout (typically with brightband rain and that commonly are ARs) and vapour masses having lower rainout (commonly with non-brightband rain).