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The atmosphere of Mars has been studied for many years now by a long series of missions. The paper focuses on the results obtained by two of these that are led by European researchers overseen by the European Space Agency, i.e., Mars Express which was launched in 2003 and ExoMars Trace Gas Orbiter launched in 2016. Both missions are still providing high-quality data about the atmosphere of Mars, such as abundances of its key species – CO 2 , CO, H 2 O, O 3  - playing an important role in the different cycles existing on the planet, as well as other trace gases – O 2 (mixing ratio of 3.1 to 5.8 × 10 −3 above 90 km), the recently discovered HCl (up to 4 ppbv below 30 km), and the elusive CH 4 (stringent detection limit of 20 pptv). Some instruments are also sensitive enough to provide information on isotopologues of the key elements and have delivered for some of these the first and unique vertical profiles available today ( δ 13 C and δ 18 O in CO 2 and CO, D/H, δ 17 O and δ 18 O in water vapour). The paper retraces the history of the exploration of the Martian atmosphere putting the results from both missions in perspective.

Transit spectroscopy is a powerful tool for probing atmospheric structures of exoplanets. Accurately accounting for the effects of aerosols is key to reconstructing atmospheric properties from transit spectra, yet this remains a significant challenge. To advance this effort, it is invaluable to examine the spectral features of well-characterized planetary atmospheres. Here, we synthesize empirical transit spectra of Mars across different seasons based on data from the NOMAD’s Solar Occultation channel on board ExoMars/TGO, which operates at wavelengths of 0.2–0.65 and 2–4 μm. In the generated empirical transit spectra, the atmosphere below 25 km is found to be largely opaque due to the presence of micron-sized dust and H2O ice clouds, both of which substantially weaken spectral features. The spectra exhibit CO2 absorption features at 2.7–2.8 μm and signatures of submicron-sized mesospheric H2O ice clouds around 3.1 μm, accompanied by a continuum slope. The amplitudes of these spectral features are found to vary with the Martian seasons, where the dust storms weaken the CO2 signatures and strengthen the H2O ice features, which serve as potential indicators of a dusty planet like Mars. If TRAPPIST-1f possessed a Mars-like atmospheric structure, both CO2 and H2O ice features would be detectable at a noise level of 3 ppm, a level likely beyond current observational capabilities. Nevertheless, the 3.1 μm feature produced by submicron-sized mesospheric H2O ice clouds offers a novel avenue for characterizing the atmospheres of habitable-zone exoplanets.

Reports of methane detection in the Martian atmosphere have been intensely debated. The presence of methane could enhance habitability and may even be a signature of life. However, no detection has been confirmed with independent measurements. Here, we report a firm detection of 15.5 ± 2.5 ppb by volume of methane in the Martian atmosphere above Gale Crater on 16 June 2013, by the Planetary Fourier Spectrometer onboard Mars Express, one day after the in situ observation of a methane spike by the Curiosity rover. Methane was not detected in other orbital passages. The detection uses improved observational geometry, as well as more sophisticated data treatment and analysis, and constitutes a contemporaneous, independent detection of methane. We perform ensemble simulations of the Martian atmosphere, using stochastic gas release scenarios to identify a potential source region east of Gale Crater. Our independent geological analysis also points to a source in this region, where faults of Aeolis Mensae may extend into proposed shallow ice of the Medusae Fossae Formation and episodically release gas trapped below or within the ice. Our identification of a probable release location will provide focus for future investigations into the origin of methane on Mars.A methane spike 15.5 ± 2.5 parts per billion by volume was detected in the Martian atmosphere above Gale Crater on 16 June 2013 by Mars Express, independently confirming the debated in situ observation by the Curiosity rover a day earlier.

NOMAD is a suite of spectrometers on the board of the ESA-Roscosmos Trace Gas Orbiter (TGO) spacecraft and is capable of investigating the Martian environment at very high spectral resolution in the ultraviolet–visible and infrared spectral ranges by means of three separate channels: UVIS (0.2–0.65 μm), LNO (2.2–3.8 μm), and SO (2.3–4.3 μm). Among all channels, LNO is the only one operating at infrared wavelengths in nadir-viewing geometry, providing information on the whole atmospheric column and on the surface. Unfortunately, the LNO data are characterized by an overall low level of signal-to-noise ratio (SNR), limiting their contribution to the scientific objectives of the TGO mission. In this study, we assess the possibility of enhancing LNO nadir data SNR by applying the Minimum Noise Fraction (MNF), a well-known algorithm based on the Principal Components technique that has the advantage of providing transform eigenvalues ordered with increasing noise. We set up a benchmark process on an ensemble of synthetic spectra in order to optimize the algorithm specifically for LNO datasets. We verify that this optimization is limited by the presence of spectral artifacts introduced by the MNF itself, and the maximum achievable SNR is dependent on the scientific purpose of the analysis. MNF application study cases are provided to LNO data subsets in the ranges 2.627–2.648 μm and 2.335–2.353 μm (spectral orders 168 and 189, respectively) covering absorption features of gaseous H2O and CO and CO2 ice, achieving a substantial enhancement in the quality of the observations, whose SNR increases up to a factor of 10. While such an enhancement is still not enough to enable the investigation of spectral features of faint trace gases (in any case featured in orders whose spectral calibration is not fully reliable, hence preventing the application of the MNF), interesting perspectives for improving retrieval of both atmospheric and surface features from LNO nadir data are implied.

As part of the payload of the 2016 ExoMars Trace Gas Orbiter (TGO) mission, the Nadir and Occultation for MArs Discovery (NOMAD) suite instrument has been observing the Martian atmosphere since March 2018. NOMAD is mainly dedicated to the study of trace atmospheric species taking advantage of a high-spectral resolution. We demonstrate that when NOMAD is observing in nadir mode, i.e., when the line-of-sight points to the centre of Mars, it can be also exploited to detect ice. In this study we present a method based on the investigation of nadir observations of the NOMAD infrared channel, acquired during Mars Years 34 and 35 (March 2018 to February 2021). We take advantage of the strong water ice absorption band at 2.7 µm by selecting the diffraction orders 167, 168, and 169. We derive the Frost and Clouds Index (FCI), which is a good proxy for ice mapping, and obtain latitudinal-seasonal maps for water ice clouds. FCI is sensitive to the Polar Hood clouds. Nevertheless, detections in the Aphelion Cloud Belt (ACB) are limited. This is consistent with previous observations showing different physical properties between the two main Martian atmospheric structures and making the ACB less detectable in the infrared. We hence derive the infrared nadir channel sensitivity limit for the detection of these clouds.

Mars almost certainly had a considerable amount of water in its past. Recent observations reveal that during southern summer, when the atmosphere is warmer and dustier, water vapor can reach high altitudes without condensing, leading to water loss to space. Here, by combining infrared, visible, and ultraviolet data from multiple Mars orbiters, we identify a new pathway for water loss, observed for the first time to our knowledge during the opposite season. Our findings show that a strong, localized, and short-lived dust storm in Martian Year 37 (August 2023) drove considerable vertical transport of water vapor in the northern summer season. Just days after the storm, enhanced water vapor concentrations were observed at altitudes over 40 km across northern high latitudes, followed by an increase in escaping hydrogen detected at the exobase. These results suggest that water loss on Mars can be triggered by strong local dust storms at any time of year. Observations compiled from several Mars observation missions suggest a significant but short-lived dust storm during the Northern hemisphere summer of Mars Year 37 drove substantial vertical transport of water vapor into the upper atmosphere.

The surname of author Cathy Quantin-Nataf was misspelled 'Quantin-Nata' , authors Ehouarn Millour and Roland Young were missing from the ACS Science Team list, and minor changes have been made to the author and affiliation lists; see accompanying Amendment. These errors have been corrected online.

Global dust storms on Mars are rare.sup.1,2 but can affect the Martian atmosphere for several months. They can cause changes in atmospheric dynamics and inflation of the atmosphere.sup.3, primarily owing to solar heating of the dust.sup.3. In turn, changes in atmospheric dynamics can affect the distribution of atmospheric water vapour, with potential implications for the atmospheric photochemistry and climate on Mars.sup.4. Recent observations of the water vapour abundance in the Martian atmosphere during dust storm conditions revealed a high-altitude increase in atmospheric water vapour that was more pronounced at high northern latitudes.sup.5,6, as well as a decrease in the water column at low latitudes.sup.7,8. Here we present concurrent, high-resolution measurements of dust, water and semiheavy water (HDO) at the onset of a global dust storm, obtained by the NOMAD and ACS instruments onboard the ExoMars Trace Gas Orbiter. We report the vertical distribution of the HDO/H.sub.2O ratio (D/H) from the planetary boundary layer up to an altitude of 80 kilometres. Our findings suggest that before the onset of the dust storm, HDO abundances were reduced to levels below detectability at altitudes above 40 kilometres. This decrease in HDO coincided with the presence of water-ice clouds. During the storm, an increase in the abundance of H.sub.2O and HDO was observed at altitudes between 40 and 80 kilometres. We propose that these increased abundances may be the result of warmer temperatures during the dust storm causing stronger atmospheric circulation and preventing ice cloud formation, which may confine water vapour to lower altitudes through gravitational fall and subsequent sublimation of ice crystals.sup.3. The observed changes in H.sub.2O and HDO abundance occurred within a few days during the development of the dust storm, suggesting a fast impact of dust storms on the Martian atmosphere.

The oxygen emission at 557.7 nm is a ubiquitous component of the spectrum of the terrestrial polar aurora and the reason for its usual green colour 1 . It is also observed as a thin layer of glow surrounding the Earth near 90 km altitude in the dayside atmosphere 2 , 3 but it has so far eluded detection in other planets. Here we report dayglow observations of the green line outside the Earth. They have been performed with the Nadir and Occultation for Mars Discovery ultraviolet and visible spectrometer instrument on board the European Space Agency’s ExoMars Trace Gas Orbiter. Using a special observation mode, scans of the dayside limb provide the altitude distribution of the intensity of the 557.7 nm line and its variability. Two intensity peaks are observed near 80 and 120 km altitude, corresponding to photodissociation of CO 2 by solar Lyman α and extreme ultraviolet radiation, respectively. A weaker emission, originating from the same upper level of the oxygen atom, is observed in the near ultraviolet at 297.2 nm. These simultaneous measurements of both oxygen lines make it possible to directly derive a ratio of 16.5 between the visible and ultraviolet emissions, and thereby clarify a controversy between discordant ab initio calculations and atmospheric measurements that has persisted despite multiple efforts. This ratio is considered a standard for measurements connecting the ultraviolet and visible spectral regions. This result has consequences for the study of auroral and airglow processes and for spectral calibration. The oxygen emission at 557.7 nm, responsible for the green colour of auroras on Earth, is present in two layers at 80 and 120 km altitude on the dayside atmosphere of Mars. Simultaneous observations of the oxygen both in this visible line and in the ultraviolet could also constrain the elusive visible/ultraviolet intensity ratio of the auroral emission to a value of 16.5.

Global dust storms on Mars are rare but can affect the Martian atmosphere for several months. They can cause changes in atmospheric dynamics and inflation of the atmosphere , primarily owing to solar heating of the dust . In turn, changes in atmospheric dynamics can affect the distribution of atmospheric water vapour, with potential implications for the atmospheric photochemistry and climate on Mars . Recent observations of the water vapour abundance in the Martian atmosphere during dust storm conditions revealed a high-altitude increase in atmospheric water vapour that was more pronounced at high northern latitudes , as well as a decrease in the water column at low latitudes . Here we present concurrent, high-resolution measurements of dust, water and semiheavy water (HDO) at the onset of a global dust storm, obtained by the NOMAD and ACS instruments onboard the ExoMars Trace Gas Orbiter. We report the vertical distribution of the HDO/H O ratio (D/H) from the planetary boundary layer up to an altitude of 80 kilometres. Our findings suggest that before the onset of the dust storm, HDO abundances were reduced to levels below detectability at altitudes above 40 kilometres. This decrease in HDO coincided with the presence of water-ice clouds. During the storm, an increase in the abundance of H O and HDO was observed at altitudes between 40 and 80 kilometres. We propose that these increased abundances may be the result of warmer temperatures during the dust storm causing stronger atmospheric circulation and preventing ice cloud formation, which may confine water vapour to lower altitudes through gravitational fall and subsequent sublimation of ice crystals . The observed changes in H O and HDO abundance occurred within a few days during the development of the dust storm, suggesting a fast impact of dust storms on the Martian atmosphere.