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2,840 result(s) for "Davis, Sean"
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Hadley cell expansion in CMIP6 models
In response to increasing greenhouse gases, the subtropical edges of Earth's Hadley circulation shift poleward in global climate models. Recent studies have found that reanalysis trends in the Hadley cell edge over the past 30–40 years are within the range of trends simulated by Coupled Model Intercomparison Project Phase 5 (CMIP5) models and have documented seasonal and hemispheric asymmetries in these trends. In this study, we evaluate whether these conclusions hold for the newest generation of models (CMIP6). Overall, we find similar characteristics of Hadley cell expansion in CMIP5 and CMIP6 models. In both CMIP5 and CMIP6 models, the poleward shift of the Hadley cell edge in response to increasing greenhouse gases is 2–3 times larger in the Southern Hemisphere (SH), except during September–November. The trends from CMIP5 and CMIP6 models agree well with reanalyses, although prescribing observed coupled atmosphere–ocean variability allows the models to better capture reanalysis trends in the Northern Hemisphere (NH). We find two notable differences between CMIP5 and CMIP6 models. First, while both CMIP5 and CMIP6 models contract the NH summertime Hadley circulation equatorward (particularly over the Pacific sector), this contraction is larger in CMIP6 models due to their higher average climate sensitivity. Second, in recent decades, the poleward shift of the NH annual-mean Hadley cell edge is slightly larger in CMIP6 models. Increasing greenhouse gases drive similar trends in CMIP5 and CMIP6 models, so the larger recent NH trends in CMIP6 models point to the role of other forcings, such as aerosols.
Boy dad
Celebrating fathers who raise, love, and uplift little men, this picture book shows how there's nothing a dad won't do for his favorite boy.
RCircos: an R package for Circos 2D track plots
Background Circos is a Perl language based software package for visualizing similarities and differences of genome structure and positional relationships between genomic intervals. Running Circos requires extra data processing procedures to prepare plot data files and configure files from datasets, which limits its capability of integrating directly with other software tools such as R. Recently published R Bioconductor package ggbio provides a function to display genomic data in circular layout based on multiple other packages, which increases its complexity of usage and decreased the flexibility in integrating with other R pipelines. Results We implemented an R package, RCircos, using only R packages that come with R base installation. The package supports Circos 2D data track plots such as scatter, line, histogram, heatmap, tile, connectors, links, and text labels. Each plot is implemented with a specific function and input data for all functions are data frames which can be objects read from text files or generated with other R pipelines. Conclusion RCircos package provides a simple and flexible way to make Circos 2D track plots with R and could be easily integrated into other R data processing and graphic manipulation pipelines for presenting large-scale multi-sample genomic research data. It can also serve as a base tool to generate complex Circos images.
Defective hierarchical porous copper-based metal-organic frameworks synthesised via facile acid etching strategy
Introducing hierarchical pore structure to microporous materials such as metal-organic frameworks (MOFs) can be beneficial for reactions where the rate of reaction is limited by low rates of diffusion or high pressure drop. This advantageous pore structure can be obtained by defect formation, mostly via post-synthetic acid etching, which has been studied extensively on water-stable MOFs. Here we show that a water-unstable HKUST-1 MOF can also be modified in a corresponding manner by using phosphoric acid as a size-selective etching agent and a mixture of dimethyl sulfoxide and methanol as a dilute solvent. Interestingly, we demonstrate that the etching process which is time- and acidity- dependent, can result in formation of defective HKUST-1 with extra interconnected hexagonal macropores without compromising on the bulk crystallinity. These findings suggest an intelligent scalable synthetic method for formation of hierarchical porosity in MOFs that are prone to hydrolysis, for improved molecular accessibility and diffusion for catalysis.
A Multidiagnostic Intercomparison of Tropical-Width Time Series Using Reanalyses and Satellite Observations
Poleward migration of the latitudinal edge of the tropics of 0.25°–3.0° decade−1has been reported in several recent studies based on satellite and radiosonde data and reanalysis output covering the past ∼30 yr. The goal of this paper is to identify the extent to which this large range of trends can be explained by the use of different data sources, time periods, and edge definitions, as well as how the widening varies as a function of hemisphere and season. Toward this end, a suite of tropical edge latitude diagnostics based on tropopause height, winds, precipitation–evaporation, and outgoing longwave radiation (OLR) are analyzed using several reanalyses and satellite datasets. These diagnostics include both previously used definitions and new definitions designed for more robust detection. The wide range of widening trends is shown to be primarily due to the use of different datasets and edge definitions and only secondarily due to varying start–end dates. This study also shows that the large trends (>∼1° decade−1) previously reported in tropopause and OLR diagnostics are due to the use of subjective definitions based on absolute thresholds. Statistically significant Hadley cell expansion based on the mean meridional streamfunction of 1.0°–1.5° decade−1is found in three of four reanalyses that cover the full time period (1979–2009), whereas other diagnostics yield trends of −0.5°–0.8° decade−1that are mostly insignificant. There are indications of hemispheric and seasonal differences in the trends, but the differences are not statistically significant.
Structure-property relationships of a biological mesocrystal in the adult sea urchin spine
Structuring over many length scales is a design strategy widely used in Nature to create materials with unique functional properties. We here present a comprehensive analysis of an adult sea urchin spine, and in revealing a complex, hierarchical structure, show how Nature fabricates a material which diffracts as a single crystal of calcite and yet fractures as a glassy material. Each spine comprises a highly oriented array of Mg-calcite nanocrystals in which amorphous regions and macromolecules are embedded. It is postulated that this mesocrystalline structure forms via the crystallization of a dense array of amorphous calcium carbonate (ACC) precursor particles. A residual surface layer of ACC and/or macromolecules remains around the nanoparticle units which creates the mesocrystal structure and contributes to the conchoidal fracture behavior. Nature's demonstration of how crystallization of an amorphous precursor phase can create a crystalline material with remarkable properties therefore provides inspiration for a novel approach to the design and synthesis of synthetic composite materials.
Re-examining tropical expansion
Observations reveal a poleward expansion of the tropics in recent decades, implying a potential role of human activity. However, although theory and modelling suggest increasing GHG concentrations should widen the tropics, previous observational-based studies depict disparate rates of expansion, including many that are far higher than those simulated by climate models. Here, we review the rates and possible causes of observed and projected tropical widening. By accounting for methodological differences, the tropics are found to have widened about 0.5° of latitude per decade since 1979. However, it is too early to detect robust anthropogenically induced widening imprints due to large internal variability. Future work should target the seasonal and regional signatures of forced widening, as well as the associated dynamical mechanisms.
Shift in cold-point tropopause trends derived from radiosonde, satellite and reanalysis data
The tropical tropopause layer is the transition region between the well-mixed convective troposphere and the radiatively controlled stratosphere and plays a crucial role in air mass transport between these layers. In this paper, we present updated trends of tropopause and lower stratospheric temperature from radiosondes, GNSS-RO data, and the reanalyses ERA5, JRA-3Q and MERRA-2. Given its importance in determining the concentration of water vapour entering the stratosphere, we focus on temperature trends at the cold-point tropopause (CPT), which we determined from radiosonde observations after correcting for time-varying biases. Radiosonde and GNSS-RO data show a significant shift from strong cold-point cooling for 1980–2001 to warming for 2002–2023. Reanalysis datasets reproduce the robust change in the tropical tropopause temperature trends and furthermore show opposite trends in tropical upwelling for 1980–2001 compared to 2002–2023, consistent with the cold-point and lower stratosphere temperature changes. The shift in cold-point temperature trends around 2000 suggests a regime shift in the dominant mechanism controlling CPT temperatures, from ozone-depleting substance-induced dynamical changes before 2000 to greenhouse-gas-induced radiative warming with some dynamical contributions after 2000. While the role of dynamical changes after 2000 is not completely clear, this regime shift suggests that in the absence of strong dynamically induced cooling trends, radiative warming could dominate the cold-point temperature trends and thus stratospheric water vapour entry values.