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We present the analysis of 205 spatially resolved measurements of the surface composition of Mercury from MESSENGER's X‐Ray Spectrometer. The surface footprints of these measurements are categorized according to geological terrain. Northern smooth plains deposits and the plains interior to the Caloris basin differ compositionally from older terrain on Mercury. The older terrain generally has higher Mg/Si, S/Si, and Ca/Si ratios, and a lower Al/Si ratio than the smooth plains. Mercury's surface mineralogy is likely dominated by high‐Mg mafic minerals (e.g., enstatite), plagioclase feldspar, and lesser amounts of Ca, Mg, and/or Fe sulfides (e.g., oldhamite). The compositional difference between the volcanic smooth plains and the older terrain reflects different abundances of these minerals and points to the crystallization of the smooth plains from a more chemically evolved magma source. High‐degree partial melts of enstatite chondrite material provide a generally good compositional and mineralogical match for much of the surface of Mercury. An exception is Fe, for which the low surface abundance on Mercury is still higher than that of melts from enstatite chondrites and may indicate an exogenous contribution from meteoroid impacts. Key Points Analysis of spatially resolved X‐ray spectrometry data from MESSENGER Volcanic smooth plains units differ compositionally from older terrains Mercury's surface consists of high‐Mg mafic minerals, plagioclase, and sulfides

We present an overview of the operations, calibration, geodetic control, photometric standardization, and processing of images from the Mercury Dual Imaging System (MDIS) acquired during the orbital phase of the MESSENGER spacecraft’s mission at Mercury (18 March 2011–30 April 2015). We also provide a summary of all of the MDIS products that are available in NASA’s Planetary Data System (PDS). Updates to the radiometric calibration included slight modification of the frame-transfer smear correction, updates to the flat fields of some wide-angle camera (WAC) filters, a new model for the temperature dependence of narrow-angle camera (NAC) and WAC sensitivity, and an empirical correction for temporal changes in WAC responsivity. Further, efforts to characterize scattered light in the WAC system are described, along with a mosaic-dependent correction for scattered light that was derived for two regional mosaics. Updates to the geometric calibration focused on the focal lengths and distortions of the NAC and all WAC filters, NAC–WAC alignment, and calibration of the MDIS pivot angle and base. Additionally, two control networks were derived so that the majority of MDIS images can be co-registered with sub-pixel accuracy; the larger of the two control networks was also used to create a global digital elevation model. Finally, we describe the image processing and photometric standardization parameters used in the creation of the MDIS advanced products in the PDS, which include seven large-scale mosaics, numerous targeted local mosaics, and a set of digital elevation models ranging in scale from local to global.

MESSENGER observations from Mercury orbit reveal that a large contiguous expanse of smooth plains covers much of Mercury's high northern latitudes and occupies more than 6% of the planet's surface area. These plains are smooth, embay other landforms, are distinct in color, show several flow features, and partially or completely bury impact craters, the sizes of which indicate plains thicknesses of more than 1 kilometer and multiple phases of emplacement. These characteristics, as well as associated features, interpreted to have formed by thermal erosion, indicate emplacement in a flood-basalt style, consistent with x-ray spectrometric data indicating surface compositions intermediate between those of basalts and komatiites. The plains formed after the Caloris impact basin, confirming that volcanism was a globally extensive process in Mercury's post—heavy bombardment era.

A technique for converting gamma‐ray count rates measured by the Gamma‐Ray Spectrometer on the MESSENGER spacecraft to spatially resolved maps of the gamma‐ray emission from the surface of Mercury is utilized to map the surface distributions of the elements Si, O, and K over the planet's northern hemisphere. Conversion of the K gamma‐ray count rates to elemental abundances on the surface reveals variations from 300 to 2400 ppm. A comparison of these abundances with models for the maximum surface temperature suggests the possibility that a temperature‐related process is controlling the K abundances on the surface as well as providing K to the exosphere. The abundances of K and Th have been determined for several geologically distinct regions, including Mercury's northern smooth plains and the plains interior to the Caloris basin. The lack of a significant variation in the measured Th abundances suggests that there may be considerable variability in the K/Th abundance ratio over the mapped regions. Key Points First spatially resolved measurements of Si, O, K, and Th on Mercury K abundances vary significantly across the surface Potassium abundances may be driven by the thermal conditions on the surface

Mapping the distribution and extent of major terrain types on a planet's surface helps to constrain the origin and evolution of its crust. Together, MESSENGER and Mariner 10 observations of Mercury now provide a near-global look at the planet, revealing lateral and vertical heterogeneities in the color and thus composition of Mercury's crust. Smooth plains cover approximately 40% of the surface, and evidence for the volcanic origin of large expanses of plains suggests that a substantial portion of the crust originated volcanically. A low-reflectance, relatively blue component affects at least 15% of the surface and is concentrated in crater and basin ejecta. Its spectral characteristics and likely origin at depth are consistent with its apparent excavation from a lower crust or upper mantle enriched in iron- and titanium-bearing oxides.

Magnetized rocks can record the history of the magnetic field of a planet, a key constraint for understanding its evolution. From orbital vector magnetic field measurements of Mercury taken by the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft at altitudes below 150 kilometers, we have detected remanent magnetization in Mercury's crust. We infer a lower bound on the average age of magnetization of 3.7 to 3.9 billion years. Our findings indicate that a global magnetic field driven by dynamo processes in the fluid outer core operated early in Mercury's history. Ancient field strengths that range from those similar to Mercury's present dipole field to Earth-like values are consistent with the magnetic field observations and with the low iron content of Mercury's crust inferred from MESSENGER elemental composition data.

High-resolution images of Mercury's surface from orbit reveal that many bright deposits within impact craters exhibit fresh-appearing, irregular, shallow, rimless depressions. The depressions, or hollows, range from tens of meters to a few kilometers across, and many have high-reflectance interiors and halos. The host rocks, which are associated with crater central peaks, peak rings, floors, and walls, are interpreted to have been excavated from depth by the crater-forming process. The most likely formation mechanisms for the hollows involve recent loss of volatiles through some combination of sublimation, space weathering, outgassing, or pyroclastic volcanism. These features support the inference that Mercury's interior contains higher abundances of volatile materials than predicted by most scenarios for the formation of the solar system's innermost planet.

On the Moon, extensional tectonic features have only been observed close to the influence of the mare basalt-filled basins and floor-fractured craters. Analysis of Lunar Reconnaissance Orbiter Camera images reveals several potentially very young extensional tectonic features in the farside highlands, implying that extensional stresses may locally exceed compressional ones. Large-scale expressions of lunar tectonics—contractional wrinkle ridges and extensional rilles or graben—are directly related to stresses induced by mare basalt-filled basins 1 , 2 . Basin-related extensional tectonic activity ceased about 3.6 Gyr ago, whereas contractional tectonics continued until about 1.2 Gyr ago 2 . In the lunar highlands, relatively young contractional lobate scarps, less than 1 Gyr in age, were first identified in Apollo-era photographs 3 . However, no evidence of extensional landforms was found beyond the influence of mare basalt-filled basins and floor-fractured craters. Here we identify previously undetected small-scale graben in the farside highlands and in the mare basalts in images from the Lunar Reconnaissance Orbiter Camera. Crosscut impact craters with diameters as small as about 10 m, a lack of superposed craters, and graben depths as shallow as ∼1 m suggest these pristine-appearing graben are less than 50 Myr old. Thus, the young graben indicate recent extensional tectonic activity on the Moon where extensional stresses locally exceeded compressional stresses. We propose that these findings may be inconsistent with a totally molten early Moon, given that thermal history models for this scenario predict a high level of late-stage compressional stress 4 , 5 , 6 that might be expected to completely suppress the formation of graben.

Faustini crater (41 km diameter) hosts a large (664 km2) permanently shadowed region (PSR) with a high potential to harbor water-ice deposits. One of the 13 candidate Artemis III landing areas contains a portion of the crater rim and proximal ejecta. The ShadowCam instrument aboard the Korea Pathfinder Lunar Orbiter provides detailed images of the PSR within Faustini. We characterize the terrain and thermal environment within the Faustini PSR from ShadowCam images, Lunar Reconnaissance Orbiter thermal measurements and laser ranging, and thermal modeling. Our mapping revealed three distinct areas of the floor of Faustini based on elevations, slopes, and surface roughness. These units broadly correlate with temperatures; thus, they may be influenced by variations in volatile sublimation. Crater retention and topographic diffusion rates appear to be asymmetric across the floor, likely due to differences in maximum and average temperatures. Several irregular depressions and a pronounced lobate-rim crater are consistent with subsurface ice. However, differences in the thicknesses of deposited materials on the floor may also explain the asymmetry. Additionally, zones of elevated surface roughness across Faustini appear to result from overprinted crater ray segments, possibly from Tycho and Jackson craters. Mass wasting deposits and pitting on opposite sides of the crater wall may have resulted from the low-angle delivery of material ejected by the Shackleton crater impact event, suggesting that the Artemis III candidate landing region named “Faustini Rim A” will contain material from Shackleton.

During its first two flybys of Mercury, the MESSENGER spacecraft acquired images confirming that pervasive volcanism occurred early in the planet's history. MESSENGER's third Mercury flyby revealed a 290-kilometer-diameter peak-ring impact basin, among the youngest basins yet seen, having an inner floor filled with spectrally distinct smooth plains. These plains are sparsely cratered, postdate the formation of the basin, apparently formed from material that once flowed across the surface, and are therefore interpreted to be volcanic in origin. An irregular depression surrounded by a halo of bright deposits northeast of the basin marks a candidate explosive volcanic vent larger than any previously identified on Mercury. Volcanism on the planet thus spanned a considerable duration, perhaps extending well into the second half of solar system history.