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The theory, applications, strengths and weaknesses of approaches commonly used for measuring trace gas fluxes are reviewed. Chambers, representing the smallest scale (∼1 m2), are the most common tools. Their operating principle is simple, they can be highly sensitive, the cost can be low and field requirements small. Problems include leaks, stickiness of some gases, inhibition of fluxes through concentration build-up, pressure effects and spatial and temporal variability in gas fluxes. Mass balance techniques are suitable for small, defined source areas, typically tens to thousands of square metres in extent. Emissions are calculated from the difference in the rates at which the gas is carried into a control volume above the source area by the wind and carried out. The required primary data are profiles of gas concentration on the downwind boundaries as well as the wind speed profile, the wind direction and the upwind background gas concentration. They have been used to measure gas emissions from landfills, treated fields and small animal herds. Circular test areas make the method independent of wind direction. A newly developed technique based on a backward Lagrangian stochastic dispersion model is also applicable to small, well-defined source areas of any shape. The surface flux is calculated form measurements of atmospheric turbulence and stability and the gas concentration at any height downwind. Implementation of the method is aided greatly by a software package WindTrax. The combination provides a powerful new tool for measuring gas emissions from treated areas and intensive animal production systems. Finally, techniques suitable for measuring gas emissions on large landscape scales (ha) are discussed. Eddy covariance is the micrometeorologist's preferred technique for this scale. The method uses fast response anemometers and gas sensors to make direct measurements of the vertical gas flux at a point, several times a second. However, it is not feasible for many trace gases for a variety of reasons. These are discussed. Relaxed eddy accumulation is an alternative technique that retains the attraction of eddy covariance by providing a direct point measurement. It removes the need for a fast response gas sensor by substituting for it a fast solenoid valve sampling system. Flux–gradient methods are in more common use. Fluxes are calculated as the product of an eddy diffusivity and the vertical concentration gradient of the gas or the product of a transfer coefficient and the difference in gas concentration between two heights. Assumptions of the method and precautions in its application are discussed.

As farmers in southern Australia typically apply nitrogen (N) to cereal crops by top-dressing with ammonia (NH 3 ) based fertilizer in late winter or early spring there is the potential for large losses of NH 3 . This paper describes the results of micrometeorological measurements to determine NH 3 loss and emission factors following applications of urea, urea ammonium nitrate (UAN), and ammonium sulfate (AS) at different rates to cereal crops at two locations in southern Australia. The amounts of NH 3 lost are required for farm economics and management, whilst emission factors are needed for inventory purposes. Ammonia loss varied with fertilizer type (urea > UAN > AS) and location, and ranged from 1.8 to 23 % of N applied. This compares with the emission factor of 10 % of applied N advocated by IPCC ( 2007 ). The variation with location seemed to be due to a combination of factors including soil texture, soil moisture content when fertilizer was applied and rainfall after fertilizer application. Two experiments at one location, 1 week apart, demonstrated how small, temporal differences in weather conditions and initial soil water content affected the magnitude of NH 3 loss. The results of these experiments underline the difficulties farmers face in timing fertilization as the potential for loss, depending on rainfall, can be large.

Received for publication June 26, 2009. Open cattle feedlots are a source of air pollutants that include particular matter (PM). Over 24 h, exposure to ambient concentrations of 50 µg m–3 of the coarse-sized fraction PM (aerodynamic diameter <10 µm [PM10]) is recognized as a health concern for humans. The objective of our study was to document PM10 concentration and emissions at two cattle feedlots in Australia over several days in summer. Two automated samplers were used to monitor the background and in-feedlot PM10 concentrations. At the in-feedlot location, the PM10 emission was calculated using a dispersion model. Our measurements revealed that the 24-h PM10 concentrations on some of the days approached or exceeded the health criteria threshold of 50 µg m–3 used in Australia. A key factor responsible for the generation of PM10 was the increased activity of cattle in the evening that coincided with peak concentrations of PM10 (maximum, 792 µg m–3) between 1930 and 2000 h. Rain coincided with a severe decline in PM10 concentration and emission. A dispersion model used in our study estimated the emission of PM10 between 31 and 60 g animal–1 d–1. These data contribute to needed information on PM10 associated with livestock to develop results-based environmental policy.

Methane (CH4) emissions from animals represent a significant contribution to anthropogenically produced radiatively active trace gases. Global and national CH4 budgets currently use predictive models based on emission data from laboratory experiments to estimate the magnitude of the animal source. This paper presents a method for measuring CH4 from animals under undisturbed field conditions and examines the performance of common models used to simulate field conditions. A micrometeorological mass difference technique was developed to measure CH4 production by cattle in pasture and feedlot conditions. Measurements were made continuously under field conditions, semiautomatically for several days, and the technique was virtually nonintrusive. The method permits a relatively large number of cattle to be sampled. Limitations include light winds (less than approximately 2 m/s), rapid wind direction changes, and high-precision CH4 gas concentration measurement. Methane production showed a marked periodicity, with greater emissions during periods of rumination as opposed to grazing. When the cattle were grazed on pasture, they produced .23 kg CH4 x animal(-1) x d(-1), which corresponded to the conversion of 7.7 to 8.4% of gross energy into CH4. When the same cattle were fed a highly digestible, high-grain diet, they produced .07 kg CH4 x animal(-1) x d(-1), corresponding to a conversion of only 1.9 to 2.2% of the feed energy to CH4. These measurements clearly document higher CH4 production (about four times) for cattle receiving low-quality, high-fiber diets than for cattle fed high-grain diets. The mass difference method provides a useful tool for \"undisturbed\" measurements on the influence of feedstuffs and nutritional management practices on CH4 production from animals and for developing improved management practice for enhanced environmental quality.

The Great Barrier Reef World Heritage Area contains highly sensitive ecosystems that are threatened by the effects of anthropogenic activity including eutrophication. The nearby sugarcane plantations of tropical north Queensland are fertilised annually and there has been ongoing concern about the magnitude of the loss of applied nitrogen to the environment. Previous studies have considered the potential of rainwater run-off to deposit reactive nitrogen species into rivers and ultimately into the Great Barrier Reef Lagoon, but have neglected the possibility of transport via the atmosphere. This paper reports the results of a modelling study commissioned by Australia’s National Heritage Trust aimed at assessing whether or not atmospheric deposition of reactive nitrogen from Queensland’s sugarcane plantations posed a potential threat to the Great Barrier Reef Lagoon. Atmospheric dispersion modelling was undertaken using The Air Pollution Model, developed by Australia’s Commonwealth Scientific and Industrial Research Organisation. Despite the predominance of onshore southeasterly winds, the dispersion model results indicate that 9% of the time during the sugarcane fertilization season (in the modeled years 2001–2006) the meteorological conditions resulted in emissions from the coastal regions of north Queensland being transported out over the ocean around the Great Barrier Reef. The results suggest that there may be a greater efficiency for transport out over the reef during October than for November and December. For the 2 months that exhibited the greatest potential for transport of coastal pollution to the Great Barrier Reef, the modeled deposition of nitrogen oxides (NOX) into the Great Barrier Reef lagoon was less than 1% of the total emissions from the sugarcane plantations, but was not zero. Our model has a simple chemical scheme that does not cover the full chemistry of all reactive nitrogen compounds and so the results are only indicative of the potential levels of deposition. Nevertheless, our study shows that small amounts of NOX that originate from sugarcane fertilization may be transported and dry deposited into the Great Barrier Reef lagoon. Other pathways not included in the modeling scheme may provide a more efficient transport mechanism. Whilst modern practices for the application of fertilizer to sugarcane plantations have drastically reduced emissions, the potential efficiency of transport of pollutants via the atmosphere may be of concern for other more highly polluting agricultural industries.

This paper reports on the fate of nitrogen (N) in a first ratoon sugarcane (Saccharum officinarum L.) crop in the wet tropics of Queensland when urea was either surface applied or drilled into the soil 3–4 days after harvesting the plant cane. Ammonia volatilization was measured with a micrometeorological method, and fertilizer N recovery in plants and soil, to a depth of 140 cm, was determined by mass balance in macroplots with 15N labelled urea 166 and 334 days after fertilizer application. The bulk of the fertilizer and soil N uptake by the sugarcane occurred between fertilizing and the first sampling on day 166. Nitrogen use efficiency measured as the recovery of labelled N in the plant was very low. At the time of the final sampling (day 334), the efficiencies for the surface and subsurface treatments were 18.9% and 28.8%, respectively. The tops, leaves, stalks and roots in the subsurface treatment contained significantly more fertilizer N than the corresponding parts in the surface treatment. The total recoveries of fertilizer N for the plant-trash-soil system on day 334 indicate significant losses of N in both treatments (59.1% and 45.6% of the applied N in the surface and subsurface treatments, respectively). Drilling the urea into the soil instead of applying it to the trash surface reduced ammonia loss from 37.3% to 5.5% of the applied N. Subtracting the data for ammonia loss from total loss suggests that losses by leaching and denitrification combined increased from 21.8% and 40.1% of the applied N as a result of the change in method of application. While the treatment resulted in increased denitrification and/or leaching loss, total N loss was reduced from 59.1% to 45.6%, (a saving of 13.5% of the applied N), which resulted in an extra 9.9%of the applied N being assimilated by the crop.

The paper deals with flux measurements in two contexts: small plots and plant canopies. Mass balance methods have been developed for small experimental plots with lateral dimensions of tens of metres rather than the 1 m typical of chambers or the hundreds of metres required for conventional micrometeorological estimates. The general method relies on the conservation of mass to equate the differences in horizontal fluxes across upwind and downwind boundaries of a test plot with the surface flux within the plot along the line of the wind. Applications to soil and animal experiments are discussed. Lagrangian descriptions of transport now supplant older, but inappropriate gradient-diffusion theory for inferring fluxes and source-sink distributions of scalars in plant canopies. An inverse Lagrangian theory due to M. R. Raupach provides a relatively simple observational and computational scheme for making such inferences from measurements of mean concentration profiles and canopy turbulence. The scheme and a range of applications are described.

This paper introduces the micrometeorological field campaigns known asOASIS (Observations At Several Interacting Scales) and then summarizesseveral companion studies that have used the OASIS dataset. Instrumentedtowers, aircraft and atmospheric sondes were used for measurements overthree paired sites (crops and pastures), approximately equi-spaced along an88-km transect in south-eastern New South Wales, Australia, during the australsprings of 1994 and 1995. Measurements included standard meteorologicaldata and the fluxes of solar and net radiation, sensible heat, water vapour andthe greenhouse gases CO^sub 2^, N^sub 2^O, CH^sub 4^. Descriptions of the site, andthe spatial and temporal variations of climate fields and fluxes, are presented.There were strong contrasts in fluxes and surface conductances, evaporationratios and water use efficiencies between the 1994 drought year and the normalrainfall year of 1995. Despite greater incoming solar radiation in 1994 associatedwith less cloud cover, net radiation was lower than in 1995 because of greateroutgoing thermal radiation caused by higher surface temperatures. In 1994 dailysensible heat fluxes were about 50% higher and evaporation rates about half thosefor 1995. Rainfall in the three-month growing season prior to the field campaignswas the key determinant of leaf area index, surface conductances and the fluxes ofsensible and latent heat and CO^sub 2^. Antecedent rainfall distribution also controlled variation in fluxes and surface properties along the transect within each year. There was a net loss of CO^sub 2^ to the atmosphere at the drier central sites in 1994, and a net uptake at the wetter north-eastern sites. Both sites recorded uptake of CO^sub 2^ in 1995, but values were lower at the central site than at the north-east site due to the strong rainfall gradient along the transect in the three months prior to each fieldcampaign. Differences in fluxes between crops and pastures at each site were smallerthan between sites.[PUBLICATION ABSTRACT]

The paper examines the strengths and weaknesses of a rangeof meteorological flux measurement techniques that mightbe used to verify predictions of greenhouse gas inventories.Recent research into emissions of methane (CH sub(4))produced by enteric fermentation in grazing cattle and sheepis used to illustrate various methodologies. Quantifying thisimportant source presents special difficulties because the animalsconstitute moving, heterogeneously distributed, intermittent, pointsources. There are two general approaches: one, from the bottom up,involves direct measurements of emissions from a known number ofanimals, and the other, from the top down, infers areal emissions ofCH sub(4) from its atmospheric signature. A mass-balance methodproved successful for bottom-up verification. It permits undisturbedgrazing, has a simple theoretical basis and is appropriate for fluxmeasurements on small plots and where there are scattered pointsources. The top-down methodologies include conventional flux-gradientapproaches and convective and nocturnal boundary-layer (CBL and NBL)budgeting schemes. Particular attention is given to CBL budget methods inboth differential and integral form. All top-down methodologies require ideal weather conditions for their application, and they suffer from the scattered nature of the source, varying wind directions and low instrument resolution. As for mass-balance, flux-gradient micrometeorological measurements were in good agreement with inventory predictions of CH sub(4) production by livestock, but the standard errors associated with both methods were too large to permit detection of changes of a few per cent in emission rate, which might be important for inventory, regulatory or research purposes. Fluxes calculated by CBL and NBL methods were of the same order of magnitude as inventory predictions, but more improvement is needed before their use can be endorsed. Opportunities for improving the precision of both bottom-up and top-down methodologies are discussed.

Two methods are examined for combining measurements from instrumented aircraft and towers to estimate regional scale evapotranspiration. Aircraft data provided spatially averaged values of properties of the surface, the evaporative fraction and maximum stomatal conductance. These quantities are less sensitive to meteorological conditions than the turbulent fluxes of heat and water vapour themselves. The methods allowed aircraft data collected over several days to be averaged and thus to reduce the random error associated with the temporal under-sampling inherent in aircraft measurements. Evaporative fraction is estimated directly from the aircraft data, while maximum stomatal conductance is estimated by coupling the Penman-Monteith equation to a simple model relating surface conductance to the incoming shortwave radiation and specific humidity saturation deficit. The spatial averages of evaporative fraction and maximum stomatal conductance can then be used with routine tower data to estimate the regional scale evapotranspiration. Data from aircraft flights and six ground based sites during the OASIS field campaign in south-east New South Wales in 1995 have been used to check the methods. Both the evaporative fraction and the maximum stomatal conductance derived from the aircraft data give information on the spatial variability of the surface energy budget at scales from 10 to 100 km. Daily averaged latent heat fluxes estimated using these methods for the OASIS study region agree with the available observations in quasi-stationary conditions or in weakly non-stationary conditions when the data from several aircraft flights are averaged to reduce the impact of short term imbalances in the surface energy budget.