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The NOMAD (“Nadir and Occultation for MArs Discovery”) spectrometer suite on board the ExoMars Trace Gas Orbiter (TGO) has been designed to investigate the composition of Mars’ atmosphere, with a particular focus on trace gases, clouds and dust. The detection sensitivity for trace gases is considerably improved compared to previous Mars missions, compliant with the science objectives of the TGO mission. This will allow for a major leap in our knowledge and understanding of the Martian atmospheric composition and the related physical and chemical processes. The instrument is a combination of three spectrometers, covering a spectral range from the UV to the mid-IR, and can perform solar occultation, nadir and limb observations. In this paper, we present the science objectives of the instrument and explain the technical principles of the three spectrometers. We also discuss the expected performance of the instrument in terms of spatial and temporal coverage and detection sensitivity.

The oxygen emission at 557.7 nm is a ubiquitous component of the spectrum of the terrestrial polar aurora and the reason for its usual green colour 1 . It is also observed as a thin layer of glow surrounding the Earth near 90 km altitude in the dayside atmosphere 2 , 3 but it has so far eluded detection in other planets. Here we report dayglow observations of the green line outside the Earth. They have been performed with the Nadir and Occultation for Mars Discovery ultraviolet and visible spectrometer instrument on board the European Space Agency’s ExoMars Trace Gas Orbiter. Using a special observation mode, scans of the dayside limb provide the altitude distribution of the intensity of the 557.7 nm line and its variability. Two intensity peaks are observed near 80 and 120 km altitude, corresponding to photodissociation of CO 2 by solar Lyman α and extreme ultraviolet radiation, respectively. A weaker emission, originating from the same upper level of the oxygen atom, is observed in the near ultraviolet at 297.2 nm. These simultaneous measurements of both oxygen lines make it possible to directly derive a ratio of 16.5 between the visible and ultraviolet emissions, and thereby clarify a controversy between discordant ab initio calculations and atmospheric measurements that has persisted despite multiple efforts. This ratio is considered a standard for measurements connecting the ultraviolet and visible spectral regions. This result has consequences for the study of auroral and airglow processes and for spectral calibration. The oxygen emission at 557.7 nm, responsible for the green colour of auroras on Earth, is present in two layers at 80 and 120 km altitude on the dayside atmosphere of Mars. Simultaneous observations of the oxygen both in this visible line and in the ultraviolet could also constrain the elusive visible/ultraviolet intensity ratio of the auroral emission to a value of 16.5.

The NOMAD‐UVIS instrument on board the ExoMars Trace Gas Orbiter has been investigating the Martian atmosphere with the occultation technique since April 2018. Here, we analyze almost two Mars Years of ozone vertical distributions acquired at the day‐night terminator. The ozone retrievals proved more difficult than expected due to spurious detections of ozone caused by instrumental effects, high dust content, and very low values of ozone. This led us to compare the results from three different retrieval approaches: (a) an onion peeling method, (b) a full occultation Optimal Estimation Method, and (c) a direct onion peeling method. The three methods produce consistently similar results, especially where ozone densities are higher. The main challenge was to find reliable criteria to exclude spurious detections of O3, and we finally adopted two criteria for filtering: (a) a detection limit, and (b) the Δχ2 criterion. Both criteria exclude spurious O3 values especially near the perihelion (180° < Ls < 340°), where up to 98% of ozone detections are filtered out, in agreement with general circulation models, that expect very low values of ozone in this season. Our agrees well with published analysis of the NOMAD‐UVIS data set, as we confirm the main features observed previously, that is, the high‐altitude ozone peak around 40 km at high latitudes. The filtering approaches are in good agreement with those implemented for the SPICAM/MEx observations and underline the need to evaluate carefully the quality of ozone retrievals in occultations. Key Points We compare three different retrieval codes and different criteria to filter spurious detection of ozone on Mars The filtering criteria demonstrate the ozone detection in perihelion season is mostly spurious in both years The three retrieval methods produce consistent results with a maximum percentage difference of ∼30% for large ozone densities below 50 km

On Mars, atomic oxygen controls the carbon dioxide radiative cooling of the upper atmosphere and the presence of an ozone layer near the poles. To remotely probe meridional transport of O atoms from the summer to the winter hemisphere and the descending flow in the winter polar regions, the O 2 Herzberg II atmospheric emission could be used as a proxy. This emission is quite weak on Earth’s nightside, but it is prominent in the Venus night airglow, and it has not previously been observed on Mars. Here we report the limb detection of the O 2 Herzberg II visible bands in the Mars nightglow with the NOMAD ultraviolet–visible spectrometer onboard the European Space Agency’s Trace Gas Orbiter. The emission layer reaches up to hundreds of kilorayleighs in the limb viewing geometry. It is mainly located between 40 km and 60 km at high latitudes during the winter season, consistent with three-body recombination of oxygen atoms. This O 2 nightglow should be observable from a Martian orbiter as well as from the Martian surface with the naked eye under clear sky conditions. These observations pave the way to future global observations of the Martian atmospheric circulation with simpler lower-cost instrumentation. ESA’s Trace Gas Orbiter reveals that the winter night sky on Mars emits visible light between 50 km and 70 km altitude in the polar regions. This nightglow should be observable with simple space camera systems and the naked eyes of future Mars astronauts.

The detection of methane on Mars has been interpreted as indicating that geochemical or biotic activities could persist on Mars today. A number of different measurements of methane show evidence of transient, locally elevated methane concentrations and seasonal variations in background methane concentrations. These measurements, however, are difficult to reconcile with our current understanding of the chemistry and physics of the Martian atmosphere, which—given methane’s lifetime of several centuries—predicts an even, well mixed distribution of methane. Here we report highly sensitive measurements of the atmosphere of Mars in an attempt to detect methane, using the ACS and NOMAD instruments onboard the ESA-Roscosmos ExoMars Trace Gas Orbiter from April to August 2018. We did not detect any methane over a range of latitudes in both hemispheres, obtaining an upper limit for methane of about 0.05 parts per billion by volume, which is 10 to 100 times lower than previously reported positive detections. We suggest that reconciliation between the present findings and the background methane concentrations found in the Gale crater would require an unknown process that can rapidly remove or sequester methane from the lower atmosphere before it spreads globally.

The surname of author Cathy Quantin-Nataf was misspelled ‘Quantin-Nata’, authors Ehouarn Millour and Roland Young were missing from the ACS and NOMAD Science Teams list, and minor changes have been made to the author and affiliation lists; see accompanying Amendment. These errors have been corrected online. © 2019, The Author(s), under exclusive licence to Springer Nature Limited.

Global dust storms on Mars are rare but can affect the Martian atmosphere for several months. They can cause changes in atmospheric dynamics and inflation of the atmosphere , primarily owing to solar heating of the dust . In turn, changes in atmospheric dynamics can affect the distribution of atmospheric water vapour, with potential implications for the atmospheric photochemistry and climate on Mars . Recent observations of the water vapour abundance in the Martian atmosphere during dust storm conditions revealed a high-altitude increase in atmospheric water vapour that was more pronounced at high northern latitudes , as well as a decrease in the water column at low latitudes . Here we present concurrent, high-resolution measurements of dust, water and semiheavy water (HDO) at the onset of a global dust storm, obtained by the NOMAD and ACS instruments onboard the ExoMars Trace Gas Orbiter. We report the vertical distribution of the HDO/H O ratio (D/H) from the planetary boundary layer up to an altitude of 80 kilometres. Our findings suggest that before the onset of the dust storm, HDO abundances were reduced to levels below detectability at altitudes above 40 kilometres. This decrease in HDO coincided with the presence of water-ice clouds. During the storm, an increase in the abundance of H O and HDO was observed at altitudes between 40 and 80 kilometres. We propose that these increased abundances may be the result of warmer temperatures during the dust storm causing stronger atmospheric circulation and preventing ice cloud formation, which may confine water vapour to lower altitudes through gravitational fall and subsequent sublimation of ice crystals . The observed changes in H O and HDO abundance occurred within a few days during the development of the dust storm, suggesting a fast impact of dust storms on the Martian atmosphere.

The surname of author Cathy Quantin-Nataf was misspelled ‘Quantin-Nata’ , authors Ehouarn Millour and Roland Young were missing from the ACS Science Team list, and minor changes have been made to the author and affiliation lists; see accompanying Amendment. These errors have been corrected online. © 2019, The Author(s), under exclusive licence to Springer Nature Limited.