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17
result(s) for
"Dhananjayan, V."
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Organochlorine Pesticides and Polychlorinated Biphenyls in Various Tissues of Waterbirds in Nalabana Bird Sanctuary, Chilika Lake, Orissa, India
2012
In order to understand whether organochlorine pesticides and polychlorinated biphenyls (PCBs) are responsible for the mortality of waterbirds in Nalaban bird sanctuary in Chilika Lake, the current investigation was carried out in tissues of 11 individuals comprising 7 species of birds. One or more residues were detected in all the tissues of birds analysed. Concentration of ∑HCH, ∑DDT, and ∑PCBs were ranged from below detectable level (BDL)-811 ng/g, BDL-1,987 ng/g and BDL-1,027 ng/g respectively. PCBs levels were less than the food and drug administration’s (FDA) action limits. Although varying levels of residues were detected among tissues, they do not appear to be responsible for the mass mortality of waterfowl. However, the need for additional research is heightened when considering that some of the birds are classified as a globally protected species by the international bodies.
Journal Article
Spatio-seasonal variation in ambient air pollutants and influence of meteorological factors in Coimbatore, Southern India
by
Dhananjayan, V
,
Kalaiselvi, K
,
Banupriya, G S
in
Air pollution
,
Air pollution control
,
Air pollution measurements
2018
Air quality is used worldwide to confirm the current status of air pollution level and associated health risks to the public. Several air pollutants reach very high concentrations in many regions across India. In this study, air pollutants were measured in an urban city of Coimbatore, Tamil Nadu, Southern India, during 2013 to 2014 based on season and location, and the influence of meteorological factors. Air pollutants (PM10, PM2.5, SO2, NO2, CO, and O3) across eight locations including industrial, residential, traffic, and commercial areas were assessed. The results showed that PM10, PM2.5, and CO were the most serious pollutants and their average concentrations ranged from 65.5 to 98.6 μg/m3, 27.6 to 56.9 μg/m3, and 1.58 to 8.21 mg/m3, respectively, among various locations. Significantly higher concentration of air pollutants was recorded in industrial areas followed by traffic and commercial areas. Comparatively higher mean concentration of O3 (2.22 ± 0.75 μg/m3) and CO (7.73 ± 1.86 mg/m3) was recorded during the summer season, whereas the concentration of PM10 (80.3 ± 24.4 μg/m3), PM2.5 (45.1 ± 17.7 μg/m3), SO2 (7.86 ± 1.55 μg/m3), and NO2 (13 ± 1.81 μg/m3) was higher in southwest monsoon. Ozone (O3) and CO positively correlated with temperature and negatively correlated with relative humidity. The level of PM10, PM2.5, and CO concentrations exceeded the National Ambient Air Quality Standards (NAAQS) guidelines. The present study’s results emphasize the need of effective air pollution control in Coimbatore. Precautionary measures to be taken to avoid exposure of air pollutants to the public and minimize pollutants. This study further suggests an investigation on the adverse impact on human health and environment using appropriate risk analysis techniques.
Journal Article
Assessment of Particulate and Gaseous Fluoride in Phosphate Fertilizer Industry
by
Nath, A. Ravinder
,
Rao, Nirmala Babu
,
Dhananjayan, V.
in
Agricultural production
,
Cellulose
,
Dust
2023
Fluorides are emitted in both gaseous and particle forms in the industrial sector. However, studies usually only report total fluoride content. Therefore, the study aimed to assess the particulate, gaseous fluoride and correlate it with the respirable dust particles in Single Super Phosphate (SSP), Granular Single Super Phosphate (GSSP), and administration divisions of the industry. Respirable dust particles, particulate fluoride, and hydrogen fluoride in the work environment were collected on a filter cassette containing an MCE filter paper (0.8 micron 37-mm) and Na2CO3 impregnated backup pad, respectively, using a personal sampler. The fluoride samples were analyzed using Ion Selective Electrode (ISE) and expressed as milligrams per meter cube (mg.m-3). The respirable dust, particulate, and gaseous fluoride content were found to have statistically significant differences (p<0.001) between the divisions (SSP, GSSP, and administration) in the static monitoring, whereas, in the case of personal monitoring, no significant differences were observed. Average airborne respirable, particulate, and gaseous fluoride levels in static monitoring were 1.37, 1.03, 0.20 mg.m-3, 0.018, 0.008, 0.001 mg.m-3, and 0.808, 0.403, 0.026 ppm in SSP, GSSP and administration respectively, whereas in personal monitoring the average respirable, particulate and gaseous fluoride concentrations were 1.18, 0.85, 0.30 mg.m-3, 0.0013, 0.007, 0.002 mg.m-3 and 0.356, 0.258, 0.011 ppm in SSP, GSSP and administration respectively. The present study observed that the levels of fluoride decreased with an increase in distance from SSP, followed by GSSP and administration. It indicates that the fluoride exposure was inversely proportional to the distance of the source. This study outcome will help to design a policy and intervention to mitigate fluoride exposure among workers.
Journal Article
Levels of Polycyclic Aromatic Hydrocarbons, Polychlorinated Biphenyls, and Organochlorine Pesticides in Various Tissues of White-Backed Vulture in India
2013
This study provides information on the current status of contamination by polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs) in the tissues of endangered White-backed Vulture Gyps bengalensis in India. Chemical analyses revealed detectable amounts of PAHs, PCBs, and OCPs. Concentration ranges of ∑PAHs, ∑PCBs, and ∑OCPs in tissues were 60–2037 ng/g, 30–5790 ng/g, and 3.2–5836 ng/g wet weight, respectively. 1,1-Dichloro-2,2-bis(p-chlorophenyl)ethylene (p,p′-DDE) concentrations ranged from below detectable level to 599 ng/g wet weight, representing more than 90% of the total dichlorodiphenyltrichloroethane (DDT). Among the various OCPs analyzed, p,p′-DDE was detected most frequently. All the contaminants recorded show higher accumulation in liver than other tissues. Levels of contaminants measured in the tissues of vulture are comparable with the levels documented in a number of avian species and are lower than those reported to have caused deleterious effects. Although no threat is expected from the current level of contamination, the presence of varying levels of contaminants and their additive or synergistic toxicity is a cause of concern to vultures. Values reported in this study can serve as guideline for future research.
Journal Article
Organochlorine Pesticide Residues in Blood Samples of Agriculture and Sheep Wool Workers in Bangalore (Rural), India
by
Dhananjayan, V.
,
Rajmohan, H. R.
,
Ravichandran, B.
in
Adult
,
adulterated products
,
Agriculture
2012
To describe exposure level of organochlorine pesticides (OCP) among workers occupationally engaged in agriculture and sheep wool associated jobs, the present study was carried out in rural neighborhood of Bangalore city, India. Thirty participants were interviewed and obtained informed consent before blood sample collection. The maximum concentrations of OCP were detected in blood samples of agriculture workers than sheep wool workers. Among the metabolites of HCH and DDT, lindane (γ-HCH) and
p,p’
-DDE were the most contributed to the total OCP. There were no differences in pesticide residues found between sex and work groups. It was observed that about 30% of samples exceeded the tolerance limits of 10 μg/L prescribed for HCH under the prevention of food adulteration act. Therefore, the present study recommends continuous monitoring with larger sample size.
Journal Article
Diclofenac Residues in Blood Plasma and Tissues of Vultures Collected from Ahmedabad, India
by
Dhananjayan, V
,
Muralidharan, S
in
Animals
,
Anti-inflammatory agents
,
Anti-Inflammatory Agents, Non-Steroidal
2010
The study reports residues of diclofenac, a non-steroidal anti inflammatory drug, in tissues of 11 White-backed Vulture, Gyps bengalensis collected between 2005 and 2007 and blood plasma of 12 White-backed Vulture, four Egyptian Vulture, Neophron percnopterus and two Griffon Vulture, Gyps fulvus collected during 2005. Samples were analysed using High Performance Liquid Chromatograhy (HPLC) equipped with UV detector. One of the White-backed Vultures collected during 2005 had substantial urate deposits on its viscera and diclofenac was detected in its liver (1.42 ppm wet weight) and kidney (1.18 ppm wet weight), which is suggestive of diclofenac exposure and intoxication. Although uric acid crystals were not observed in the remaining birds received during 2005, the residues of diclofenac detected were at levels higher than the toxic limits (0.25-1 ppm). No residues were detected in any of the tissues of birds collected during 2006 and 2007 (6 birds). About 89% (16 of 18) of plasma samples collected during 2005 had diclofenac residues (White-backed vulture: BDL to 0.17 ppm; Egyptian vulture: BDL to 0.09 ppm; Griffon vulture: 0.07-0.14 ppm). However, plasma diclofenac concentrations were less than the concentrations reported to be toxic. Although use of diclofenac for treating cattle has been banned in India, regular monitoring is recommended to assess the effectiveness of the ban on the drug in support of the conservation of these species.
Journal Article
Organochlorine Pesticide Residues in Eggs and Tissues of House Sparrow, Passer domesticus, from Tamil Nadu, India
2011
This study provides information on the current status of contamination by organochlorine pesticides (OCPs) in eggs and tissues of House Sparrow,
Passer domesticus
, in Tamil Nadu, India. The mean concentration of total hexachlorocyclohexane (∑HCH) and total dichloro-diphenyl-trichloroethane (∑DDT) in eggs ranged from 0.01 to 1.81 μg/g and 0.02 to 1.29 μg/g, respectively. Concentration of 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (
p,p′
-DDE) ranged from below detectable limit (BDL) to 0.64 μg/g, representing more than 60% of the ∑DDTs. About 28% of samples had
p,p′
-DDE levels above the critical concentration associated with reproductive impairment. However, the mean concentrations of cyclodiene insecticides were less than 0.5 μg/g
.
Although OCPs levels detected in tissues are not indicative of toxicity, continuous monitoring is recommended.
Journal Article
Assessment of acetylcholinesterase and butyrylcholinesterase activities in blood plasma of agriculture workers
2012
Background: Cholinesterase determination indicates whether the person has been under pesticide exposure is not. It is recommended that the worker′s cholinesterase level should be assessed for workers at a pesticide applied region. Hence, cholinesterase activities in blood samples of agricultural workers exposed to vegetables and grape cultivation with age matched, unexposed workers, who never had any exposure to pesticides, were estimated. Methods: The detailed occupational history and lifestyle characters were obtained by questionnaire. Cholinesterase activity was determined by the method of Ellman as modified by Chambers and Chambers. Results: AChE was ranging from 1.65 to 3.54μmoles/min/ml in exposed subjects where as it was ranged from 2.22 to 3.51μmoles/min/ml in control subjects. BChE activity was ranging from 0.16 to 5.2μmoles/min/ml among exposed subjects, where as it was ranged from 2.19 to 5.06μmoles/min/ml in control subjects. The results showed statistically significant reduction in enzyme activities (AChE 14%; BChE 56%) among exposed subjects. Conclusion: It was concluded that the reduction in cholinesterase activity may lead to varieties of effects. Hence it is compulsory to use protective gadgets during pesticide spray. Further a continuous biomonitoring study is recommended to assess pesticide exposure.
Journal Article
Persistent Organochlorine Pesticide Residues in Tissues and Eggs of White-Backed Vulture, Gyps bengalensis from Different Locations in India
2008
Organochlorine pesticide residues were determined in tissues of five Indian white-backed vultures and two of their eggs collected from different locations in India. All the samples had varying levels of residues. p,p'-DDE ranged between 0.002 μg/g in muscle of vulture from Mudumali and 7.30 μg/g in liver of vulture from Delhi. Relatively higher levels of p,p'-DDT and its metabolites were documented in the bird from Delhi than other places. Dieldrin was 0.003 and 0.015 μg/g while p,p'-DDE was 2.46 and 3.26 μg/g in egg one and two respectively. Dieldrin appeared to be lower than the threshold level of 0.5 μg/g. p,p'-DDE exceeded the levels reported to have created toxic effects in eggs of other wild birds. Although varying levels of DDT, HCH, dieldrin, heptachlor epoxide and endosulfan residues were detected in the vulture tissues, they do not appear to be responsible for the present status of population in India.
Journal Article
Polycyclic Aromatic Hydrocarbons in Various Species of Fishes from Mumbai Harbour, India, and Their Dietary Intake Concentration to Human
2012
Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental contaminants which have caused worldwide concerns as toxic pollutant. This study reports the concentrations of 15 PAHs in 5 species of fish samples collected along the harbour line, Mumbai, between 2006 and 2008. Among 5 species of fish investigated, Mandeli, Coilia dussimieri, detected the maximum concentration of PAHs (P<0.05) followed by Doma, Otolithes ruber. The concentration of total and carcinogenic PAHs ranged from 17.43 to 70.44 ng/g wet wt. and 9.49 to 31.23 ng/g wet wt, respectively, among the species tested. The lower-molecular-weight PAHs were detected at highest levels. Estimated intakes of PAHs by fish consumption for the general population were ranged between 1.77 and 10.70 ng/kg body weight/day. Mandeli contributed to the highest intakes of PAHs. The toxic equivalents (TEQs) of PAHs were calculated using a TEQ proposed in literature, and the intake ranged from 8.39 to 15.78 pg TEQ/kg body weight/d. The estimated excess cancer risk value (2.37×10−7–1.43×10−6) from fish consumption for the general population exceeded the guideline value (1.0 × 10−6) for potential cancer risk.
Journal Article