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Electrolyte solutions with high concentrations of ions are prevalent in biological systems and energy storage technologies. Nevertheless, the high interaction free energy and long-range nature of electrostatic interactions makes the development of a general conceptual picture of concentrated electrolytes a significant challenge. In this work, we study ionic liquids, single-component liquids composed solely of ions, in an attempt to provide a novel perspective on electrostatic screening in very high concentration (nonideal) electrolytes. We use temperature-dependent surface force measurements to demonstrate that the long-range, exponentially decaying diffuse double-layer forces observed across ionic liquids exhibit a pronounced temperature dependence: Increasing the temperature decreases the measured exponential (Debye) decay length, implying an increase in the thermally driven effective free-ion concentration in the bulk ionic liquids. We use our quantitative results to propose a general model of long-range electrostatic screening in ionic liquids, where thermally activated charge fluctuations, either free ions or correlated domains (quasiparticles), take on the role of ions in traditional dilute electrolyte solutions. This picture represents a crucial step toward resolving several inconsistencies surrounding electrostatic screening and charge transport in ionic liquids that have impeded progress within the interdisciplinary ionic liquids community. More broadly, our work provides a previously unidentified way of envisioning highly concentrated electrolytes, with implications for diverse areas of inquiry, ranging from designing electrochemical devices to rationalizing electrostatic interactions in biological systems. Significance Liquid solutions with high concentrations of electrically charged ions are key elements of many energy storage technologies and are prevalent in biology. Nevertheless, they remain poorly understood. We study ionic liquids—liquids composed solely of ions—with the goal of providing a general picture of concentrated ionic solutions. Using molecular-scale experiments, we show that, surprisingly, less than 0.1% of the ions in ionic liquids are “free” to contribute to electrostatic screening, with the remainder “stuck” as neutral aggregates. Our temperature-dependent results provide fundamental guidance for designing high-performance ionic liquids for numerous applications. More broadly, we provide a novel way of envisioning concentrated ionic solutions with wide-ranging implications, such as elucidating the nanoscale properties of underwater bioadhesives and other self-assembled biomolecules.

An in-depth knowledge of the interaction of water with amorphous silica is critical to fundamental studies of interfacial hydration water, as well as to industrial processes such as catalysis, nanofabrication, and chromatography. Silica has a tunable surface comprising hydrophilic silanol groups and moderately hydrophobic siloxane groups that can be interchanged through thermal and chemical treatments. Despite extensive studies of silica surfaces, the influence of surface hydrophilicity and chemical topology on the molecular properties of interfacial water is not well understood. In this work, we controllably altered the surface silanol density, and measured surface water diffusivity using Overhauser dynamic nuclear polarization (ODNP) and complementary silica–silica interaction forces acrosswater using a surface forces apparatus (SFA). The results show that increased silanol density generally leads to slower water diffusivity and stronger silica–silica repulsion at short aqueous separations (less than ∼4 nm). Both techniques show sharp changes in hydration properties at intermediate silanol densities (2.0–2.9 nm−2). Molecular dynamics simulations of model silica–water interfaces corroborate the increase in water diffusivity with silanol density, and furthermore show that even on a smooth and crystalline surface at a fixed silanol density, adjusting the spatial distribution of silanols results in a range of surface water diffusivities spanning ∼10%. We speculate that a critical silanol cluster size or connectivity parameter could explain the sharp transition in our results, and can modulate wettability, colloidal interactions, and surface reactions, and thus is a phenomenon worth further investigation on silica and chemically heterogeneous surfaces.

Non-aqueous lithium–air batteries represent the next-generation energy storage devices with very high theoretical capacity. The benefit of lithium–air batteries is based on the assumption that the anodic lithium is completely reversible during the discharge–charge process. Here we report our investigation on the reversibility of the anodic lithium inside of an operating lithium–air battery using spatially and temporally resolved synchrotron X-ray diffraction and three-dimensional micro-tomography technique. A combined electrochemical process is found, consisting of a partial recovery of lithium metal during the charging cycle and a constant accumulation of lithium hydroxide under both charging and discharging conditions. A lithium hydroxide layer forms on the anode separating the lithium metal from the separator. However, numerous microscopic ‘tunnels’ are also found within the hydroxide layer that provide a pathway to connect the metallic lithium with the electrolyte, enabling sustained ion-transport and battery operation until the total consumption of lithium. Lithium–oxygen batteries are expected to have high-energy density, assuming that anodic lithium is fully reversible upon cycling. Shui et al . disprove this assumption by monitoring the changes of anode composition and morphology, and reveal the loss mechanism and transport paths of lithium ions.

The South Pole Telescope Summertime Line Intensity Mapper (SPT-SLIM) is a pathfinder experiment that will demonstrate the use of on-chip filter-bank spectrometers for mm-wave line intensity mapping. The SPT-SLIM focal plane consists of 18 dual-polarization filter-bank spectrometers covering 120–180 GHz with resolving power of 300, coupled to aluminum kinetic inductance detectors. A compact cryostat holds the detectors at 100 mK. SPT-SLIM will be deployed to the 10-m South Pole Telescope for observations during the 2023–2024 austral summer without removing the primary receiver. We discuss the overall instrument design, expected detector performance, and sensitivity to the carbon monoxide line signal at 0.5 < z < 2 . The technology and observational techniques demonstrated by SPT-SLIM will enable next-generation line intensity mapping experiments that constrain cosmology beyond the redshift reach of galaxy surveys.

The South Pole Telescope (SPT) is a 10 m diameter, wide-field, offset Gregorian telescope with a 966 pixel, multicolor, millimeter-wave, bolometer camera. It is located at the Amundsen-Scott South Pole station in Antarctica. The design of the SPT emphasizes careful control of spillover and scattering, to minimize noise and false signals due to ground pickup. The key initial project is a large-area survey at wavelengths of 3, 2, and 1.3 mm, to detect clusters of galaxies via the Sunyaev-Zel’dovich effect and to measure the small-scale angular power spectrum of the cosmic microwave background (CMB). The data will be used to characterize the primordial matter power spectrum and to place constraints on the equation of state of dark energy. A second-generation camera will measure the polarization of the CMB, potentially leading to constraints on the neutrino mass and the energy scale of inflation.

Muon beams of low emittance provide the basis for the intense, well characterised neutrino beams for a Neutrino Factory and for lepton-antilepton collisions at energies of up to several TeV at a Muon Collider. The international Muon Ionization Cooling Experiment (MICE) will demonstrate ionization cooling, the technique by which it is proposed to reduce the phase-space volume occupied by the muon beam. MICE is being constructed in a series of Steps. The configuration currently in operation at the Rutherford Appleton Laboratory is optimised for the study of the properties of liquid hydrogen and lithium hydride that affect cooling. The plans for data taking in the present configuration will be described together with some preliminary results. A description of the next experimental configuration, used for the final cooling demonstration, is also presented.

The Muon Ionization Cooling Experiment (MICE) is a proof-of-principle experiment designed to demonstrate muon ionization cooling for the first time. MICE is currently on Step IV of its data taking programme, where transverse emittance reduction will be demonstrated. The MICE Analysis User Software (MAUS) is the reconstruction, simulation and analysis framework for the MICE experiment. MAUS is used for both offline data analysis and fast online data reconstruction and visualization to serve MICE data taking. This paper provides an introduction to MAUS, describing the central Python and C++ based framework, the data structure and and the code management and testing procedures.

Leaf litter inputs can influence the structure and function of both terrestrial and adjacent aquatic ecosystems. Dioecy and herbivory are two factors that together have received little attention, yet have the potential to affect the quantity, quality, and timing of riparian litterfall, litter chemistry, and litter decomposition processes. Here, we explore litter chemistry differences for the dioecious Sitka willow (Salix sitchensis Sanson ex. Bong), which is establishing on primary successional habitats at Mount St. Helens (WA, USA) and is heavily infested with a stem‐boring weevil (Cryptorhynchus lapathi). Weevil‐attacked branches produced summer senesced litter that had significantly higher %N, lower C:N ratios, and lower condensed tannins than litter from branches that were unattacked by the weevil and senesced naturally in the autumn. Weevils more often attack female willows; however, these common litter chemicals did not significantly differ between males and females within the weevil‐attacked and ‐unattacked groups. High‐resolution mass spectrometry was used to isolate compounds in litter from 10 Sitka willow individuals with approximately 1500–1600 individual compounds isolated from each sample. There were differences between weevil‐attacked litter and green leaf samples, but at this level, there was no clustering of male and female samples. However, further exploration of the isolated compounds determined a suite of compounds present only in either males or females. These findings suggest some variation in more complex litter chemistry between the sexes, and that significant differences in weevil‐attacked litter chemistry, coupled with the shift in seasonality of litter inputs to streams, could significantly affect in‐stream ecological processes, such as decomposition and detritivore activity. In this paper, we explore the effects of dioecy and herbivory on leaf litter chemistry. The recently created headwater streams at Mt. St. Helens receive litter from the dioecious Sitka willow (Salix sitchensis Sanson ex. Bong), which is heavily infested with a stem‐boring weevil (Cryptorhynchus lapathi). This study suggests some variation in complex litter chemistry between the sexes and demonstrates that the weevil is altering not just the seasonality of litter inputs to these streams but also the chemical composition of that litter.

Cation– π interactions drive the self-assembly and cohesion of many biological molecules, including the adhesion proteins of several marine organisms. Although the origin of cation– π bonds in isolated pairs has been extensively studied, the energetics of cation– π -driven self-assembly in molecular films remains uncharted. Here we use nanoscale force measurements in combination with solid-state NMR spectroscopy to show that the cohesive properties of simple aromatic- and lysine-rich peptides rival those of the strong reversible intermolecular cohesion exhibited by adhesion proteins of marine mussel. In particular, we show that peptides incorporating the amino acid phenylalanine, a functional group that is conspicuously sparing in the sequences of mussel proteins, exhibit reversible adhesion interactions significantly exceeding that of analogous mussel-mimetic peptides. More broadly, we demonstrate that interfacial confinement fundamentally alters the energetics of cation– π -mediated assembly: an insight that should prove relevant for diverse areas, which range from rationalizing biological assembly to engineering peptide-based biomaterials. Cation– π interactions are critical for the adhesion proteins of marine organisms, yet the energetics of cation– π interactions in underwater environments remains uncharted. Nanoscale force measurements and NMR spectroscopy reveal that interfacial confinement fundamentally alters the energetics of cation– π mediated assembly.

Cosmic microwave background (CMB) measurements are fundamentally limited by photon statistics. Therefore, ground-based CMB observatories have been increasing the number of detectors that are simultaneously observing the sky. Thanks to the advent of monolithically fabricated transition edge sensor arrays, the number of on-sky detectors has been increasing exponentially for over a decade. The next-generation experiment CMB-S4 will increase this detector count by more than an order of magnitude from the current state of the art to 500,000. The readout of such a huge number of exquisitely precise sub-Kelvin sensors is feasible using an existing technology: frequency-domain multiplexing. To further optimize this system and reduce complexity and cost, we have recently made significant advances including the elimination of 4 K electronics, a massive decrease in parasitic in-series impedances, and a significant increase in multiplexing factor.