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Large Igneous Province (LIP) eruptions are thought to have driven environmental and climate change over wide temporal scales ranging from a few to thousands of years. Since the radiative effects and atmospheric lifetime of carbon dioxide (CO2, warming) and sulfur dioxide (SO2, cooling) are very different, the conventional assumption has been to analyze the effects of CO2 and SO2 emissions separately and add them together afterward. In this study, we test this assumption by analyzing the joint effect of CO2 and SO2 on the marine carbonate cycle using a biogeochemical carbon cycle box model (Long‐term Ocean‐atmosphere‐Sediment CArbon cycle Reservoir Model). By performing model runs with very fine temporal resolution (∼0.1‐year timestep), we analyze the effects of LIP carbon and sulfur gas emissions on timescales ranging from an individual eruption (hundreds to thousands of years) to the entire long‐term carbon cycle (>100,000 years). We find that, contrary to previous work, sulfur emissions have significant long‐term (>1,000 years) effects on the marine carbon cycle (dissolved inorganic carbon, pH, alkalinity, and carbonate compensation depth). This is due to two processes: the strongly temperature‐dependent equilibrium coefficients for marine carbonate chemistry and the few thousand‐year timescale for ocean overturning circulation. Thus, the effects of volcanic sulfur are not simply additive to the impact of carbon emissions. We develop a causal mechanistic framework to visualize the feedbacks associated with combined carbon and sulfur emissions and the associated timescales. Our results provide a new perspective for understanding the complex feedback mechanisms controlling the environmental effects of large volcanic eruptions over Earth history. Plain Language Summary Large Igneous Province (LIP) eruptions are among the largest volcanic events in Earth history and have been linked with environmental catastrophes such as mass extinctions and oceanic anoxic events. One of the main ways these volcanic events affect the environment is through the emission of climate‐active gases, primarily carbon dioxide (CO2) and sulfur dioxide (SO2). These gases are often thought of as behaving independently, as CO2 causes long‐term climate warming, while SO2, which turns into sulfate aerosols, causes short‐term climate cooling. However, in addition to directly causing climate change, both gases also cause more complex environmental changes, including changes to the ocean carbon cycle (e.g., ocean acidification and the amount and chemical species of dissolved carbon). Our study uses a long‐term marine carbon cycle box model to investigate these complex effects. We find that the assumption that the effects of each type of gas are independent is not accurate. Instead, we show that the carbon‐cycle effects of sulfur emissions, in particular, can persist on long timescales (>1,000 years) in addition to short‐term cooling. Our results provide a new perspective for understanding the environmental effects of large volcanic eruptions over Earth history. Key Points Volcanic CO2 and SO2 emissions have complex and interconnected effects on the ocean‐atmosphere system and biosphere Results show sulfate aerosol driven cooling has long‐lasting (>1,000 years) effects on the ocean carbon cycle Conventional assumption of strict timescale separation between the effects of volcanic CO2 and SO2 emissions is incorrect

The long-term effects of the Central Atlantic Magmatic Province, a large igneous province connected to the end-Triassic mass-extinction (201.5 Ma), remain largely elusive. Here, we document the persistence of volcanic-induced mercury (Hg) pollution and its effects on the biosphere for ~1.3 million years after the extinction event. In sediments recovered in Germany (Schandelah-1 core), we record not only high abundances of malformed fern spores at the Triassic-Jurassic boundary, but also during the lower Jurassic Hettangian, indicating repeated vegetation disturbance and stress that was eccentricity-forced. Crucially, these abundances correspond to increases in sedimentary Hg-concentrations. Hg-isotope ratios (δ 202 Hg, Δ 199 Hg) suggest a volcanic source of Hg-enrichment at the Triassic-Jurassic boundary but a terrestrial source for the early Jurassic peaks. We conclude that volcanically injected Hg across the extinction was repeatedly remobilized from coastal wetlands and hinterland areas during eccentricity-forced phases of severe hydrological upheaval and erosion, focusing Hg-pollution in the Central European Basin. This study provides evidence for long-term effects of volcanic emissions of large quantities of gaseous mercury (Hg) and plant mutagenesis by recording high abundances of malformed fern spores across the Triassic-Jurassic boundary and Early Jurassic.

Continental Cretaceous-Paleogene boundary sections are best known from North America, where they invariably exhibit a marked shift in sedimentary facies at or very near the boundary level. Uppermost Cretaceous strata typically reflect water-logged soils and unstable meandering-river deposits, whereas lowermost Paleogene strata typically reflect coal swamps and broad, stable meander-belt deposits. Causal links between facies shifts at the Cretaceous-Paleogene boundary and the end-Cretaceous mass extinction have been largely dismissed. Here, we present five new Cretaceous-Paleogene boundary sections identified via iridium anomalies in the Bighorn and Williston basins and assess the sedimentological changes that occur at North American Cretaceous-Paleogene boundaries. We hypothesize that the geographically widespread Cretaceous–Paleogene facies shifts were driven by the extinction of dinosaur megafauna. Large-bodied dinosaurs likely promoted open vegetation structure, prompting fluvial avulsion and clastic sediment input to distal floodplains. After the end-Cretaceous mass extinction, dense forests could establish, stabilizing meander belts and starving the floodplain of clastic sediment, favoring the accumulation of organic-rich strata. More empirical data are needed, but facies change in continental Cretaceous-Paleogene boundary sections suggests dinosaurs were ecosystem engineers that promoted habitat openness in the Late Cretaceous, and their extinction likely led to a dramatic reorganization of ecosystem structure in the earliest Paleogene. Dinosaurs promoted open habitats in the Late Cretaceous, and their extinction could have led to a radical reorganization of the landscape and ecosystem structure at the beginning of the Paleogene, according to sedimentology, biostratigraphy, and geochemistry data from western North America.

Large igneous province eruptions and their carbon emissions often coincide with, and are hypothesized to have driven, severe environmental perturbations in the geological past. However, the vast scale of large igneous provinces and uncertainties in magmatic volatile contents and radioisotopic dates limit our ability to resolve gas emissions in detail over time. Here we employ high-resolution (~5–200 kyr) sedimentary mercury data from the Llanbedr (Mochras Farm) borehole, Wales, to derive quantitative large igneous province degassing estimates over a 20-million-year-long Early Jurassic interval (195–175 million years ago). Intervals of relatively elevated sedimentary mercury coincide with episodes of carbon-cycle change, including the Toarcian Oceanic Anoxic Event (183–182 million years ago). We use excess mercury loading to estimate large igneous province-associated carbon emissions, revealing that multi-millennial episodes of activity plausibly drove recognized p CO 2 and temperature increases. However, previous carbon-cycle model-based carbon emission scenarios require faster and larger carbon inputs than our proposed emissions. Resolving this discrepancy may require climate–carbon-cycle feedbacks or co-emitted gases to substantially exacerbate the carbon-cycle response, processes potentially underestimated in current models. Our long and near-continuous record of Early Jurassic large igneous province activity demonstrates mercury’s potential as a tool to resolve past carbon fluxes. Sedimentary mercury measurements suggest carbon emissions from Early Jurassic large igneous province activity were lower than estimates from carbon-cycle models, implying feedbacks that are unaccounted for.

Changing hydrology impacts the biogeochemical cycling of elements such as mercury (Hg), whose transport and transformation in the environment appear linked to hydroclimate on diverse timescales. Key questions remain about how these processes manifest over different timescales and about their potential environmental consequences. For example, millennial-scale Hg–hydroclimate interactions in the terrestrial realm are poorly understood, as few sedimentary records have sufficient length and resolution to record abrupt and long-lasting changes in Hg cycling and the relative roles of depositional processes in these changes. Here, we present a high-resolution sedimentary Hg record from tropical Lake Bosumtwi (Ghana, western Africa) since ∼ 96 ka. A coupled response is observed between Hg flux and shifts in sediment composition, the latter reflecting changes in lake level. Specifically, we find that the amplitude and frequency of Hg peaks increase as the lake level rises, suggesting that Hg burial was enhanced in response to an insolation-driven increase in precipitation at ∼ 73 ka. A more transient, 3-fold increase in Hg concentration and accumulation rate is also recorded between ∼ 13 and 4 ka, coinciding with a period of distinctly higher rainfall across northern Africa known as the African Humid Period. Two mechanisms, likely working in tandem, could explain this correspondence: (1) an increase in wet deposition of Hg by precipitation and (2) efficient sequestration of organic-hosted Hg. Taken together, our results reaffirm that changes in hydroclimate, directly and/or indirectly, can be linked to millennial-scale changes in tropical Hg cycling and that these signals can be recorded in lake sediments.

The element mercury (Hg) is a key pollutant, and much insight has been gained by studying the present-day Hg cycle. However, many important processes within this cycle operate on timescales responsive to centennial- to millennial-scale environmental variability, highlighting the importance of also investigating the longer-term Hg records in sedimentary archives. To this end, we here explore the timing, magnitude, and expression of Hg signals retained in sediments over the past ∼ 90 kyr from two lakes, linked by a subterranean karst system: Lake Prespa (Greece, North Macedonia, and Albania) and Lake Ohrid (North Macedonia and Albania). Results suggest that Hg fluctuations are largely independent of variability in common host phases in each lake, and the recorded sedimentary Hg signals show distinct differences first during the Late Pleistocene (Marine Isotope Stages 2–5). The Hg signals in Lake Prespa sediments highlight an abrupt, short-lived peak in Hg accumulation coinciding with local deglaciation. In contrast, Lake Ohrid shows a broader interval with enhanced Hg accumulation and, superimposed, a series of low-amplitude oscillations in Hg concentration peaking during the Last Glacial Maximum, which may result from elevated clastic inputs. Divergent Hg signals are also recorded during the Early and Middle Holocene (Marine Isotope Stage 1). Here, Lake Prespa sediments show a series of large Hg peaks, while Lake Ohrid sediments show a progression to lower Hg values. Since ∼ 3 ka, anthropogenic influences overwhelm local fluxes in both lakes. The lack of coherence in Hg accumulation between the two lakes suggests that, in the absence of an exceptional perturbation, local differences in sediment composition, lake structure, Hg sources, and water balance all influence the local Hg cycle and determine the extent to which Hg signals reflect local- or global-scale environmental changes.

The carbon emissions of large igneous province magmatism are commonly associated with severe environmental crises. We developed a technique that used sedimentary mercury records to estimate these carbon fluxes through time and found that they are smaller and/or slower than assumed, which suggests that the influence of carbon-cycle feedback processes is underestimated in current models.

Drilling for the International Continental Scientific Drilling Program (ICDP) Early Jurassic Earth System and Timescale project (JET) was undertaken between October 2020 and January 2021. The drill site is situated in a small-scale synformal basin of the latest Triassic to Early Jurassic age that formed above the major Permian–Triassic half-graben system of the Cheshire Basin. The borehole is located to recover an expanded and complete succession to complement the legacy core from the Llanbedr (Mochras Farm) borehole drilled through 1967–1969 on the edge of the Cardigan Bay Basin, North Wales. The overall aim of the project is to construct an astronomically calibrated integrated timescale for the Early Jurassic and to provide insights into the operation of the Early Jurassic Earth system. Core of Quaternary age cover and Early Jurassic mudstone was obtained from two shallow partially cored geotechnical holes (Prees 2A to 32.2 m below surface (m b.s.) and Prees 2B to 37.0 m b.s.) together with Early Jurassic and Late Triassic mudstone from the principal hole, Prees 2C, which was cored from 32.92 to 651.32 m (corrected core depth scale). Core recovery was 99.7 % for Prees 2C. The ages of the recovered stratigraphy range from the Late Triassic (probably Rhaetian) to the Early Jurassic, Early Pliensbachian (Ibex Ammonoid Chronozone). All ammonoid chronozones have been identified for the drilled Early Jurassic strata. The full lithological succession comprises the Branscombe Mudstone and Blue Anchor formations of the Mercia Mudstone Group, the Westbury and Lilstock formations of the Penarth Group, and the Redcar Mudstone Formation of the Lias Group. A distinct interval of siltstone is recognized within the Late Sinemurian of the Redcar Mudstone Formation, and the name “Prees Siltstone Member” is proposed. Depositional environments range from playa lake in the Late Triassic to distal offshore marine in the Early Jurassic. Initial datasets compiled from the core include radiography, natural gamma ray, density, magnetic susceptibility, and X-ray fluorescence (XRF). A full suite of downhole logs was also run. Intervals of organic carbon enrichment occur in the Rhaetian (Late Triassic) Westbury Formation and in the earliest Hettangian and earliest Pliensbachian strata of the Redcar Mudstone Formation, where up to 4 % total organic carbon (TOC) is recorded. Other parts of the succession are generally organic-lean, containing less than 1 % TOC. Carbon-isotope values from bulk organic matter have also been determined, initially at a resolution of ∼ 1 m, and these provide the basis for detailed correlation between the Prees 2 succession and adjacent boreholes and Global Stratotype Section and Point (GSSP) outcrops. Multiple complementary studies are currently underway and preliminary results promise an astronomically calibrated biostratigraphy, magnetostratigraphy, and chemostratigraphy for the combined Prees and Mochras successions as well as insights into the dynamics of background processes and major palaeo-environmental changes.