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We present the properties of a magneto-optical trap (MOT) of CaF molecules. We study the process of loading the MOT from a decelerated buffer-gas-cooled beam, and how best to slow this molecular beam in order to capture the most molecules. We determine how the number of molecules, the photon scattering rate, the oscillation frequency, damping constant, temperature, cloud size and lifetime depend on the key parameters of the MOT, especially the intensity and detuning of the main cooling laser. We compare our results to analytical and numerical models, to the properties of standard atomic MOTs, and to MOTs of SrF molecules. We load up to 2 × 10 4 molecules, and measure a maximum scattering rate of 2.5 × 10 6 s−1 per molecule, a maximum oscillation frequency of 100 Hz, a maximum damping constant of 500 s−1, and a minimum MOT rms radius of 1.5 mm. A minimum temperature of 730 K is obtained by ramping down the laser intensity to low values. The lifetime, typically about 100 ms, is consistent with a leak out of the cooling cycle with a branching ratio of about 6 × 10 − 6 . The MOT has a capture velocity of about 11 m s−1.

Using frequency-chirped radiation pressure slowing, we precisely control the velocity of a pulsed CaF molecular beam down to a few m s-1, compressing its velocity spread by a factor of 10 while retaining high intensity: at a velocity of 15 m s-1 the flux, measured 1.3 m from the source, is 7 × 105 molecules per cm2 per shot in a single rovibrational state. The beam is suitable for loading a magneto-optical trap or, when combined with transverse laser cooling, improving the precision of spectroscopic measurements that test fundamental physics. We compare the frequency-chirped slowing method with the more commonly used frequency-broadened slowing method.

The electric dipole moment of the electron (eEDM) can be measured with high precision using heavy polar molecules. In this paper, we report on a series of new techniques that have improved the statistical sensitivity of the YbF eEDM experiment. We increase the number of molecules participating in the experiment by an order of magnitude using a carefully designed optical pumping scheme. We also increase the detection efficiency of these molecules by another order of magnitude using an optical cycling scheme. In addition, we show how to destabilise dark states and reduce backgrounds that otherwise limit the efficiency of these techniques. Together, these improvements allow us to demonstrate a statistical sensitivity of 1.8 × 10−28 e cm after one day of measurement, which is 1.2 times the shot-noise limit. The techniques presented here are applicable to other high-precision measurements using molecules.

We present the design and characterization of a low-noise environment for measuring the electron’s electric dipole moment (EDM) with a beam of molecules. To minimize magnetic Johnson noise from metals, the design features ceramic electric field plates housed in a glass vacuum chamber. To suppress external magnetic noise the apparatus is enclosed within a cylindrical four-layer mu-metal shield with a shielding factor exceeding 106 in one radial direction and 105 in the other. Finite element modelling shows that the difference between these shielding factors is due to imperfect joints between sections of mu-metal. Using atomic magnetometers to monitor the magnetic field inside the shield, we measure noise below 40 fT  Hz−1 at 1 Hz and above, rising to 500 fT  Hz−1 at 0.1 Hz. Analytical and numerical studies show that residual magnetic Johnson noise contributes approximately 13 fT  Hz−1. The background magnetic field averaged along the beamline is maintained below 3 pT, with typical gradients of a few nT m−1. An electric field of 20 kV cm−1 is applied without discharges and with leakage currents below 1 nA. Each magnetometer measures the magnetic field correlated with the direction of the applied electric field with a precision of 0.11 fT in 104 h of data. These results demonstrate that the apparatus is suitable for measuring the electron EDM with precision at the 10−31 e cm level. The design principles and characterization techniques presented here are broadly applicable to precision measurements probing fundamental symmetries in molecules, atoms, and neutrons.

Magneto-optical trapping and sub-Doppler cooling of atoms has been instrumental for research in ultracold atomic physics. This regime has now been reached for a molecular species, CaF. Magneto-optical trapping and sub-Doppler cooling have been essential to most experiments with quantum degenerate gases, optical lattices, atomic fountains and many other applications. A broad set of new applications await ultracold molecules 1 , and the extension of laser cooling to molecules has begun 2 , 3 , 4 , 5 , 6 . A magneto-optical trap (MOT) has been demonstrated for a single molecular species, SrF 7 , 8 , 9 , but the sub-Doppler temperatures required for many applications have not yet been reached. Here we demonstrate a MOT of a second species, CaF, and we show how to cool these molecules to 50 μK, well below the Doppler limit, using a three-dimensional optical molasses. These ultracold molecules could be loaded into optical tweezers to trap arbitrary arrays 10 for quantum simulation 11 , launched into a molecular fountain 12 , 13 for testing fundamental physics 14 , 15 , 16 , 17 , 18 , and used to study collisions and chemistry 19 between atoms and molecules at ultracold temperatures.

The detection of variations of fundamental constants of the Standard Model would provide us with compelling evidence of new physics, and could lift the veil on the nature of dark matter and dark energy. In this work, we discuss how a network of atomic and molecular clocks can be used to look for such variations with unprecedented sensitivity over a wide range of time scales. This is precisely the goal of the recently launched QSNET project: A network of clocks for measuring the stability of fundamental constants. QSNET will include state-of-the-art atomic clocks, but will also develop next-generation molecular and highly charged ion clocks with enhanced sensitivity to variations of fundamental constants. We describe the technological and scientific aims of QSNET and evaluate its expected performance. We show that in the range of parameters probed by QSNET, either we will discover new physics, or we will impose new constraints on violations of fundamental symmetries and a range of theories beyond the Standard Model, including dark matter and dark energy models.

The last few years have seen rapid progress in the application of laser cooling to molecules. In this review, we examine what kinds of molecules can be laser cooled, how to design a suitable cooling scheme, and how the cooling can be understood and modelled. We review recent work on laser slowing, magneto-optical trapping, sub-Doppler cooling, and the confinement of molecules in conservative traps, with a focus on the fundamental principles of each technique. Finally, we explore some of the exciting applications of laser-cooled molecules that should be accessible in the near term.

We use two-dimensional transverse laser cooling to produce an ultracold beam of YbF molecules. Through experiments and numerical simulations, we study how the cooling is influenced by the polarization configuration, laser intensity, laser detuning and applied magnetic field. The ultracold part of the beam contains more than \\(2 \\times 10^5\\) molecules per shot and has a temperature below 200 \\(\\mu\\)K, and the cooling yields a 300-fold increase in the brightness of the beam. The method can improve the precision of experiments that use molecules to test fundamental physics. In particular, the beam is suitable for measuring the electron electric dipole moment with a statistical precision better than \\(10^{-30}\\) e cm.

Measurements of interactions between cold molecules and ultracold atoms can allow for a detailed understanding of fundamental collision processes. These measurements can be done using various experimental geometries including where both species are in a beam, where one species is trapped, or when both species are trapped. Simultaneous trapping offers significantly longer interaction times and an associated increased sensitivity to rare collision events. However, there are significant practical challenges associated with combining atom and molecule systems, which often have competing experimental requirements. Here, we describe in detail an experimental system that allows for studies of cold collisions between ultracold atoms and cold molecules in a dual trap, where the atoms and molecules are trapped using static magnetic and electric fields, respectively. As a demonstration of the system's capabilities, we study cold collisions between ammonia (\\(^{14}\\)ND\\(_{3}\\) and \\(^{15}\\)ND\\(_{3}\\)) molecules and rubidium (\\(^{87}\\)Rb and \\(^{85}\\)Rb) atoms.

New experimental techniques, involving an increasingly large set of molecule types under high levels of control, are currently opening up new avenues of research with a vast array of potential applications. From understanding the role of quantum mechanics in molecular scattering and cold chemistry, to testing the fundamental symmetries of nature and realizing quantum computing with dipolar molecular qubits, experiments are accessing regimes not dreamed of even a few years ago. Theoretical interest and computing capabilities are also at an all time high, spurred on by the possibility of creating ultracold dipolar gases as tunable realizations of strongly interacting quantum Hamiltonians, creating exotic phases of matter, and the investigation of controlling molecular interactions with applied electromagnetic fields. Research of cold and ultracold molecules is currently a burgeoning field in experimental and theoretical physics. Less than a decade ago, cold molecule experiments had seemingly reached a technological plateau, being capable of creating moderate densities of 10 6-107 molecules/cm3 at temperatures of 10-100 mK. With many applications requiring colder temperatures and higher densities, the field was ripe for new advances. Today, through a plethora of methods, such as direct molecular laser cooling, electro-optical cooling, magneto- and photo-association, and new molecular beam deceleration techniques, the field is just beginning to have the tools capable of producing truly interesting systems for study. This work will discuss a couple of major steps taken in the direction of achieving scientific goals using cold molecules. The first experimental advancement discussed will be the development of a co-trap environment for studying interactions and collisions between ultracold atoms and Stark decelerated cold polar molecules. In this experiment, rubidium atoms are trapped using magnetic fields, and ammonia atoms are decelerated and trapped using electric fields. The two traps are spatially overlapped in order to investigate inter-species interactions. The co-trap environment provides exceedingly long interaction times, many orders of magnitude longer than typical beam-based interaction studies. As a result, it provides extremely high sensitivity to weak interaction mechanisms. The second experimental advancement discussed will be the development and construction of a new style of Stark decelerator, capable of producing much larger densities of cold molecules. This apparatus has the potential to expand the realm of possible experiments with chemically interesting species, and provide an unprecedented amount of control over molecular beams and traps. The gains haven't come easily though, as a new class of custom high-voltage amplifiers have needed to be developed. This part of the experiment alone took approximately two years of consistent effort to bring to fruition. After many years of development, this experiment is poised to come online, finally fulfilling its potential.