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19 result(s) for "Gajendra Kumar Inwati"
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Health and Environmental Risks of Incense Smoke: Mechanistic Insights and Cumulative Evidence
Incense burning is practiced alongside many sacred rituals across different regions of the world. Invariable constituents of incense brands are 21% (by weight) herbal and wood powder, 33% bamboo stick, 35% fragrance material, and 11% adhesive powder. Major incense-combustion outputs include particulate matter (PM), volatile organic content, and polyaromatic hydrocarbons. The relative toxicity of these products is an implicit function of particle size and incomplete combustion, which in turn vary for a specific incense brand. Lately, the attention given to the Air Quality Index by international regulatory bodies has created concern about mounting PM toxicity. The uncharacteristically small physical dimensions of these entities complicates their detection, and with no effect of gravity PM fractions rapidly contribute to oxidative stress, enhancing random biochemical reactions upon being inhaled. Incense burning generates four times the PM extent (45 mg•g ) of cigarettes (~10 mg•g ). Several poisonous gases, such as CO, CO , NO , and SO , and the unavoidable challenge of disposing of the burnt incense ash further add to the toxicity. Taken together, these issues demonstrate that incense burning warrants prompt attention. The aim of this article is to highlight the toxicity of incense-combustion materials on the environment and human health. This discussion could be significant in framing future policy regarding ecofriendly incense manufacture and reduced usage.
Remediation of Azure A Dye from Aqueous Solution by Using Surface-Modified Coal Fly Ash Extracted Ferrospheres by Mineral Acids and Toxicity Assessment
The Indian coal fly ash (CFA) is composed of 5-15% ferrous fractions. The variation in percentage depends on the source of coal and the operating conditions of the thermal power plants. The present research work reports the recovery of ferrous particles from CFA by the wet magnetic separation method. The morphological, elemental, and chemical properties of the extracted ferrous fractions were analyzed. In order to achieve surface-modified ferrospheres, the extracted ferrospheres were treated with concentrated HCl followed by sonication. The instrumental analysis reported the ferrous composition is around 16% by weight and belongs to class F. The toxicity of CFA was determined on normal human lung (BEAS-2B) cells using MTS assay. The results showed that CFA’s induced cell toxicity in a dose-dependent manner. The ferrous particles were spherically shaped with various sizes ranging from 200 nm to 7000 nm. It was crystalline in nature and is a mixture of hematite and magnetite. The particles were found to be associated with alumina, silica, oxygen, and traces of Ca, Mg, Ti, and C. The surface-modified ferrospheres were used for the remediation of Azure A dye by batch adsorption study. The removal percentage of dye was 25.03%, within 30 minutes at neutral pH, i.e., 7.2. The surface-modified ferrospheres show potential as an alternate, more economical, and reusable adsorbent for the remediation of Azure A dye in the industries or in common effluent treatment plants. Moreover, the recovery of surface-modified ferrospheres using an external magnet and the reuse of the particles make the material much economical for dye removal at an industrial scale.
Recent Trends in Fascinating Applications of Nanotechnology in Allied Health Sciences
The increased advancement in nanosciences in recent times has led to fascinating innovations. It has potential applications for altering the structural, surface, and physicochemical properties of nano-ranged metamaterials. The adaptable optical, structural, and surface characteristics of the nanoscopic regimes enhance the quality of integrated nanodevices and sensors. These are further used in optoelectronics, biomedicines, and catalysis. The use of nanomaterials for constructing nano-biosensors and various other organic and inorganic functional nanomaterials is quite promising. They have excellent electronic and surface-to-volume reactivity. Their various applications include metal and metal-oxides-based nanoparticles, clusters, wires, and 2D nanosheets as carbon nanotubes. More recently, hybrid nanomaterials are being developed to regulate sensing functionalities in the field of nanomedicine and the pharmaceutical industry. They are used as nano-markers, templates, and targeted agents. Moreover, the mechanical strength, chemical stability, durability, and flexibility of the hybrid nanomaterials make them appropriate for developing a healthy life for humans. This consists of a variety of applications, such as drug delivery, antimicrobial impacts, nutrition, orthopedics, dentistry, and fluorescence fabrics. This review article caters to the essential importance of nanoscience for biomedical applications and information for health science and research. The fundamental characteristics and functionalities of nanomaterials for particular biomedical uses are specifically addressed here.
Variations and similarities in structural, chemical, and elemental properties on the ashes derived from the coal due to their combustion in open and controlled manner
Coal fly ash (CFA) and coal-based incense sticks ash (ISA) have several similarities and differences due to the presence of coal as a common component in both of them. CFA are produced from the combustion of pulverized coal during electricity production in the thermal power plants while ISA are produced from the burning of incense sticks at religious places and at houses. A typical black colored Indian, incense sticks are mainly are comprised of coal powder or potassium nitrate, wood chip, fragrance, binder or binding agent, and bamboo sticks. The black colored incense sticks have coal powder or charcoal as a facilitator for smoother burning of incense sticks. The detailed investigation of CFA and ISA by X-ray fluorescence spectroscopy (XRF), electron diffraction spectroscopy (EDS), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), Fourier transform-infrared (FTIR), X-ray diffraction (XRD), particle size analyzer (PSA), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) revealed the morphological, chemical, and elemental properties. Both the coal based ashes comprises minerals like calcites, silicates, ferrous, alumina, and traces of Mg, Na, K, P, Ti, and numerous toxic heavy metals as confirmed by the XRF, ICP-AES, and EDS. While, microscopy revealed the presence of well-organized spherical shaped particles, namely cenospheres, plerospheres, and ferrospheres of size varying from 0.02 μm to 7 microns in CFA. Whereas, ISA particles are irregular, aggregated, calcium to carbon rich whose size varies from 60 nm to 9 microns and absence of well-organized spherical structures. The well developed and crystalline structure in CFA is due to the controlled combustion parameter in thermal power plants during the burning of coal while incense sticks (IS) burning is under uncontrolled manner. So, FTIR and XRD confirmed that the major portion of fly ash constitutes crystalline minerals whereas ISA have mainly amorphous phase minerals. CFA have ferrospheres of both rough and smooth surfaced, which was absent from the ISA and hence ferrous particles of CFA are of high magnetic strength. The detailed investigation of ashes will lead to the applications of ashes in new fields, which will minimize the solid waste pollution in the environment.
Nanostructured Antibiotics and Their Emerging Medicinal Applications: An Overview of Nanoantibiotics
Bacterial strains resistant to antimicrobial treatments, such as antibiotics, have emerged as serious clinical problems, necessitating the development of novel bactericidal materials. Nanostructures with particle sizes ranging from 1 to 100 nanometers have appeared recently as novel antibacterial agents, which are also known as “nanoantibiotics”. Nanomaterials have been shown to exert greater antibacterial effects on Gram-positive and Gram-negative bacteria across several studies. Antibacterial nanofilms for medical implants and restorative matters to prevent bacterial harm and antibacterial vaccinations to control bacterial infections are examples of nanoparticle applications in the biomedical sectors. The development of unique nanostructures, such as nanocrystals and nanostructured materials, is an exciting step in alternative efforts to manage microorganisms because these materials provide disrupted antibacterial effects, including better biocompatibility, as opposed to minor molecular antimicrobial systems, which have short-term functions and are poisonous. Although the mechanism of action of nanoparticles (NPs) is unknown, scientific suggestions include the oxidative-reductive phenomenon, reactive ionic metals, and reactive oxygen species (ROS). Many synchronized gene transformations in the same bacterial cell are essential for antibacterial resistance to emerge; thus, bacterial cells find it difficult to build resistance to nanoparticles. Therefore, nanomaterials are considered as advanced solution tools for the fields of medical science and allied health science. The current review emphasizes the importance of nanoparticles and various nanosized materials as antimicrobial agents based on their size, nature, etc.
Study of Defect-Induced Chemical Modifications in Spinel Zinc-Ferrites Nanostructures by In-Depth XPS Investigation
Spinel zinc ferrite nanomaterials with exceptional physiochemical properties are potential candidates for various applications in the energy and environmental fields. Their properties can be tailored using several methods to widen their applications. The chemical combustion approach was followed to prepare the spinel zinc ferrite nanomaterials, which were then subjected to thermal treatment at a fixed temperature. Thermal heat treatment at a fixed temperature was used to evaluate the phase and morphological characteristics of the prepared spinel zinc−ferrite nanocomposites. Various techniques were employed to examine the samples, including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). XPS and X-ray−induced Auger electron spectroscopy were used to extensively examine the surface characteristics of the zinc−ferrite. To study the actual chemical states of the synthesized spinel zinc ferrite nanomaterials and the defects created during the thermal treatment, an extensive investigation of the kinetic energy of the X-ray−induced Zn L3M45M45 and Fe L3M45M45 was conducted. Finally, a detailed analysis of the Wagner plot using the modified Auger parameter was performed to verify the exact chemical states of Zn and Fe. Thus, the findings of the investigation show that XPS is a promising and powerful technique to study the composition and chemical states of spinel zinc ferrites, providing an understanding of changes in their properties for functional applications.
Enriched Catalytic Activity of TiO2 Nanoparticles Supported by Activated Carbon for Noxious Pollutant Elimination
Cleaning wastewater has become one of the most serious issues for a number of scientists and researchers in recent years, as water is the most basic need for the daily life of humans. There has been a focus on the removal of noxious pollutants from wastewater effluents by using nanocatalysts owing to their unique physicochemical actions and stability. Herein we manufactured TiO2 nanoparticles supported by activated carbon (AC-TiO2) using a cost-effective sonochemical method. The band structures of the AC-TiO2 and TiO2 were modified from 3.2 to 3.1 eV, thus increasing the catalytic activity. The structural, optical and anatase crystal phase properties, with morphological confirmation, were studied by applying UV-DRS, PL, FESEM, XRD, along with HRTEM, respectively. The specific surface area, calculated by BET analysis, was found to be ~241 m2/gm and ~46 m2/gm for AC-TiO2 and TiO2. The degradation efficiency of the as-prepared nanocatalysts against the very toxic but rarely studied organic textile dye pollutant RO 84 was investigated and 97% efficiency were found for the AC-TiO2 as compared to pure TiO2, which is a highly appreciated finding in the catalytic dye degradation application domain. Such surface-modified nanocatalysts could be further implemented for the treatment of wastewaters/waste effluents released from chemical industries, laboratories and other sources.
Recent trends in the nanozeolites-based oxygen concentrators and their application in respiratory disorders
Medical-grade oxygen is the basic need for all medical complications, especially in respiratory-based discomforts. There was a drastic increase in the demand for medical-grade oxygen during the current pandemic. The non-availability of medical-grade oxygen led to several complications, including death. The oxygen concentrator was only the last hope for the patient during COVID-19 pandemic around the globe. The demands also are everlasting during other microbial respiratory infections. The yield of oxygen using conventional molecular zeolites in the traditional oxygen concentrator process is less than the yield noticed when its nano-form is used. Nanotechnology has enlightened hope for the efficient production of oxygen by such oxygen concentrators. Here in the current review work, the authors have highlighted the basic structural features of oxygen concentrators along with the current working principle. Besides, it has been tried to bridge the gap between conventional oxygen concentrators and advanced ones by using nanotechnology. Nanoparticles being usually within 100 nm in size have a high surface area to volume ratio, which makes them suitable adsorbents for oxygen. Here authors have suggested the use of nano zeolite in place of molecular zeolites in the oxygen concentrator for efficient delivery of oxygen by the oxygen concentrators.
Development of Novel Microcomposite Materials from Coal Fly Ash and Incense Sticks Ash Waste and Their Application for Remediation of Malachite Green Dye from Aqueous Solutions
Coal fly ash (CFA) is one of the major pollutants around the whole world. At the same time, incense stick ash (ISA) is another waste that is generated in huge amounts in Southeast Asia. Both of these wastes are rich in different types of minerals; for instance, CFA is rich in alumina, silica, and ferrous, while incense sticks ash is rich in calcium and silica. ISA has intermediate to trace amounts of ferrous, alumina, and magnesium. The addition of alkali-rich materials with high Al and Si-containing CFA helps in the formation of zeolites or geopolymers. So, in the current research work, the authors have prepared a CFA: ISA mixture in the ratio of 1:1, followed by mixing them with NaOH, CaOH2, and KOH in a dry state in a crucible. Further, all these mixtures were then calcined at 600 °C for six hours in a muffle furnace. Further, the developed products were analyzed by various sophisticated instruments for detailed information. Finally, the developed material’s potential was assessed for the remediation of malachite green from the aqueous solution by batch adsorption study. The developed adsorbents efficiently removed the dye from the aqueous solutions within one hour. The kinetic study revealed that the dye removal followed a pseudo-second-order reaction. Finally, the developed material was also assessed for its suitability as an adsorbent by observing the effect of leaching of potassium, aluminum, and silica from the adsorbent surface into the water systems. Such approaches will solve the problem of solid waste disposal arising from both the ashes.
Experimental and Computational Approaches for the Structural Study of Novel Ca-Rich Zeolites from Incense Stick Ash and Their Application for Wastewater Treatment
At present, chemical Si/Al sources are mainly used as precursor materials for the manufacturing of zeolites. Such precursor materials are quite expensive for commercial synthesis. Here, we have reported the synthesis of Ca-based zeolite from incense stick ash waste by the alkali-treatment method for the first time. Incense stick ash (ISA) was used as a precursor material for the synthesis of low Si zeolites by the alkali-treatment method. The as-synthesized zeolites were characterized by various instruments like particle size analyzer (PSA), Fourier transform infrared (FTIR), X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), electron diffraction spectroscopy (EDS), transmission electron microscopy (TEM), and X-ray fluorescence (XRF). FTIR and XRD helped in the identification of the microstructure and crystalline nature of the zeolites and also confirmed the synthesis of Ca-based zeolite with two thetas at 25.7°. The microscopic analysis by FESEM and TEM exhibited that the size of synthesized Ca-rich zeolites varies from 200 to 700 nm and they are aggregated and cuboidal in shape. Additionally, structural, electronic, and density of states’ characteristics of gismondine (Ca2Al4Si4O16·9H2O) structures were evaluated by computational simulations (first principle, density functional theorem). The structural optimization of structures was carried out in the first stage under the lowest condition of total energy and forces acting on atoms for the lattice constant, as well as the available experimental and theoretical findings. The present research approach predicted the transformation of ISA waste into a value-added mineral, i.e., zeolite, which was further used for the removal of both heavy metals and alkali metals from fly ash-based wastewater using inductively coupled plasma-optical emission spectroscopy (ICP-OES).