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Predicted climate warming and prolonged droughts pose a threat to the soil structure as organic carbon losses weaken the stability of soil aggregates. Well-structured soils are important for storage and movement of water, solutes, and air, the development of plant roots, as habitat for soil organisms, and the microbial activity. Structural stability is measured in terms of hydro-mechanical properties. This study compares effects of amorphous silica with those of organic carbon on stability parameters during drying of aggregates from relatively finer- and coarser-textured soils. Silica amendment enhanced the positive effect of organic carbon on structural stability in terms of the tensile strength. Synergistic effects between silica and organic carbon in soil colloids appear to dynamically alter aggregate density and friability (i.e., ability to crumble) during drying. Silica together with organic carbon could help soil management to reduce negative effects of predicted prolonged droughts on soil structure and stability.

The decrease of organic matter content in agricultural soils is a problem of great concern to farmers around the world. Indeed, it lowers soil fertility that directly impairs agricultural crop production and affects a number of other soil properties like water retention capacity, aggregation and structure formation, soil mechanical strength or compactibility. Scarcity in plant available water poses a risk to agriculture, especially in drought-prone areas. However, the increase of organic waste recycling in agriculture may also lead to an increase in soil organic matter contents and to changes in related soil properties. Here, we review 17 long-term field experiments (≥9 years) that investigated the effects of organic amendments on organic carbon and water availability in topsoils. We paid particular attention to the effects of added organic matter on soil bulk density or porosity and consequently on plant available water. Our main findings are that (1) plant available water generally improves after organic waste addition (relative changes from −10 to +30 vol%; p = 0.052), (2) organic matter quality affects changes in organic carbon (p < 0.05), (3) it is more suitable for plant available water quantification to use volumetric rather than gravimetric water contents, (4) the value of the matric potential defining field capacity is an issue, (5) pedotransfer functions developed for American soils adequately predicted most water contents at field capacity and wilting point, and (6) prevailing climate and initial organic carbon content may affect plant available water. This review confirms that organic amendments generally induce beneficial effects on plant available water and other soil properties. It also highlights the influence of organic matter quality on soil organic carbon. Compared with a previous review, this study reinforces reported trends of increasing plant available water with organic waste additions. This may be due to a more restrictive selection of recently published data and the use of volumetric water contents. Our findings are significant for sustainable agriculture regarding the sustainable use of organic wastes and water.

Lateral subsurface flow (LSF) is a phenomenon that is widely occurring including the hummocky ground moraine landscape. Due to the heterogeneous structure of the subsurface, transport times of pesticides and nutrients from agricultural areas to adjacent water bodies are difficult to assess. Here, LSF at Luvisol and Regosol plots of an experimental field were studied by applying potassium bromide along a 10 m trench below the plow pan in October 2019. The soil solution was collected in suction cups 3 m downslope of the trench and in April 2021, the soil was sampled down to 1 m depth. Almost no bromide was found in the soil solution except for the 160 cm depth of the Regosol plot after a 541 day period. After the same time, bromide was observed in the 90 cm soil depth directly underneath the application trench of the Luvisol plot. A 3D reconstruction of the subsurface horizon boundaries of the Regosol revealed subsurface heterogeneities such as sand lenses that might have been attributed to the heterogeneous subsurface flow pattern.

The solubility and mobility of copper (Cu) in soil is strongly influenced by the presence of dissolved organic carbon (DOC); however, the interactions between Cu and DOC are complex and not yet fully understood. In this study, Cu and DOC concentrations were measured monthly for two years in leachates from self-constructed lysimeters installed at inter- and intra-row vineyard hilltop, backslope, and footslope areas at the SUPREHILL Critical Zone Observatory, Croatia. The aim was to quantify Cu and DOC leaching from the hilltop towards the backslope and the footslope. The assumed strong relationship between Cu and DOC in the leachates was statistically analyzed and explained using chemical equilibrium software. Leachates were analyzed for pH, EC, DOC, Cu, and major ion concentrations. The highest Cu concentrations found in leachates from the intra-row footslope suggested Cu downhill transport. Although not strong, a significant positive correlation between Cu and DOC in footslope leachates confirmed the relevance of Cu complexation by DOC. Speciation confirmed that more than 99.9% of total Cu in leachates was found as a Cu-DOC complex. Data implied the role of soil water flow pathways in explaining Cu downhill transport. Critical timing for applying Cu fungicides at sloped vineyards was highlighted.

A quantitative understanding of actual evapotranspiration (ETa) and soil–water dynamics in a hillslope agroecosystem is vital for sustainable water resource management and soil conservation; however, the complexity of processes and conditions involving lateral subsurface flow (LSF) can be a limiting factor in the full comprehension of hillslope soil–water dynamics. The research was carried out at SUPREHILL CZO located on a hillslope agroecosystem (vineyard) over a period of two years (2021–2022) by combining soil characterization and field hydrological measurements, including weighing lysimeters, sensor measurements, and LSF collection system measurements. Lysimeters were placed on the hilltop and the footslope, both having a dynamic controlled bottom boundary, which corresponded to field pressure head measurements, to mimic field soil–water dynamics. Water balance components between the two positions on the slope were compared with the goal of identifying differences that might reveal hydrologically driven differences due to LSF paths across the hillslope. The usually considered limitations of these lysimeters, or the borders preventing LSF through the domain, acted as an aid within this installation setup, as the lack of LSF was compensated for through the pumping system at the footslope. The findings from lysimeters were compared with LSF collection system measurements. Weighing lysimeter data indicated that LSF controlled ETa rates. The results suggest that the onset of LSF contributes to the spatial crop productivity distribution in hillslopes. The present approach may be useful for investigating the impact of LSF on water balance components for similar hillslope sites and crops or other soil surface covers.

Grasslands are one of the most common biomes in the world with a wide range of ecosystem services. Nevertheless, quantitative data on the change in nitrogen dynamics in extensively managed temperate grasslands caused by a shift from energy- to water-limited climatic conditions have not yet been reported. In this study, we experimentally studied this shift by translocating undisturbed soil monoliths from an energy-limited site (Rollesbroich) to a water-limited site (Selhausen). The soil monoliths were contained in weighable lysimeters and monitored for their water and nitrogen balance in the period between 2012 and 2018. At the water-limited site (Selhausen), annual plant nitrogen uptake decreased due to water stress compared to the energy-limited site (Rollesbroich), while nitrogen uptake was higher at the beginning of the growing period. Possibly because of this lower plant uptake, the lysimeters at the water-limited site showed an increased inorganic nitrogen concentration in the soil solution, indicating a higher net mineralization rate. The N2O gas emissions and nitrogen leaching remained low at both sites. Our findings suggest that in the short term, fertilizer should consequently be applied early in the growing period to increase nitrogen uptake and decrease nitrogen losses. Moreover, a shift from energy-limited to water-limited conditions will have a limited effect on gaseous nitrogen emissions and nitrate concentrations in the groundwater in the grassland type of this study because higher nitrogen concentrations are (over-) compensated by lower leaching rates.

The conversion of coniferous forest to deciduous forest is accompanied by changes in the vertical distribution of fine roots and soil organic carbon (SOC) content. It is unclear how these changes affect soil CO 2 efflux and vertical soil CO 2 production, considering changing climate. Here, we present the results of a 6-year study on CO 2 efflux, covering relatively warm-dry and cool-wet years. A combination of the flux-gradient method and closed chamber measurements was used to study the CO 2 efflux and the vertical distribution of soil CO 2 production in a beech ( Fagus sylvatica L.) and a pine ( Pinus sylvestris L.) forest in northeast Germany. We observed, on average, similar CO 2 efflux with 517 (±126) and 559 (±78) g C m –2 a –1 for the beech site and the pine site, respectively. CO 2 efflux at the beech site exceeded that at the pine site during the wet year 2017, whereas in dry years, the opposite was the case. Water availability as indicated by precipitation was the primary determining long-term factor of CO 2 efflux, whereas seasonal variation was mainly affected by soil temperature, and—in the case of beech—additionally by soil water content. CO 2 efflux decreased more dramatically (-43%) at the beech site than at the pine site (-22%) during the warm-dry year 2018 compared to the cool-wet year 2017. We assumed that drought reduces heterotrophic respiration (R h ) at both sites, but additionally decreases autotrophic respiration (R a ) at the beech stand. Soil CO 2 production at the beech site ranged over a greater soil depth than at the pine site, attributed to different fine root distribution. The organic layer and the A horizon contributed 47 and 68% of total CO 2 efflux at the beech site and the pine site, respectively. The seasonal patterns of different CO 2 efflux between both sites were assumed to relate to different phases of tree physiological activity of deciduous compared to evergreen tree species.

Mineral temporary capping systems of landfills are required to accomplish the long-term coverage prerequisites or to use them as a basis layer prior to later permanent sealing. Such a capping system for a municipal waste landfill in Rastorf (Northern Germany) was developed and tested for its sealing capability on the basis of observed and simulated water balance components for the period between 2008 and 2015, considering observed local weather data and complemented by the Hydraulic Evaluation of Landfill Performance (HELP 3.95 D) model. The modeling results of this case study could be improved by the correction of previously used global solar radiation data due to the consideration of exposure and inclination angle of landfill surface areas. The model could positively be validated by comparing observed and simulated outflow (surface runoff and lateral drainage) data with R2 values ranging between 0.95 and 0.99, as well as for the leachate rates with R2 values of 0.78–0.87. The statistical-empirical HELP model was found useful in predicting the leachate generation of a temporary landfill capping system for specific soil and site conditions, even if only a restricted set of observed data was available.

Mucilage is receiving increasing attention because of its putative effects on plant growth, but so far no method is available to measure its spatial distribution in the rhizosphere. We tested whether the C-H signal related to mucilage fatty acids is detectable by infrared spectroscopy and if this method can be used to determine the spatial distribution of mucilage in the rhizosphere. Maize plants were grown in rhizoboxes filled with soil free of organic matter. Infrared measurements were carried out along transects perpendicular as well as axially to the root channels. The perpendicular profiles of gradients of the C-H proportions showed a decrease of C-H with increasing distance: 0.8 mm apart from the root center the C-H signals achieved a level near zero. The measured concentrations of mucilage were comparable with results obtained in previous studies, which encourages the use of infrared spectroscopy to quantitatively image mucilage in the rhizosphere.

In agricultural land use, organic residues such as compost, digestate, and sewage sludge are discussed as costeffective soil conditioner that may improve the water holding capacity and crop available soil moisture. The objective of this study is to determine the effect of application of digestates with different compositions in maize, sugar beet and winter wheat, compost of shrub debris and sewage sludge on shrinkage behaviour and contact angle of till-derived loamy topsoil of a Haplic Luvisol under agricultural use. Novelty is the simultaneous determination of contact angle and shrinkage of soils amended with digestates composed of different composition in maize, sugar beet and winter wheat, compost of shrub debris and sewage sludge. The results suggest that the application of organic residues impacts the air capacity, while the contact angles remained in the subcritical range between > 0° and < 90°. The relationship between CA values and moisture ratios, ϑ, during proportional shrinkage was positive and linear (r of 0.98) and negative during residual- and zero-shrinkage (r of 0.93).