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27 result(s) for "Giacomello, Giovanni"
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Unlocking the Economic and Business Potential of District Heating: The State of the Art and a Research Agenda
District heating (DH) systems offer a sustainable solution to local energy needs by improving energy efficiency, reducing emissions, and fostering economic development. Despite their growing technological relevance, DH systems remain underexplored in the economics, business, and management literature. This study addresses this gap by conducting a bibliometric analysis of DH research at the intersection of these fields, using data extracted from the Web of Science. We identify major theoretical foundations, including the resource-based view, stakeholder theory, and institutional economics, and explore key themes such as economic viability, business model innovation, regulatory frameworks, and sustainability strategies. By framing DH systems within broader economic and managerial discourses, our findings highlight the interdisciplinary nature of DH research and suggest critical avenues for future investigation, including the role of emerging technologies, consumer behavior, and policy design, and contribute to low-carbon, sustainable development.
Mechanical Feasibility of Asphalt Materials for Pavement Solar Collectors: Small-Scale Laboratory Characterization
Rutting (i.e., depressions along the wheel path) is a distress exhibited by flexible asphalt pavements at high in-service temperatures negatively affecting ride comfort and safety. In this regard, the fine asphalt mortar (i.e., bitumen filler and fine sand) plays a key role in the rutting potential of the asphalt mixtures. Given this background, this manuscript presents a small-scale laboratory experimentation aimed at assessing the rutting-related performance of a plain bitumen combined with natural (limestone) or manufactured (steel slag) fine aggregates (size up to 0.18 mm) through advanced experimental and theoretical approaches. Specific rheological tests through dynamic shear were carried out to achieve this goal. The investigated asphalt blends came from a wider research project focused on the implementation of a pavement solar collector (a road system to harvest the solar energy irradiating the pavement). In particular, the present paper aimed at verifying the mechanical suitability of the produced asphalt mixes with respect to permanent deformation resistance. Such a small-scale investigation mainly showed that the previously selected constituent materials did not imply criticisms in terms of rutting response.
Aesthetic and Mechanical Suitability of a Clear Synthetic Resin as a Unconventional Binder for Road Pavements
Current environmental awareness interests several aspects of civil engineering, including road construction. Indeed, new challenges related to environmental pollution and landscape preservation must be faced. In this sense, clear road pavement surfaces represent an effective technology aimed at guaranteeing environmental-friendly aesthetic pavements. The use of clear synthetic resin as a binder involves several benefits for the mitigation of in-service reached temperatures and the heat distribution within pavements (with appreciable effects on pavement mechanical performance too). The present paper illustrates an experimental study aimed at analysing the chromatic and mechanical properties of a clear synthetic resin and thus its suitability as a binder for road pavement mixes. Chromatic characteristics were assessed through digital image analysis at different aging conditions. A dynamic shear rheometer was used to evaluate the linear viscoelastic properties as well as fatigue and rutting potential of the binder in a wide range of temperatures and frequencies. A conventional 35/50 penetration grade bitumen was also investigated for comparison purposes. The clear resin exhibited limited changes in colour (darkening effects), mainly in the case of short-term aging. On the other hand, a low temperature-dependency of such a binder was observed up to 58°C. Slightly increased aptitude to rutting at the higher temperatures was detected, even if it is worth noting that clear in-service mixtures would achieve lower temperatures than traditional “black” materials at a given environmental condition (air temperature, solar radiation, etc.). The resin also exhibited a softer behaviour, along with an enhanced fatigue resistance. Overall, the studied innovative binder showed promising results in view of its effective use in road paving.
The Use of Steel Slags in Asphalt Pavements: A State-of-the-Art Review
Steel slag is a by-product obtained through the separation of molten steel from impurities in steel-making furnaces. It can be produced by different types of furnaces (blast, basic oxygen, electric arc, ladle furnaces). The reuse of metallurgical slags in road pavements can pursue aims of recycling and environmental sustainability. Based on the extensive literature, the paper presents a state-of-the-art review concerning the use of slags in asphalt pavements, discussing the main controversial literature findings. Slag manufacturing processes, chemical, morphological, and physical characteristics, affect its contribution to the asphalt mixture, when it partially or fully substitutes natural aggregates. Legislative state-of-the-art environmental issues, weathering, and leaching aspects are also discussed. The main mechanical and durability properties of pavements containing different types of slags are analyzed based on laboratory and field studies. Generally, the higher mechanical properties of steel slag suggest that its inclusion in asphalt mixtures can provide high-performance pavement layers (excellent strength and stiffness, superior rutting and fatigue resistance, low moisture susceptibility). However, several research gaps still exist (e.g., mix design and seasoning procedure, bitumen–aggregate affinity, low-temperature behavior, brittleness); they are discussed to direct possible future study efforts to clarify specific technical aspects, such as, for example, the effect of slag morphology and physical properties on the final mix properties and the development of specific mix design guidelines.
Rutting Behavior of Asphalt Surface Layers Designed for Solar Harvesting Systems
Solar harvesting systems applied to asphalt roads consist of pipes or coils installed a few centimeters below the asphalt pavement surface. They work thanks to a circulating fluid able to collect the heat coming from solar irradiation of the pavement surface and convert it into thermal gradients that can be used for electric energy supply. Specific attention must be paid to the design of the asphalt mixtures comprising the system. In this sense, the high in-service temperature rutting potential is one of the main issues to be assessed in such applications since the thermal optimization of asphalt mixes could lead to excessively deformable materials. The present study is a part of a wider research area aimed at developing an efficient asphalt solar collector. Here, a laboratory mixture-scale investigation is proposed to verify the anti-rutting potential of specific asphalt layers that were initially designed based on thermal properties only. Repeated load axial and wheel tracking tests are carried out on limestone- and steel slag-based bituminous mixtures. Overall, the tested layers were not fully able to satisfy the permanent deformation acceptance criteria; in this regard, possible improvements in terms of mix constituents and properties are ultimately addressed.
Advances in the Rheology of Synthetic Binder for Sustainable Road Pavements: An Improved Protocol for DSR Testing
Bituminous binders are thermal-dependent visco-elastic materials commonly used in pavement engineering. However, synthetic binders represent quite a new family of products that can be used in the substitution of conventional binders with various purposes. Among them, clear synthetic resins recently experienced a quick diffusion since they can be employed in the production of sustainable road pavements (which address aesthetic concerns, thermal aspects, etc.). Since specific studies addressing the rheological modeling of clear synthetic binders cannot be found in the literature, the purpose of this research is setting up an advanced rheological protocol to characterize such materials, bridging the existing knowledge gap. An extensive laboratory investigation with the dynamic shear rheometer was carried out in oscillatory mode (amplitude and frequency sweeps) to analyze the stress–strain state of such binders. An innovative test at a constant strain rate was used to construct non-linear master curves, overcoming various criticisms about the stress state of the binder when subjected to time-dependent deformations. Results indicated that, using non-linear data, horizontal and vertical shift factors (functions of temperature and strain rate) can be modeled through power law equations to obtain the master curves. This method was considered suitable for depicting the rheological response of the binders displaying such complex behaviors.
Hydrophobically gated memristive nanopores for neuromorphic applications
Signal transmission in the brain relies on voltage-gated ion channels, which exhibit the electrical behaviour of memristors, resistors with memory. State-of-the-art technologies currently employ semiconductor-based neuromorphic approaches, which have already demonstrated their efficacy in machine learning systems. However, these approaches still cannot match performance achieved by biological neurons in terms of energy efficiency and size. In this study, we utilise molecular dynamics simulations, continuum models, and electrophysiological experiments to propose and realise a bioinspired hydrophobically gated memristive nanopore. Our findings indicate that hydrophobic gating enables memory through an electrowetting mechanism, and we establish simple design rules accordingly. Through the engineering of a biological nanopore, we successfully replicate the characteristic hysteresis cycles of a memristor and construct a synaptic device capable of learning and forgetting. This advancement offers a promising pathway for the realization of nanoscale, cost- and energy-effective, and adaptable bioinspired memristors. Designing efficient nanoscale and adaptable bioinspired memristors remains a challenge. Here, the authors develop a bioinspired hydrophobically gated memristive nanopore capable of learning, forgetting, and retaining memory through an electrowetting mechanism.
Lipid-mediated hydrophobic gating in the BK potassium channel
Structures of the large-conductance, calcium-activated potassium (BK) channel in the Ca 2+  −bound and Ca 2+  −free states have suggested that K + conduction is not gated via a steric closure of the pore-lining helices of the channel, in contrast to the gating mechanism of other 6TM channels. This has raised the question of how gating might occur in the absence of apparent steric hindrance by protein residues. To answer this question, we perform molecular simulations and free-energy calculations to develop a microscopic picture of the gating mechanism. Our results highlight an unexpected role for annular lipids, which appear to be an integral part of the gating machinery. In the Ca 2+  −free (“closed”) pore, methyl groups from lipid alkyl chains can enter the pore through fenestrations between the pore-lining helices. This dynamic occupancy directly contributes to dewetting of the inner-pore cavity, thus hindering ion conduction. In contrast, Ca 2+ binding leads to occlusion of the fenestrations, thus preventing the lipids from entering the pore cavity and permitting pore hydration and ion conduction. This apparent lipid-mediated hydrophobic gating may also explain functional observations that include state-dependent pore accessibility of hydrophobic channel blockers. BK channels regulate potassium flow but lack clear steric gates. Here, authors show that lipid tails enter the pore in the closed state, triggering dewetting and blocking ion flow-revealing a lipid-mediated hydrophobic gating mechanism.
From sea monsters to charismatic megafauna: Changes in perception and use of large marine animals
Marine megafauna has always elicited contrasting feelings. In the past, large marine animals were often depicted as fantastic mythological creatures and dangerous monsters, while also arousing human curiosity. Marine megafauna has been a valuable resource to exploit, leading to the collapse of populations and local extinctions. In addition, some species have been perceived as competitors of fishers for marine resources and were often actively culled. Since the 1970s, there has been a change in the perception and use of megafauna. The growth of marine tourism, increasingly oriented towards the observation of wildlife, has driven a shift from extractive to non-extractive use, supporting the conservation of at least some species of marine megafauna. In this paper, we review and compare the changes in the perception and use of three megafaunal groups, cetaceans, elasmobranchs and groupers, with a special focus on European cultures. We highlight the main drivers and the timing of these changes, compare different taxonomic groups and species, and highlight the implications for management and conservation. One of the main drivers of the shift in perception, shared by all the three groups of megafauna, has been a general increase in curiosity towards wildlife, stimulated inter alia by documentaries (from the early 1970s onwards), and also promoted by easy access to scuba diving. At the same time, environmental campaigns have been developed to raise public awareness regarding marine wildlife, especially cetaceans, a process greatly facilitated by the rise of Internet and the World Wide Web. Currently, all the three groups (cetaceans, elasmobranchs and groupers) may represent valuable resources for ecotourism. Strikingly, the economic value of live specimens may exceed their value for human consumption. A further change in perception involving all the three groups is related to a growing understanding and appreciation of their key ecological role. The shift from extractive to non-extractive use has the potential for promoting species conservation and local economic growth. However, the change in use may not benefit the original stakeholders (e.g. fishers or whalers) and there may therefore be a case for providing compensation for disadvantaged stakeholders. Moreover, it is increasingly clear that even non-extractive use may have a negative impact on marine megafauna, therefore regulations are needed.
Liquid and Vapour Phase of Lavandin (Lavandula × intermedia) Essential Oil: Chemical Composition and Antimicrobial Activity
Essential oils from Lavandula genus and the obtained hybrids are widely used for different purposes such as perfume production in the cosmetic field and for its biological properties. This is the first study on the liquid and vapour phase of Lavandula × intermedia “Grosso” essential oil grown in the Lazio Region, Italy, investigated using headspace coupled to gas chromatography and mass spectrometry (HS-GC/MS). The results showed the most abundant components were linalool and linalyl acetate, followed by 1,8-cineole and terpinen-4-ol, while lavandulyl acetate and borneol were identified as minor compounds, maintaining the same proportion in both the liquid and vapour phase. Furthermore, we tested lavandin liquid and vapour phase essential oil on gram-negative bacteria (Escherichia coli, Acinetobacter bohemicus, and Pseudomonas fluorescens) and gram-positive bacteria (Bacillus cereus and Kocuria marina).