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The rare earth elements (REE) have attracted much attention in recent years, being viewed as critical metals because of China’s domination of their supply chain. This is despite the fact that REE enrichments are known to exist in a wide range of settings, and have been the subject of much recent exploration. Although the REE are often referred to as a single group, in practice each individual element has a specific set of end-uses, and so demand varies between them. Future demand growth to 2026 is likely to be mainly linked to the use of NdFeB magnets, particularly in hybrid and electric vehicles and wind turbines, and in erbium-doped glass fiber for communications. Supply of lanthanum and cerium is forecast to exceed demand. There are several different types of natural (primary) REE resources, including those formed by high-temperature geological processes (carbonatites, alkaline rocks, vein and skarn deposits) and those formed by low-temperature processes (placers, laterites, bauxites and ion-adsorption clays). In this paper, we consider the balance of the individual REE in each deposit type and how that matches demand, and look at some of the issues associated with developing these deposits. This assessment and overview indicate that while each type of REE deposit has different advantages and disadvantages, light rare earth-enriched ion adsorption types appear to have the best match to future REE needs. Production of REE as by-products from, for example, bauxite or phosphate, is potentially the most rapid way to produce additional REE. There are still significant technical and economic challenges to be overcome to create substantial REE supply chains outside China.

Global resources of heavy Rare Earth Elements (REE) are dominantly sourced from Chinese regolith-hosted ion-adsorption deposits in which the REE are inferred to be weakly adsorbed onto clay minerals. Similar deposits elsewhere might provide alternative supply for these high-tech metals, but the adsorption mechanisms remain unclear and the adsorbed state of REE to clays has never been demonstrated in situ. This study compares the mineralogy and speciation of REE in economic weathering profiles from China to prospective regoliths developed on peralkaline rocks from Madagascar. We use synchrotron X-ray absorption spectroscopy to study the distribution and local bonding environment of Y and Nd, as proxies for heavy and light REE, in the deposits. Our results show that REE are truly adsorbed as easily leachable 8- to 9-coordinated outer-sphere hydrated complexes, dominantly onto kaolinite. Hence, at the atomic level, the Malagasy clays are genuine mineralogical analogues to those currently exploited in China. Global resources of heavy Rare Earth Elements (REE) are dominantly sourced from Chinese regolith-hosted ion-adsorption deposits, yet the adsorption mechanisms remain unclear. Here, the authors find that heavy REE are adsorbed as easily leachable 8-coordinated outer-sphere hydrated complexes, dominantly onto kaolinite, in clays from both China and Madagascar.

Caldera-forming volcanic eruptions are among the most dangerous, and can generate extensive pyroclastic deposits and deliver ash into global atmospheric circulation systems. As calderas collapse, the eruptions can deposit thick proximal ignimbrite sequences and thinner ignimbrites more distally. However, the proximal record of caldera collapse is often obscured by later intrusions, volcanism, faults, alteration, water and sediments, which significantly limits our understanding of these eruptions. A Palaeogene caldera system in central Arran, western Scotland, preserves a rare proximal caldera-fill succession, the Arran Volcanic Formation. This caldera largely comprises highly heterogeneous ignimbrites and minor intra-caldera sedimentary rocks. The current level of erosion, and the general absence of faults, intrusions and sediments, allows a complex stratigraphy and collapse history to be determined, which can be linked to changing eruptive styles at a constantly evolving volcano. The first recorded phase was eruption of a homogeneous rhyolitic lava-like tuff, deposited from high temperature, high mass-flux pyroclastic density currents generated from low fountaining columns that retained heat. A succeeding phase of highly explosive Plinian eruptions, marked by a thick blanket of massive lapilli tuffs, was then followed by piston-like caldera collapse and erosion of steep caldera walls. Volcanism then became generally less explosive, with predominantly lava-like and eutaxitic tuffs and cognate spatter-rich agglomerates interbedded with non-homogenous lapilli tuffs. High topographic relief between distinct units indicate long periods of volcanic quiescence, during which erosive processes dominated. These periods are, in several places, marked by sedimentary rocks and evidence for surface water, which includes a localised basaltic-andesitic phreatomagmatic tuff. The caldera-forming eruptions recorded by the Arran Volcanic Formation provide an important insight into caldera collapse processes and proximal ignimbrite successions. The lack of thick autobreccias and lithic-rich lapilli- and block-layers indicates that subsidence was relatively gradual and incremental in this caldera, and not accompanied by catastrophic wall collapse during eruption. The relatively horizontal nature of the caldera-fill units and paucity of intra-caldera faulting indicate that piston subsidence was the dominant method of collapse, with a relatively coherent caldera floor bounded by a steeply dipping ring fault. Possible resurgence may have caused later doming of the floor and radial distribution of subsequent ignimbrites and sedimentary rocks. Our work emphasises the continued need for field studies of caldera volcanoes.

Artisanal and small-scale mining is an important livelihood activity in many biodiversity hotspots. There is substantial international concern about the negative impact of artisanal and small-scale mining on biodiversity, yet in most places this remains poorly understood. We explore the impacts of a high-profile mining rush: the 2016 sapphire rush at Bemainty, Eastern Madagascar, where tens of thousands of miners descended on a protected forest. Media coverage claimed the rush caused hundreds of hectares of deforestation and threatened lemur populations. Using the synthetic control method to estimate counterfactual outcomes, we find no evidence that mining increased forest loss or degradation. Supported by informal interviews and a lemur survey, we argue that mining at Bemainty had limited impacts on the surrounding forest, relative to other threats. Our results highlight the heterogeneity of environmental impacts from artisanal and small-scale mining and emphasize the need for more robust evaluations to inform context-specific policies.

Zircon is a key mineral in geochemical and geochronological studies in a range of geological settings as it is mechanically and chemically robust. However, distortion of its crystal lattice can facilitate enhanced diffusion of key elements such as U and Pb. Electron backscatter diffraction (EBSD) analysis of ninety-nine zircons from the Lewisian Gneiss Complex (LGC) of northwest Scotland has revealed five zircons with lattice distortion. The distortion can take the form of gradual bending of the lattice or division of the crystal into subgrains. Zircon lattices are distorted because of either post-crystallisation plastic distortion or growth defects. Three of the five distorted zircons, along with many of the undistorted zircons in the population, were analysed by ion microprobe to measure U and Pb isotopes, Ti and REEs. Comparison of Th/U ratio, 207 Pb/ 206 Pb age, REE profile and Ti concentration between zircons with and without lattice distortion suggests that the distortion is variably affecting the concentration of these trace elements and isotopes within single crystals, within samples and between localities. REE patterns vary heterogeneously, sometimes relatively depleted in heavy REEs or lacking a Eu anomaly. Ti-in-zircon thermometry records temperatures that were either low (~700 °C) or high (>900 °C) relative to undistorted zircons. One distorted zircon records apparent 207 Pb/ 206 Pb isotopic ages (−3.0 to +0.3 % discordance) in the range of ~2,420–2,450 Ma but this does not correlate with any previously dated tectonothermal event in the LGC. Two other distorted zircons give discordant ages of 2,331 ± 22 and 2,266 ± 40 Ma, defining a discordia lower intercept within error of a late amphibolite-facies tectonothermal event. This illustrates that Pb may be mobilised in distorted zircons at lower metamorphic grade than in undistorted zircons. These differences in trace element abundances and isotope systematics in distorted zircons relative to undistorted zircons are generally interpreted to have been facilitated by subgrain walls. Trace elements and isotopes would have moved from undistorted lattice into these subgrain walls as their chemical potential is modified due to the presence of the dislocations which make up the subgrain wall. Subgrain walls provided pathways for chemical exchange between crystal and surroundings. Only five per cent of zircons in this population have lattice distortion suggesting it will not have a major impact on zircon geochronology studies, particularly as three of the five distorted zircons are from strongly deformed rocks not normally sampled in such studies. However, this does suggest there may be a case for EBSD analysis of zircons prior to geochemical analysis when zircons from highly deformed rocks are to be investigated.

The relative depletion of high field strength elements (HFSE), such as Nb, Ta and Ti, on normalised trace-element plots is a geochemical proxy routinely used to fingerprint magmatic processes linked to Phanerozoic subduction. This proxy has increasingly been applied to ultramafic-mafic units in Archaean cratons, but as these assemblages have commonly been affected by high-grade metamorphism and hydrothermal alteration/metasomatism, the likelihood of element mobility is high relative to Phanerozoic examples. To assess the validity of HFSE anomalies as a reliable proxy for Archaean subduction, we here investigate their origin in ultramafic rocks from the Ben Strome Complex, which is a 7 km2 ultramafic-mafic complex in the Lewisian Gneiss Complex of NW Scotland. Recently interpreted as a deformed layered intrusion, the Ben Strome Complex has been subject to multiple phases of high-grade metamorphism, including separate granulite- and amphibolite-facies deformation events. Additional to bulk-rock geochemistry, we present detailed petrography, and major- and trace-element mineral chemistry for 35 ultramafic samples, of which 15 display negative HFSE anomalies. Our data indicate that the magnitude of HFSE anomalies in the Ben Strome Complex are correlated with light rare earth-element (LREE) enrichment likely generated during interaction with H2O and CO2-rich hydrothermal fluids associated with amphibolitisation, rather than primary magmatic (subduction-related) processes. Consequently, we consider bulk-rock HFSE anomalies alone to be an unreliable proxy for Archaean subduction in Archaean terranes that have experienced multiple phases of high-grade metamorphism, with a comprehensive assessment of element mobility and petrography a minimum requirement prior to assigning geodynamic interpretations to bulk-rock geochemical data.

Rare earth elements (REE) are essential raw materials used in modern technology. Current production of REE is dominated by hard-rock mining, particularly in China, which typically requires high energy input. In order to expand the resource base of the REE, it is important to determine what alternative sources exist. REE placers have been known for many years, and require less energy than mining of hard rock, but the REE ore minerals are typically derived from eroded granitic rocks and are commonly radioactive. Other types of REE placers, such as those derived from volcanic activity, are rare. The Aksu Diamas heavy mineral placer in Turkey has been assessed for potential REE extraction as a by-product of magnetite production, but its genesis was not previously well understood. REE at Aksu Diamas are hosted in an array of mineral phases, including apatite, chevkinite group minerals (CGM), monazite, allanite and britholite, which are concentrated in lenses and channels in unconsolidated Quaternary sands. Fingerprinting of pyroxene, CGM, magnetite and zircon have identified the source of the placer as the nearby Gölcük alkaline volcanic complex, which has a history of eruption throughout the Plio-Quaternary. Heavy minerals were eroded from tephra and reworked into basinal sediments. This type of deposit may represent a potential resource of REE in other areas of alkaline volcanism.

The physical and chemical evolution of the Earth is driven by geodynamic cycles that are global in scale, operating over 4.57 Ga of Earth’s history. Some processes are truly cyclic, e.g., the Wilson Cycle, while others are irreversible (e.g., core formation). Heat and mass transfer between the lowermost mantle (e.g., core-mantle boundary) and the surface drives these global geodynamic processes. Subduction of lithospheric plates transfers cool fractionated material into the lower mantle and leads indirectly to the formation of new oceanic lithosphere, while the rise of thermochemical plumes recycles the remnants of these plates back to the surface, driven by heat transfer across the core–mantle boundary. These global geodynamic cycles are responsible for hotspot volcanism, the formation of continental crust, collisional orogenies, continental rifting, subduction zone processes (arcs, accretionary prisms), and ore deposits. Each of these presents opportunities for investigation by continental scientific drilling. In addition, these cycles affect other processes that are targets of continental scientific drilling: the origin and evolution of life and an oxygenated atmosphere, the impact of large volcanic eruptions on climate, and geological hazards such as earthquakes and volcanic eruptions. In this paper, we present the scientific rationale for continental scientific drilling to study global geodynamic processes, review past successes in this realm that were sponsored in part by ICDP, and suggest potential new targets for drilling campaigns that focus on solid earth evolution. This paper builds on discussions at the 2013 ICDP Science Meeting on the future of continental scientific drilling, held in Potsdam in November 2013.

In NW Scotland, several alkaline intrusive complexes of Silurian age intrude the Caledonian orogenic front. The most northerly is the Loch Loyal Syenite Complex, which is divided into three separate intrusions (Ben Loyal, Beinn Stumanadh and Cnoc nan Cuilean). Mapping of the Cnoc nan Cuilean intrusion shows two main zones: a Mixed Syenite Zone (MZ) and a Massive Leucosyenite Zone (LZ), with a gradational contact. The MZ forms a lopolith, with multiple syenitic lithologies, including early basic melasyenites and later felsic leucosyenites. Leucosyenite melts mixed and mingled with melasyenites, resulting in extreme heterogeneity within the MZ. Continued felsic magmatism resulted in formation of the relatively homogeneous LZ, invading western parts of the MZ and now forming the topographically highest terrane. The identification of pegmatites, microgranitic veins and unusual biotite-magnetite veins demonstrates the intrusion's complex petrogenesis. Cross-sections have been used to create a novel 3D GoCad™ model contributing to our understanding of the intrusion. The Loch Loyal Syenite Complex is known to have relatively high concentrations of rare earth elements (REEs), and thus the area has potential economic and strategic value. At Cnoc nan Cuilean, abundant REE-bearing allanite is present within melasyenites of the MZ. Extensive hydrothermal alteration of melasyenites here formed steeply dipping biotite-magnetite veins, most enriched in allanite and other REE-bearing accessories. This study has thus identified the area of greatest importance for further study of REE enrichment processes in the Cnoc nan Cuilean intrusion.

The study of volcanic rocks and igneous centres has long been a classic part of geological research. Despite the lack of active volcanism, the British Isles have been a key centre for the study of igneous rocks ever since ancient lava flows and excavated igneous centres were recognized there in the 18th century (Hutton, 1788). This led to some of the earliest detailed studies of petrology. The starting point for many of these studies was the British Palaeogene Igneous Province (BPIP; formerly known as the ‘British Tertiary’ (Judd, 1889), and still recognized by this name by many geologists around the globe). This collection of lavas, volcanic centres and sill/dyke swarms covers much of the west of Scotland and the Antrim plateau of Northern Ireland, and together with similar rocks in the Faroe Islands, Iceland and Greenland forms a world-class Large Igneous Province. This North Atlantic Igneous Province (NAIP) began to form through continental rifting above a mantle plume at c. 60 Ma, and subsequently evolved as North America separated from Europe, creating the North Atlantic Ocean.