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"HAHN, NATHAN"
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Energy storage emerging
by
Mueller, Karl T.
,
Persson, Kristin A.
,
Zavadil, Kevin R.
in
Applied Physical Sciences
,
Arthur M. Sackler on the Status and Challenges in Decarbonizing our Energy Landscape
,
Artificial intelligence
2020
Energy storage is an integral part of modern society. A contemporary example is the lithium (Li)-ion battery, which enabled the launch of the personal electronics revolution in 1991 and the first commercial electric vehicles in 2010. Most recently, Li-ion batteries have expanded into the electricity grid to firm variable renewable generation, increasing the efficiency and effectiveness of transmission and distribution. Important applications continue to emerge including decarbonization of heavy-duty vehicles, rail, maritime shipping, and aviation and the growth of renewable electricity and storage on the grid. This perspective compares energy storage needs and priorities in 2010 with those now and those emerging over the next few decades. The diversity of demands for energy storage requires a diversity of purpose-built batteries designed to meet disparate applications. Advances in the frontier of battery research to achieve transformative performance spanning energy and power density, capacity, charge/discharge times, cost, lifetime, and safety are highlighted, along with strategic research refinements made by the Joint Center for Energy Storage Research (JCESR) and the broader community to accommodate the changing storage needs and priorities. Innovative experimental tools with higher spatial and temporal resolution, in situ and operando characterization, first-principles simulation, high throughput computation, machine learning, and artificial intelligence work collectively to reveal the origins of the electrochemical phenomena that enable new means of energy storage. This knowledge allows a constructionist approach to materials, chemistries, and architectures, where each atom or molecule plays a prescribed role in realizing batteries with unique performance profiles suitable for emergent demands.
Journal Article
Identifying conservation technology needs, barriers, and opportunities
2022
Amid accelerating threats to species and ecosystems, technology advancements to monitor, protect, and conserve biodiversity have taken on increased importance. While most innovations stem from adaptation of off-the-shelf devices, these tools can fail to meet the specialized needs of conservation and research or lack the support to scale beyond a single site. Despite calls from the conservation community for its importance, a shift to bottom-up innovation driven by conservation professionals remains limited. We surveyed practitioners, academic researchers, and technologists to understand the factors contributing to or inhibiting engagement in the collaborative process of technology development and adoption for field use and identify emerging technology needs. High cost was the main barrier to technology use across occupations, while development of new technologies faced barriers of cost and partner communication. Automated processing of data streams was the largest emerging need, and respondents focused mainly on applications for individual-level monitoring and automated image processing. Cross-discipline collaborations and expanded funding networks that encourage cyclical development and continued technical support are needed to address current limitations and meet the growing need for conservation technologies.
Journal Article
Highly reversible Zn metal anode enabled by sustainable hydroxyl chemistry
2022
Rechargeable Zn metal batteries (RZMBs) may provide a more sustainable and lower-cost alternative to established battery technologies in meeting energy storage applications of the future. However, the most promising electrolytes for RZMBs are generally aqueous and require high concentrations of salt(s) to bring efficiencies toward commercially viable levels and mitigate water-originated parasitic reactions including hydrogen evolution and corrosion. Electrolytes based on nonaqueous solvents are promising for avoiding these issues, but full cell performance demonstrations with solvents other than water have been very limited. To address these challenges, we investigated MeOH as an alternative electrolyte solvent. These MeOH-based electrolytes exhibited exceptional Zn reversibility over a wide temperature range, with a Coulombic efficiency > 99.5% at 50% Zn utilization without cell short-circuit behavior for > 1,800 h. More important, this remarkable performance translates well to Zn ∥ metal-free organic cathode full cells, supporting < 6% capacity decay after > 800 cycles at −40 °C.
Journal Article
Near-ambient oxidation of melt-processed aluminum-mercury alloy compounds under air with controlled humidity
2022
Aluminum-mercury alloys prepared by a thermal processing route were exposed to humid air environments under controlled temperature and humidity. The mass changes and energetics associated with the ensuing reaction were monitored by thermal analysis techniques, and it was found that a surprising inverse relationship exists between reaction rate and temperature under constant mass flow rate of water vapor. Additionally, at constant temperature there exists a water mass flow rate threshold below which no reaction occurs. The presence of mercury in the alloy at a gravimetric loading of 120 ppm or less produces no measurable reaction with humid air under the conditions employed, while higher mercury loadings result in the formation of voluminous low-density alumina filaments. Increasing the surface area of a bulk alloy sample through mechanical attrition reduces the rate and extent of reaction, contrary to the behavior of typical surface-moderated reactions. These findings demonstrate that “homogeneously” distributed Hg in Al, as produced by our thermal processing route, generally retains its strongly activating behavior in air. Furthermore, the systematic variation in Hg composition and reaction conditions has quantified the thresholds required for sustaining air-reactivity of such materials.
Graphical abstract
Journal Article
Crop use structures resource selection strategies for African elephants in a human‐dominated landscape
by
Mbise, Noel
,
Wall, Jake
,
Deninger‐Snyder, Kristen
in
African elephant (Loxodonta africana)
,
Agricultural land
,
Animal behavior
2024
To conserve wide‐ranging species in degraded landscapes, it is essential to understand how the behavior of animals changes in relation to the degree and composition of modification. Evidence suggests that large inter‐individual variation exists in the propensity for use of degraded areas and may be driven by both behavioral and landscape factors. The use of cultivated lands by wildlife is of particular interest, given the importance of reducing human‐wildlife conflicts and understanding how such areas can function as biodiversity buffers. African elephant space use can be highly influenced by human activity and the degree to which individuals crop‐raid. We analyzed GPS data from 56 free‐ranging elephants in the Serengeti‐Mara Ecosystem using resource selection functions (RSFs) to assess how crop use may drive patterns of resource selection and space use within a population. We quantified drivers of similarity in resource selection across individuals using proximity analysis of individual RSF coefficients derived from random forest models. We found wide variation in RSF coefficient values between individuals indicating strongly differentiated resource selection strategies. Proximity assessment indicated the degree of crop use in the dry season, individual repeatability, and time spent in unprotected areas drove similarity in resource selection patterns. Crop selection was also spatially structured in relation to agricultural fragmentation. In areas with low fragmentation, elephants spent less time in crops and selected most strongly for crops further from protected area boundaries, but in areas of high fragmentation, elephants spent twice as much time in crops and selected most strongly for crops closer to the protected area boundary. Our results highlight how individual differences and landscape structure can shape use of agricultural landscapes. We discuss our findings in respect to the conservation challenges of human‐elephant conflict and incorporating behavioral variation into human‐wildlife coexistence efforts. We assessed patterns of similarity in resource selection across individual elephants linked to crop use, and identified how fragmentation influenced spatial variation in crop selection across the landscape. In areas with low fragmentation, elephants spent less time in crops and selected most strongly for crops further from protected area boundaries, but in areas of high fragmentation, elephants spent twice as much time in crops and selected most strongly for crops closer to the protected area boundary. Our results highlight how individual differences and landscape structure can shape use of agricultural landscapes.
Journal Article
Alkali‐Ion‐Assisted Activation of ε‐VOPO4 as a Cathode Material for Mg‐Ion Batteries
2024
Rechargeable multivalent‐ion batteries are attractive alternatives to Li‐ion batteries to mitigate their issues with metal resources and metal anodes. However, many challenges remain before they can be practically used due to the low solid‐state mobility of multivalent ions. In this study, a promising material identified by high‐throughput computational screening is investigated, ε‐VOPO4, as a Mg cathode. The experimental and computational evaluation of ε‐VOPO4 suggests that it may provide an energy density of >200 Wh kg−1 based on the average voltage of a complete cycle, significantly more than that of well‐known Chevrel compounds. Furthermore, this study finds that Mg‐ion diffusion can be enhanced by co‐intercalation of Li or Na, pointing at interesting correlation dynamics of slow and fast ions. A novel cathode candidate for Mg‐ion batteries is revealed with the help of high‐throughput screening. The experimental and computational evaluation presented in this study provides a deeper understanding on promising electrochemical performance of ε‐VOPO4 and the dual cation effect.
Journal Article
The lame man at the pool of Bethesda: Christological and doxological significance of characterisation in John 5
2021
In any research of the biblical themes in Scriptures, the exegete must exercise discipline in strictly adhering to an exegetical process wherein the text is permitted to speak for itself in the context of the passage. This article therefore explored the literary traits and analysed characterisations in the story of the lame man at the pool of Bethesda as portrayed in John 5 through a 'narratological and exegetical' approach, considering literary, social, cultural and historical criticism with significant attention given to the text of the author or narrator. It is very important to know the author's theological viewpoint as seen in the characterisation of an anonymous character in the related gospel narrative, because it may be easily be overlooked due to the lack of attention for a minor character. The author's theological point of view is revealed in the characterisation of the lame man, the Jewish religious leaders, and of Jesus. Although the lame man himself is generally regarded as one of the 'minor characters' who appears in the gospel, the narrative of the lame man's healing is an important part of John's Christology and doxology, establishing Jesus as the Son whom God the Father sent to do God's work not for his own glory, but for the glory of God the Father. An analysis is undertaken of the literary traits and various characterisations evident in the seven scenes of John 5's account of the healing of the lame man, comparing him with other minor characters in John 4 and 9 who were healed. Contribution In this article a narratological and exegetical approach is employed to identify the Christological and doxological significances in John 5 by exploring the literary traits of the narrative point of view and character presentation through the theological perspective of the narrator.
Journal Article
Unmanned aerial vehicles mitigate human–elephant conflict on the borders of Tanzanian Parks: a case study
by
Konuche, Jonathan
,
Keyyu, Julius
,
Palminteri, Suzanne
in
Agriculture
,
Animal behavior
,
case studies
2017
Protected areas across the range of the African savannah elephant Loxodonta africana are increasingly being surrounded and isolated by agriculture and human settlements. Conflicts between people and crop-raiding elephants regularly lead to direct reprisals and diminish community support for conservation. We report on field trials in northern Tanzania that employed a new, humane way for wildlife managers to move elephants away from conflict zones, from distances of > 100 m, thereby enhancing the safety of wildlife managers, farmers and elephants. We deployed 10 unmanned aerial vehicles (drones) piloted by five trained teams of wildlife managers in the Tarangire–Manyara and Serengeti ecosystems. Game Scouts deployed the drones opportunistically during crop-raiding events at the peak of the maize ripening period in 2015 and 2016. In 100% of trials (n = 51) elephants responded to the presence of a drone by departing rapidly from crop fields (n = 38) and settlements (n = 13). The cost of five teams responsible for 617 km2 in Tarangire–Manyara was estimated to be USD 15,520 for 1 year, and all drones remained operational for the duration of the study. The initial success of this tool warrants further testing of the utility of small unmanned aerial vehicles as part of the toolbox for wildlife managers and communities dealing with high levels of conflict with wildlife.
Journal Article
Alkali‐Ion‐Assisted Activation of ε‐VOPO 4 as a Cathode Material for Mg‐Ion Batteries
2024
Rechargeable multivalent‐ion batteries are attractive alternatives to Li‐ion batteries to mitigate their issues with metal resources and metal anodes. However, many challenges remain before they can be practically used due to the low solid‐state mobility of multivalent ions. In this study, a promising material identified by high‐throughput computational screening is investigated, ε‐VOPO 4 , as a Mg cathode. The experimental and computational evaluation of ε‐VOPO 4 suggests that it may provide an energy density of >200 Wh kg −1 based on the average voltage of a complete cycle, significantly more than that of well‐known Chevrel compounds. Furthermore, this study finds that Mg‐ion diffusion can be enhanced by co‐intercalation of Li or Na, pointing at interesting correlation dynamics of slow and fast ions.
Journal Article
EarthRanger: An open‐source platform for ecosystem monitoring, research and management
by
Jones, Bruce
,
Krautwurst, Joshua
,
Reid, Andrea
in
Applications programs
,
Biodiversity
,
Configuration management
2024
Effective approaches are needed to conserve the planet's remaining wildlife and wilderness landscapes, especially concerning global biodiversity conservation targets. Here, we present a new software system called EarthRanger: an open‐source platform built to help monitor, research and manage ecosystems. EarthRanger consists of seven main components (Core Server, API, Storage, Gundi, Web App, Mobile App, Ecoscope) that provide functionality for data (i) aggregation & collection, (ii) storage & management, (iii) real‐time and post hoc analysis, (iv) visualisation and (v) dissemination. The mobile application provides field‐based data recording and visualisation tools. EarthRanger may be deployed for single project use or can aggregate across multiple geographies as a centralised hub. EarthRanger can be used to collect standardised tracking data (e.g. from wildlife collars, vehicles and ranger patrols) and configurable event information (e.g. a singular recording with associated user‐defined attribute information such as a wildlife sighting or encounter with a poacher). Since development began in 2015, the platform has (at the time of writing) been deployed at over 500 sites across 70 countries and with myriad configurations and objectives. EarthRanger has improved the ability to monitor data feeds and manage conservation‐related operations in real time. For instance, the deployment of EarthRanger by African Parks has led to the removal of over 50,000 snares, steady population growth of key species of concern and near cessation of poaching. In Liwonde's protected area, enhanced mitigation efforts supported by EarthRanger reduced the number of deaths from wildlife conflict by more than 91%. EarthRanger is also providing a platform to enhance standardisation, aggregation, transfer and long‐term storage of ecological information and promote collaboration between groups conducting protected area management and ecology and biodiversity research.
Journal Article