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Wildfires impact forest ecosystems, affecting tree survival and physiological responses. This study explored the effects of surface fires on Pinus densiflora and Quercus variabilis, assessing mortality, internal injuries, and canopy health. By 2024, P. densiflora had an 18.0% mortality rate, whereas Q. variabilis exhibited no crown dieback. Morphological traits, including tree height, the bark scorch index (BSI), and bark thickness, influenced fire resistance. Despite superior stand characteristics, P. densiflora showed higher mortality due to thin bark, whereas Q. variabilis maintained xylem integrity. While sonic tomography (SoT) showed no significant differences, electrical resistance tomography (ERT) detected physiological stress, with higher ERTR and ERTY area ratios correlating with mortality risk. Notably, F-W-W classified trees showed elevated resistance a year before mortality, suggesting ERT as a predictive tool. ERTR values exceeding 15.0% were associated with a 37.5% mortality rate, whereas ERTB values below 55.0% corresponded to 42.9% mortality. Despite fire exposure, canopy responses, including chlorophyll fluorescence and photosynthetic efficiency, remained stable, indicating that the surviving trees maintained functional integrity. This study underscores ERT’s efficacy in diagnosing fire-induced stress and predicting mortality risk. The findings highlight species-specific diagnostic criteria and inform post-fire management, supporting forest resilience through the early detection of high-risk trees and improved restoration strategies.

This thesis is comprised of two investigations with a draft of manuscript based on research from chapter 1. The first chapter presents the syntheses and characterization of ruthenium polypyridyl complexes: Rubpy(DMQpy) 2(PF6)6 and Ru(DMQpy)3(PF6) 8. These complexes, which may have to be useful as 4-electron or 6-electron reducing agents, are synthesized and characterized using UV-visible spectroscopy, fluorescence spectrophotometry, electrochemistry, and NMR spectroscopy. The second chapter presents the syntheses and characterizations of mono- and bis-osmium pentaammine complexes with a pyridyl viologen ligand. The electron transfer in the mixed-valence complex was investigated using spectroelectrochemistry and NIR spectroscopy.

Using a fumigation sterilizer (Dazomet) for nematode control, this study determined the effect of soil sterilization on the quantity and quality of the growth of Pinus densiflora Siebold & Zucc. and Larix kaempferi (Lamb.) Carrière seedlings in an open-field nursery at Jeongseon-gun, Kangwon-do, Republic of Korea. Most soil nematodes disappeared after fumigant sterilization. The organic matter content, cation exchange capacity, and Mg2+ content of the soil increased significantly, but the electrical conductivity (EC) decreased. The quantity of pine and larch seedlings was highly correlated with the soil nematode density. The soil properties changed due to soil fumigation, which affected the growth of both species. Pine seedling growth was affected by the soil chemical properties, such as available phosphorus (AP), Ca2+, Mg2+, and EC, and the growth of larch seedlings was affected by the EC and nematode density. The quality of the pine seedlings improved, whereas that of larch did not. This was a result of the difference in their tolerance to soil salinity. The seedling quality index (SQI) of the two species was related to the EC, but the pine seedlings were more affected by the EC, indicating that the control of soil nematodes by fumigant treatment significantly increased the quantity of seedlings produced and partly improved their quality. Soil management using a fumigant treatment was more efficient for producing pine seedlings than larch. Our results can be used to improve agricultural and forestry economics.