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Electrolyte-gated organic transistors offer low bias operation facilitated by direct contact of the transistor channel with an electrolyte. Their operation mode is generally defined by the dimensionality of charge transport, where a field-effect transistor allows for electrostatic charge accumulation at the electrolyte/semiconductor interface, whereas an organic electrochemical transistor (OECT) facilitates penetration of ions into the bulk of the channel, considered a slow process, leading to volumetric doping and electronic transport. Conducting polymer OECTs allow for fast switching and high currents through incorporation of excess, hygroscopic ionic phases, but operate in depletion mode. Here, we show that the use of glycolated side chains on a thiophene backbone can result in accumulation mode OECTs with high currents, transconductance, and sharp subthreshold switching, while maintaining fast switching speeds. Compared with alkylated analogs of the same backbone, the triethylene glycol side chains shift the mode of operation of aqueous electrolyte-gated transistors from interfacial to bulk doping/transport and show complete and reversible electrochromism and high volumetric capacitance at low operating biases. We propose that the glycol side chains facilitate hydration and ion penetration, without compromising electronic mobility, and suggest that this synthetic approach can be used to guide the design of organic mixed conductors.

Organic electrochemical transistors (OECTs) are receiving significant attention due to their ability to efficiently transduce biological signals. A major limitation of this technology is that only p-type materials have been reported, which precludes the development of complementary circuits, and limits sensor technologies. Here, we report the first ever n-type OECT, with relatively balanced ambipolar charge transport characteristics based on a polymer that supports both hole and electron transport along its backbone when doped through an aqueous electrolyte and in the presence of oxygen. This new semiconducting polymer is designed specifically to facilitate ion transport and promote electrochemical doping. Stability measurements in water show no degradation when tested for 2 h under continuous cycling. This demonstration opens the possibility to develop complementary circuits based on OECTs and to improve the sophistication of bioelectronic devices. Organic electrochemical transistors transduce ionic to electronic signals in aqueous solutions, holding promise for biological sensing applications. Here, Giovannitti et al. report an ambipolar organic electrochemical transistor, based on a conjugated copolymer, which has a high stability in water.

The low-frequency modal and non-modal linear dynamics of an incompressible, pressure-gradient-induced turbulent separation bubble (TSB) are investigated, with the objective of studying the mechanism responsible for the low-frequency contraction and expansion (breathing) commonly observed in experimental studies. The configuration of interest is a TSB generated on a flat test surface by a succession of adverse and favourable pressure gradients. The base flow selected for the analysis is the average TSB from the direct numerical simulation of Coleman et al. (J. Fluid Mech., vol. 847, 2018, pp. 28–70). Global mode analysis reveals that the eigenmodes of the linear operator are damped for all frequencies and wavenumbers. Furthermore, the least damped eigenmode appears to occur at zero frequency and low, non-zero spanwise wavenumber when scaled with the separation length. Resolvent analysis is then employed to examine the forced dynamics of the flow. At low frequency, a region of low, non-zero spanwise wavenumber is also discernible, where the receptivity appears to be driven by the identified weakly damped global mode. The corresponding optimal energy gain is shown to have the shape of a first-order, low-pass filter with a cut-off frequency consistent with the low-frequency unsteadiness in TSBs. The results from resolvent analysis are compared to the unsteady experimental database of Le Floc'h et al. (J. Fluid Mech., vol. 902, 2020, A13) in a similar TSB flow. The alignment between the optimal response and the first spectral proper orthogonal decomposition mode computed from the experiments is shown to be close to $95\\,\\%$, while the spanwise wavenumber of the optimal response is consistent with that of the low-frequency breathing motion captured experimentally. This indicates that the fluctuations observed experimentally at low frequency closely match the response computed from resolvent analysis. Based on these results, we propose that the forced dynamics of the flow, driven by the weakly damped global mode, serve as a plausible mechanism for the origin of the low-frequency breathing motion commonly observed in experimental studies of TSBs.

Conventional semiconducting polymer synthesis typically involves transition metal-mediated coupling reactions that link aromatic units with single bonds along the backbone. Rotation around these bonds contributes to conformational and energetic disorder and therefore potentially limits charge delocalisation, whereas the use of transition metals presents difficulties for sustainability and application in biological environments. Here we show that a simple aldol condensation reaction can prepare polymers where double bonds lock-in a rigid backbone conformation, thus eliminating free rotation along the conjugated backbone. This polymerisation route requires neither organometallic monomers nor transition metal catalysts and offers a reliable design strategy to facilitate delocalisation of frontier molecular orbitals, elimination of energetic disorder arising from rotational torsion and allowing closer interchain electronic coupling. These characteristics are desirable for high charge carrier mobilities. Our polymers with a high electron affinity display long wavelength NIR absorption with air stable electron transport in solution processed organic thin film transistors. Semiconducting polymers are usually prepared by transition metal mediated coupling reactions that cause problems for sustainability and biological applications. Here the authors synthesise fused electron deficient polymers that are air stable and have high electron affinities, via metal free aldol polymerisation reactions.

Spectral degeneracies where eigenvalues and eigenvectors simultaneously coalesce, also known as exceptional points, are a natural consequence of the strong non-normality of the Orr–Sommerfeld operator describing the evolution of infinitesimal disturbances in parallel shear flows. While the resonances associated with these points give rise to algebraic growth, the development of non-modal stability theory exploiting specific perturbation structures with much larger potential for transient energy growth has led to waning interest in spectral degeneracies. The appearance of subharmonic eigenvalue orbits, recently discovered in the periodic spectrum of pulsating Poiseuille flow, can be traced back to the coalescence of eigenvalues at exceptional points. We present a thorough analysis of the spectral properties of the linear operator to identify exceptional points and accurately map the prevalence of subharmonic eigenvalue orbits for a large range of pulsation amplitudes and frequencies. This information is then combined with solutions of the linear initial value problem to analyse the impact of the appearance of these orbits on the temporal evolution of linear disturbances in pulsating Poiseuille flow. The periodic amplification phases are shown to be heralded by repeated non-normal growth bursts that are intensified by the formation of subharmonic orbits involving the leading eigenvalues. These bursts are associated with the change of alignment of the perturbation from the decaying towards the amplified branch of the subharmonic eigenvalue orbits in a so-called branch transition process.

A global transient linear stability analysis of the three-dimensional time-dependent flow around an aerofoil undergoing small-amplitude pitching motion is performed using the optimally time-dependent (OTD) framework. The most salient linear instabilities associated with the instantaneous basic state are computed and tracked over time. The resulting OTD modes reflect the variations in the basic state and can be used as predictors of its spatial and temporal evolution, including the formation of a laminar separation bubble and its gradual spanwise modulation via primary global instability, leading to secondary instability and finally rapid breakdown to turbulence. The study confirms and expands upon earlier stability analyses of the same case based on the local properties of spanwise averaged velocity profiles in the bubble that predicted the onset of absolute instability soon followed by rapid breakdown of the separation bubble. The three-dimensional structure of the most unstable OTD mode is extracted, which compares well with both the locally absolutely unstable mode and the evolution of the basic state itself.

High salt consumption is an important risk factor of elevated blood pressure. In Bangladesh about 20 million people are at high risk of hypertension due to climate change induced saline intrusion in water. The objective of this study is to assess beliefs, perceptions, and practices associated with salt consumption in coastal Bangladesh. The study was conducted in Chakaria, Bangladesh between April-June 2011. It was a cross sectional mixed method study. For the qualitative study 6 focus group discussions, 8 key informant interviews, 60 free listing exercises, 20 ranking exercises and 10 observations were conducted. 400 adults were randomly selected for quantitative survey. For analysis we used SPSS for quantitative data, and Anthropac and Nvivo for qualitative data. Salt was described as an essential component of food with strong cultural and religious roots. People described both health benefits and risks related to salt intake. The overall risk perception regarding excessive salt consumption was low and respondents believed that the cooking process can render the salt harmless. Respondents were aware that salt is added in many foods even if they do not taste salty but did not recognize that salt can occur naturally in both foods and water. In the study community people had low awareness of the risks associated with excess salt consumption and salt reduction strategies were not high in their agenda. The easy access to and low cost of salt as well as unrecognised presence of salt in drinking water has created an environment conducive to excess salt consumption. It is important to design general messages related to salt reduction and test tailored strategies especially for those at high risk of hypertension.

A rigorous derivation and validation for linear fluid–structure-interaction (FSI) equations for a rigid-body motion problem is performed in an Eulerian framework. We show that the ‘added stiffness’ terms arising in the formulation of Fanion et al. (Revue Européenne des Éléments Finis, vol. 9, issue 6–7, 2000, pp. 681–708) vanish at the FSI interface in a first-order approximation and can be neglected when considering the growth of infinitesimal disturbances. Several numerical tests with rigid-body motion are performed to show the validity of the derived formulation by comparing the time evolution between the linear and nonlinear equations when the base flow is perturbed by identical small-amplitude perturbations. In all cases both the growth rate and angular frequency of the instability matches within $0.1\\,\\%$ accuracy. The derived formulation is used to investigate the phenomenon of symmetry breaking for a rotating cylinder with an attached splitter plate. The results show that the onset of symmetry breaking can be explained by the existence of a zero frequency linearly unstable mode of the coupled FSI system. Finally, the structural sensitivity of the least stable eigenvalue is studied for an oscillating cylinder, which is found to change significantly when the fluid and structural frequencies are close to resonance.

In the present work, the laminar–turbulent transition of the flow evolving around a low-pressure turbine blade has been investigated. Direct numerical simulations have been carried out for two different free stream turbulence intensity (FSTI) levels to investigate the role of free stream oscillations on the evolution of the blade boundary layer. Emphasis is placed on identifying the mechanisms driving the formation and breakup of coherent structures in the high FSTI case and how these processes are affected by the leading-edge receptivity and/or by the continuous forcing in the blade passage. Proper orthogonal decomposition (POD) has been adopted to provide a clear statistical representation of the shape of the structures. Extended POD projections provided temporal and spanwise correlations that allowed us to identify dominant temporal structures and spanwise wavelengths in the transition process. The extended POD analysis shows that the structures on the pressure side are not related to what happens at the leading edge. The results on the suction side show that the modes defining the leading edge and the passage bases correlate with coherent structures responsible for the transition. The most energetic mode of the passage basis is strongly related to the most amplified wavelength in the boundary layer and breakup events leading to transition. Modes with a smaller spanwise wavelength belong to the band predicted by optimal disturbance theory, they amplify with a smaller gain in the rear suction side, and they show the highest degree of correlation between the passage region and the rear suction side.

Thin airfoil dynamic stall at moderate Reynolds numbers is typically linked to the sudden bursting of a small laminar separation bubble close to the leading edge. Given the strong sensitivity of laminar separation bubbles to external disturbances, the onset of dynamic stall on a NACA0009 airfoil section subject to different levels of low-amplitude free stream disturbances is investigated using direct numerical simulations. The flow is practically indistinguishable from clean inflow simulations in the literature for turbulence intensities at the leading edge of ${Tu} = 0.02\\,\\%$. At slightly higher turbulence intensities of ${Tu} = 0.05\\,\\%$, the bursting process is found to be considerably less smooth and strong coherent vortex shedding from the laminar separation bubble is observed prior to the formation of the dynamic stall vortex (DSV). This phenomenon is considered in more detail by analysing its appearance in an ensemble of simulations comprising statistically independent realisations of the flow, thus proving its statistical relevance. In order to extract the transient dynamics of the vortex shedding, the classical proper orthogonal decomposition method is generalised to include time in the energy measure and applied to the time-resolved simulation data of incipient dynamic stall. Using this technique, the dominant transient spatiotemporally correlated features are distilled and the wave train of the vortex shedding prior to the emergence of the main DSV is reconstructed from the flow data exhibiting dynamics of large-scale coherent growth and decay within the turbulent boundary layer.