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Abstract Graphitic carbon nitride has long been considered incapable of splitting water molecules into hydrogen and oxygen without adding small molecule organics despite the fact that the visible-light response and proper band structure fulfills the proper energy requirements to evolve oxygen. Herein, through in-situ observations of a collective C = O bonding, we identify the long-hidden bottleneck of photocatalytic overall water splitting on a single-phased g-C 3 N 4 catalyst via fluorination. As carbon sites are occupied with surface fluorine atoms, intermediate C=O bonding is vastly minimized on the surface and an order-of-magnitude improved H 2 evolution rate compared to the pristine g-C 3 N 4 catalyst and continuous O 2 evolution is achieved. Density functional theory calculations suggest an optimized oxygen evolution reaction pathway on neighboring N atoms by C–F interaction, which effectively avoids the excessively strong C-O interaction or weak N-O interaction on the pristine g-C 3 N 4 .

Abstract Sudden channel shifting of wandering rivers poses significant challenges for river engineering, flood control strategies, and the security of water resources. This study proposes a novel analytical model to quantitatively assess such channel shifts based on the cusp catastrophe theory. Utilizing bathymetric data from 93 river sections collected biannually between 2015 and 2019, a comprehensive investigation of channel instability in the wandering reach of the Lower Yellow River was conducted. The results show that both lateral and longitudinal stabilities in the Huayuankou-Gaocun section were generally favorable. For the most part of the selected sections demonstrated a propensity for gradual change. Out of the 93 sections, totally 45 were identified as being susceptible to sudden channel shifts. These vulnerable sections were predominantly located in two highly active reaches—Xiaodabin-Jinglonggong and Huayuankou-Zhaolanzhuang—during the period from 2015 to 2017, excluding the 2018–2019 non-flood season. In the latter non-flood period, nearly half of the sections in the downstream reach from Jinglonggong displayed instability. Our findings are consistent closely with empirical observations from the Lower Yellow River. Additionally, the changed flow and sediment conditions in the 2015–2019 and the efficiency of guide works have significant effects on the stability of river channels.

By trapping sediment in reservoirs, dams interrupt the continuity of sediment transport through rivers, resulting in loss of reservoir storage and reduced usable life, and depriving downstream reaches of sediments essential for channel form and aquatic habitats. With the acceleration of new dam construction globally, these impacts are increasingly widespread. There are proven techniques to pass sediment through or around reservoirs, to preserve reservoir capacity and to minimize downstream impacts, but they are not applied in many situations where they would be effective. This paper summarizes collective experience from five continents in managing reservoir sediments and mitigating downstream sediment starvation. Where geometry is favorable it is often possible to bypass sediment around the reservoir, which avoids reservoir sedimentation and supplies sediment to downstream reaches with rates and timing similar to pre‐dam conditions. Sluicing (or drawdown routing) permits sediment to be transported through the reservoir rapidly to avoid sedimentation during high flows; it requires relatively large capacity outlets. Drawdown flushing involves scouring and re‐suspending sediment deposited in the reservoir and transporting it downstream through low‐level gates in the dam; it works best in narrow reservoirs with steep longitudinal gradients and with flow velocities maintained above the threshold to transport sediment. Turbidity currents can often be vented through the dam, with the advantage that the reservoir need not be drawn down to pass sediment. In planning dams, we recommend that these sediment management approaches be utilized where possible to sustain reservoir capacity and minimize environmental impacts of dams. Key Points Reservoirs trap sediment, losing storage capacity Downstream reaches can become sediment starved Many dams can be designed/operated to pass sediment

The watershed system has a complex game relationship between the benign operation and coordinated development of various elements of flood-sediment transportation, eco-environment, and socio-economy (FES). With the increasing breadth, depth, and intensity of human activities in watersheds, it is urgent to coordinate the FES. The relationship of water-sediment in the Yellow River Basin (YRB) is complex, with a prominent contradiction in water supply and a fragile ecosystem. This research tries to build a comprehensive evaluation model for FES and explore the complex interaction between FES in the YRB from 2000 to 2020. The results demonstrated that (1) the comprehensive flood-sediment transportation index (CFTI) and comprehensive eco-environment index (CEI) presented fluctuating growth. In contrast, the comprehensive socio-economy index (CSI) revealed a linear growth trend. The CFTI of Sanmenxia, CEI of Toudaokuan, and CSI of Ningxia had the highest growth rates, with 36.03%, 6.48%, and 107.5%, respectively. (2) FES's positive and negative effects were alternating, with heterogeneity in both time and space. (3) The coupling coordination degree (CCD) in the YRB indicated an increasing trend, ranging from 0.53 to 0.87, from reluctantly coordinated development to good coordinated development. The lagging subsystem was CFTI (2000-2001 and 2008-2020) and CSI (2002-2007), and the CEI was not lagging. (4) Exploratory Spatial Data Analysis (ESDA) demonstrated significant differences in the CCD of the YRB, and areas with similar CCD within the basin tend to be centrally distributed in space. At the same time, there was negative spatial autocorrelation in coordination. The results provide a scientific theoretical and methodological framework for strategic research on the YRB system's governance, protection, and management.

The effects of check dam reservoirs on variations in hydrological regimes commonly result in nonlinear runoff-sediment relationships, which are difficult to describe using current reservoir indicators, particularly for watersheds where floods rise rapidly and huge sediment loads occur. In this study, the evolution of the runoff-sediment relationship was investigated through tests for tendencies and abrupt changes in the Xiliu Valley, a typical hyperconcentrated tributary of the Upper Yellow River on the Northern Loess Plateau, China. Generalized additive models (GAMs) were used to simulate runoff and sediment loads as smooth functions of significant physical covariates including reservoir indices. In comparison with the existing reservoir index (RI) and its additional version (ARI), a sediment-associated reservoir index (SARI) was developed to highlight the advantages of more information on reservoir capacities for both flood control and sediment deposition. The results showed significant downward trends in both annual runoff and sediment series. Alterations in runoff-sediment relationships appeared in approximately 1990, and were mostly dominated by the factors of short-duration storm floods and check dams. GAMs including the SARI exerted more negative effects on sediment yield than on runoff and outperformed the models embracing the RI or ARI. Accordingly, incorporation of the SARI could be advocated under changing environments that are mainly influenced by check dams.

Establishment of a watershed ecological compensation mechanism between multiple subjects is an effective means to realize the collaborative governance of water pollution and maintain the security of water ecology. This paper breaks through the conventional upstream and downstream perspectives of watershed ecological compensation design research and combines them with uncertainty factors. The watershed ecological compensation mechanism for the mainstream and branches was established based on the evolutionary game and the random process. Then, taking the midstream of the Yellow River as an example, some constraint conditions and influencing factors were explored. Results show that: (1) The branch government (i.e., the Shanxi provincial government) is the key to establishing an ecological compensation mechanism between the river mainstream and branches. (2) The proportion of pollution transferred by other branches, the initial probability and the random factors are the main factors affecting the decision-making of branch governments (Shanxi and Shaanxi provincial governments). (3) The compensation and reward of the mainstream government to the branch government and the compensation of the branch government to the mainstream government are the main factors affecting the decision-making of mainstream and branch governments (Shanxi–Henan provincial governments, Shaanxi–Henan provincial governments). The study may provide scientific guidance for the construction of a watershed ecological compensation mechanism between mainstream and multiple branches.

Most 2D (two-dimensional) models either take vertical velocity profiles as uniform, or consider secondary flow in momentum equations with presupposed velocity profiles, which weakly reflect the spatio-temporal characteristics of meander flow. To tackle meander flow in a more accurate 3D (three-dimensional) way while avoiding low computational efficiency, a new 3D model based on spectral methods is established and verified in this paper. In the present model, the vertical water flow field is expanded into polynomials. Governing equations are transformed by the Galerkin method and then advection terms are tackled with a semi-Lagrangian method. The simulated flow structures of an open channel bend are then compared with experimental results. Although a zero-equation turbulence model is used in this new 3D model, it shows reasonable flow structures, and calculation efficiency is comparable to a depth-averaged 2D model.

Desert terminal lakes are important signals to discern ecological degradation crises, particularly in arid areas where an artificial project of ecological water diversion has designated a quota of river water to prevent lake body shrinkage and protect the ecosystem. Knowledge of the minimum ecological water demand (EWD) is thus necessary to ensure the basic health of lake ecosystems. This study analyzed the spatiotemporal evolution of water boundaries using Landsat satellites data via remote sensing technology from 2002 to 2017 in East Juyan Lake, an inland desert terminal lake of the Heihe River in northwest China. The minimum lake water demand was determined using two estimation methods: the lake-evaporation-oriented EWD method and the minimum water level method. In the latter method, both lake topography (using water-level area curves) and biological survival demands (using bighead carps as indicators) were considered to derive the minimum lake EWD. Water diversion to the lake over the past 15 years has increased the lake’s area, but there are still marked intra-annual seasonal variations. The annual minimum lake water demand was suggested to be 54 × 106 m3/year by comparing the different methods; however, it was not satisfied, and the lake survival was endangered when the occurrence frequency of the annual runoff in the Zhengyixia hydrological station exceeded 65%. This study offered promising directions for inland lake water resource management.

The combining of the heterostructure construction and active sites modification to remodel the traditional wide-band-gap semiconductor SrTiO3 for improving visible light absorption capacity and enhancing photocatalytic performance is greatly desired. Herein, we research a novel GO/Rh-SrTiO3 nanocomposite via a facile hydrothermal method. The champion GO/Rh-SrTiO3 nanocomposite exhibits the superior photocatalytic overall water splitting performance with an H2 evolution rate of 55.83 μmol∙g−1∙h−1 and O2 production rate of 23.26 μmol∙g−1∙h−1, realizing a breakthrough from zero with respect to the single-phased STO under visible light (λ ≥ 420 nm). More importantly, a series of characterizations results showed that significantly improving photocatalytic performance originated mainly from the construction of heterostructure and more active sites rooted in Rh metal. In addition, the possible photocatalytic reaction mechanisms and the transport behavior of photogenerated carriers have been revealed in deeper detail. This work provides an effective strategy for heterostructure construction to improve solar utilization through vastly expanding visible light response ranges from traditional UV photocatalysts.

Sperm-associated antigen 17 ( ) gene encodes a multifunctional cytoplasmic protein, which influences not only reproduction but also skeletal development related body measurement traits, especially body height. Thus, this study aimed to identify crucial insertion-deletion (indel) variations, which influence the body measurement traits of goats in large goat populations (n = 1725). As a result, two intronic indels (14 bp and 17 bp indel) were identified by sequencing. For the two indel loci, the distributions of genotypes and alleles were significantly different between the Shaanbei white cashmere goat (SBWC) and the Hainan black goat (HNBG). In SBWC goats, the different genotypes of the 14 bp indel were markedly associated with goat body height, chest width, body length and chest depth. The genotypes of the 17 bp indel were significantly related to body height and chest width. At the two loci, for all seven analyzed traits of SBWC goat, the growth data of DD homozygotes were the worst, which means that the 14 bp insertion and the 17 bp deletion were beneficial and detrimental variations, respectively. Moreover, the combined genotypes were significantly related to body height and chest width of SBWC goats and ten traits of HNBG. These results suggested that the 14 and 17 bp indels within can be used in goat growth related traits marker-assisted selection breeding, especially body height.