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Increasing heavy metal pollution in the environment and the fact that pine needles are good bio-monitors for air pollutants was the reason to investigate their accumulation in pine needles in Vienna (Austria). Pinus nigra is widespread over the city, thus allowing the study of different parameters influencing metal accumulation. The sampling sites were chosen based on traffic volume (low, medium, high). Fresh shoots were collected alongside one-year-old needles once per week from May to August 2015. The needle samples were washed and dried prior to acidic microwave-assisted digestion followed by quantitative determination using spectrometric methods. The investigation was focused on the following elements: Ag, Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Se, Sr, U, V, and Zn. The one-year-old needles mainly contained higher contents of elements than fresh shoots; in many cases, the values differed statistically significantly. By correlating needle elemental contents with the sampling site, statistically significant differences were registered for the majority of the investigated elements. These differences originate from the local traffic situation, soil elemental levels, translocation processes, and not traffic-related sources. No general trend of metal accumulation from spring to summer was registered.

The antioxidant, anti-inflammatory and antiseptic properties of turmeric (Curcuma longa L.) derive from its rich nutritional composition making it interesting for medicinal uses, besides being used as spice in cooking. To complete the picture on the composition of turmeric, not only the organic compounds need to be known, but also the elemental composition covering essential and potentially toxic elements. The samples were digested in a microwave assisted digestion system using different reagent mixtures. The best digestion mixture was semi-concentrated nitric acid combined with hydrogen peroxide. After optimization of the sample preparation method, the contents of Ag, Al, As, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Rb, Se, Sr, Te, Tl, V and Zn in curcuma were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES), as well as by inductively coupled plasma mass spectrometry (ICP-MS). Even if the general composition found is in line with the scarce data in literature, clear differences can be seen between the analyzed samples, considering provenience, production procedures, and harvesting year as potential influencing factors. Whereas all samples contained less As and Pb than regulated by WHO, one limit exceeding was found for Cd.

The elevated ecological awareness nowadays led to a higher consumption of apples juices. Apples juices are rich in dietary fiber, pectin, potassium, and vitamins A and C as well as in different classes of phenolic compounds, which can protect the human body against oxidative stress by scavenging oxygen free radicals. During production and storage some bioactive compounds might decompose resulting in a reduced antioxidative capacity. Common methods for the determination of the antioxidative capacity of other food stuff are based on the extraction of the compounds under study using acetone, which is senseless in aqueous juices. But acetone might have an influence on the compounds responsible for the antioxidative capacity. Thus, self made apple juice samples were analyzed without organic solvent as well as mixed with acetone to see differences caused by the solvent. The results obtained with both procedures were compared using a paired t-test in order to see statistically significant differences in the results. No statistically significant differences were found between the testing with and without acetone. Thus the time of analysis, the amount of solvents needed, and the required labor force can be reduced without loosing analytical quality. Total content of phenolic compounds ranged from 400 to 650 mg gallic acid equivalent /L (Folin-Ciocalteu method) and antioxidative capacity from 1.0 to 1.6 mmol Trolox®/L (ABTS assay). [PUBLICATION ABSTRACT]

The aim of this work is to assess the nutritional value of service tree (Sorbus domestica L.) bark, fruit exocarp and mesocarp, and seeds by establishing the levels of macro- and microelements, total phenolics, flavonoids and tannins. Our results revealed that all of the tested service tree samples were rich in potassium. Bark was the best source of calcium and zinc, while seeds were the best source of magnesium. Compared to the bark and seeds, fruit exocarp and mesocarp contained significantly lower amounts of these three elements. Immature exocarp and bark contained the highest amounts of total phenolics and showed the highest antioxidant activity. Maturation significantly decreased the amount of total phenolics in fruits, as well as the antioxidant activity of total phenolics and total tannins from exocarp, but not from mesocarp. Exocarp was the richest in total flavonoids. Based on the obtained data, we have concluded that the under-utilised species S. domestica L. could serve as an important source of mineral elements and antioxidants in the human diet.

Walnuts (Juglans nigra) are considered to be a functional food. In the present study, twenty one macro-, micro-, and trace elements (Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Se, Sr, and Zn) were selected to be determined in walnuts and walnut oils. The beneficial content of essential elements could be shown by the obtained results, the macro-elements Ca, K, Mg, and Na being present in nuts with 1062 mg/kg, 2771 mg/kg, 1426 mg/kg, and 42.3 mg/kg, respectively. Regarding micro- and trace elements, the following order (decreasing content) was found: Mn > Fe > Zn > B, Mo > Cu > Ni > Co > Al > Sr > Ba > Li > Pb > Se > Cr > As > Cd. Furthermore, the potentially toxic trace elements (As, Cd, Pb) determined were below the maximum allowed values in most of the investigated walnut samples. A comparison of oils and nuts revealed that the former contain lower concentrations of all elements analyzed except for Fe and Zn. This suggested the origin from contamination during oil processing. Fe influences the oil oxidation rate, thus its entry during production should be avoided.

Climate changes in coastal regions cause increased soil salinity, a well-known type of environmental stress for a high number of agricultural crop species, including Brassicaceae, whose growth and development, and consequently the crop quality and yield, are affected by salinity stress. The aim of the present study is to investigate the effect of salt stress on micro- and macro-element homeostasis in different Brassica crops. Kale (Brassica oleracea var. acephala), white cabbage (B. oleracea var. capitata) and Chinese cabbage (B. rapa ssp. pekinensis) were grown hydroponically and treated with 200 mmol/L sodium chloride for 24 h to mimic short-term salt stress. The contents of Al, Ca, K, Mg, Na, B, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn were determined in the roots and leaves of the salt-treated plants and corresponding controls by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry. While Al, Ca, K, Mg and Na were determined in the mg/g range, the contents of the other elements were found at the µg/g level. A statistical analysis of the obtained data showed that the applied salt treatment significantly influenced the single-element contents in different plant parts. The major elements Ca, K and Mg were mainly unaffected in the more-salt-tolerant kale and white cabbage under salinity stress, while K and Mg were significantly decreased in the more-sensitive Chinese cabbage. The levels of micro-elements were found to be species/variety specific. In general, potentially toxic elements were accumulated in the roots of salt-treated plants to a higher extent than in the corresponding controls.

Pine needles are widely used as bio-indicators due to their worldwide distribution and the ease of sample collection. In contrast to deciduous trees, conifers offer the possibility of monitoring long-term exposure through older needles. Pinus halepensis Miller is a pine species native to the Mediterranean region, which has been used for restoration activities in arid and semiarid areas leading to vast spatial expansion. Needles from pine trees collected in the southeastern to northwestern extension of Croatia’s coastal area at twelve sampling sites were analysed for twenty-one metals and metalloids. Statistical evaluation of the obtained data revealed significant differences for Al, As, B, Ba, Ca, Cr, Fe, K, Mg, Mn, Na, Se, and Sr between the different regions. Needles from trees growing on islands did not show elevated levels of Mg and/or Na as a result of the sea spray influence. The differences in metal accumulation are supposed to be linked to the environmental conditions at the respective sampling site, since the species was the same everywhere. By comparing the elemental contents of the soil those of with needles, it can be clearly seen, that the root as well as the foliar uptake contribute to the final amount.

Mango (Mangifera indica L.) is a very popular tropical drupe that can be consumed fresh or dried. It is rich in essential nutrients such as vitamins, dietary fibre, and minerals, as well as biologically active substances, with a positive effect on health. However, it can also contain potentially toxic elements, which justifies the need of properly investigating this food product. Commercially available samples of dried mango, as well as the mesocarp and peel of fresh mango, were analysed. Prior to the multi-element analysis by inductively coupled plasma mass spectrometry (ICP-MS), the microwave-assisted sample digestion method using various reagents and reagent mixtures was optimised, showing that a mixture of nitric acid and hydrogen peroxide gave the best recoveries. The results obtained were processed by chemometric methods. The content of elements in the peel was higher than in the mesocarp. The macroelements Ca, K, Mg, and Na were found in the largest proportion, and the micronutrients present in significant quantities were Cu, Zn, and Mn (>3 mg/kg), while toxic elements, which according to the guidelines of The European Food Safety Authority) would represent a danger to human health, were not found in mass fractions above the permissible values.

Different types of pepper (Piper nigrum L.) and cayenne pepper (Capsicum annuum L.) are widely used spices that exhibit therapeutic properties in addition to nutritional properties. In order to characterize these foods in further detail, the content of macro- (Ca, K, Mg, Na) and microelements (Ag, Al, As, Ba, Be, Bi, Cd, Co, Cr, Cu, Fe, Ga, Li, Mn, Mo, Ni, Pb, Rb, Se, Sr, Te, Tl, V and Zn) of four pepper types was determined via inductively coupled plasma mass spectrometry (ICP-MS) after microwave-assisted digestion using nitric acid and hydrogen peroxide. The obtained results were then evaluated using chemometric methods. The content of macroelements and microelements lies in the expected ranges for such spices but differs significantly between different types. The content of macro- and microelements is characteristic for pepper types originating from different plant species, but also based on further processing. Whilst green and black pepper are similar to each other, clearly diverse patterns are obtained for white pepper (different processing method) and cayenne pepper (different plant species).

Black chokeberries (Aronia melanocarpa) are considered to be functional food containing high amounts of anthocyanins, phenols, antioxidants, vitamins and minerals. Whereas organic compounds are well studied, there is little research on the mineral composition of the chokeberries. Thus, the presented study is focused on the determination of Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Se, Sr and Zn in black chokeberry fruits and infusions to study the metals’ extractability. The nutrients Ca, K and Mg are present in the fruits (dried matter) at g/kg level, whereas the other elements are present from µg/kg up to mg/kg level. The extraction yields of the metals from the infusion range from 4 (Al, Mn) up to 44% (Na). The toxic elements present do not pose any health risk when berries or infusions are consumed. Concluding, Aronia berries, as well as infusions derived from them, are a good dietary source of essential metals in addition to the organic compounds also contained.