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Inorganic nanoparticles might have played a vital role in the transition from inorganic chemistry to self-sustaining living systems. Such transition may have been triggered or controlled by processes requiring not only versatile catalysts but also suitable reaction surfaces. Here, experimental results showing that multicolor quantum dots might have been able to participate as catalysts in several specific and nonspecific reactions, relevant to the prebiotic chemistry are demonstrated. A very fast and easy UV-induced formation of ZnCd quantum dots (QDs) with a quantum yield of up to 47% was shown to occur 5 min after UV exposure of the solution containing Zn(II) and Cd(II) in the presence of a thiol capping agent. In addition to QDs formation, xanthine activity was observed in the solution. The role of solar radiation to induce ZnCd QDs formation was replicated during a stratospheric balloon flight.

The brightest gamma-ray burst ever observed, long-duration GRB 221009A, was detected by GRBAlpha nano-satellite without saturation. We present light curves of the prompt emission in 13 energy bands, from 80 keV to 950 keV, and perform a spectral analysis to calculate the peak flux and peak isotropic-equivalent luminosity. Since the satellite's attitude information is not available for the time of this GRB, more than 200 incident directions were probed in order to find the median luminosity and its systematic uncertainty. We found that the peak flux in the \\(80-800\\) keV range (observer frame) was \\(F_{\\rm{ph}}^{\\rm{p}}=1300_{-200}^{+1200}\\) ph cm\\(^{-2}\\)s\\(^{-1}\\) or \\(F_{\\rm{erg}}^{\\rm{p}}=5.7_{-0.7}^{+3.7}\\times10^{-4}\\) erg cm\\(^{-2}\\)s\\(^{-1}\\) and the fluence in the same energy range of the first GRB episode lasting 300 s, which was observable by GRBAlpha, was \\(S=2.2_{-0.3}^{+1.4}\\times10^{-2}\\) erg cm\\(^{-2}\\) or \\(S^{\\rm{bol}}=4.9_{-0.5}^{+0.8}\\times10^{-2}\\) erg cm\\(^{-2}\\) for the extrapolated range of \\(0.9-8,690\\) keV. We infer the isotropic-equivalent released energy of the first GRB episode to be \\(E_{\\rm{iso}}^{\\rm{bol}}=2.8_{-0.5}^{+0.8}\\times10^{54}\\) erg in the \\(1-10,000\\) keV band (rest frame at \\(z=0.15\\)). The peak isotropic-equivalent luminosity in the \\(92-920\\) keV range (rest frame) was \\(L_{\\rm{iso}}^{\\rm{p}}=3.7_{-0.5}^{+2.5}\\times10^{52}\\) erg s\\(^{-1}\\) and the bolometric peak isotropic-equivalent luminosity was \\(L_{\\rm{iso}}^{\\rm{p,bol}}=8.4_{-1.5}^{+2.5}\\times10^{52}\\) erg s\\(^{-1}\\) (4 s scale) in the \\(1-10,000\\) keV range (rest frame). The peak emitted energy is \\(E_p^\\ast=E_p(1+z)=1120\\pm470\\) keV. Our measurement of \\(L_{\\rm{iso}}^{\\rm{p,bol}}\\) is consistent with the Yonetoku relation. It is possible that, due to the spectral evolution of this GRB and orientation of GRBAlpha at the peak time, the true values of peak flux, fluence, \\(L_{\\rm{iso}}\\), and \\(E_{\\rm{iso}}\\) are even higher. [abridged]

We present the detector performance and early science results from GRBAlpha, a 1U CubeSat mission, which is a technological pathfinder to a future constellation of nanosatellites monitoring gamma-ray bursts (GRBs). GRBAlpha was launched in March 2021 and operates on a 550 km altitude sun-synchronous orbit. The gamma-ray burst detector onboard GRBAlpha consists of a 75x75x5 mm CsI(Tl) scintillator, read out by a dual-channel multi-pixel photon counter (MPPC) setup. It is sensitive in the ~30-900 keV range. The main goal of GRBAlpha is the in-orbit demonstration of the detector concept, verification of the detector's lifetime, and measurement of the background level on low-Earth orbit, including regions inside the outer Van Allen radiation belt and in the South Atlantic Anomaly. GRBAlpha has already detected five, both long and short, GRBs and two bursts were detected within a time-span of only 8 hours, proving that nanosatellites can be used for routine detection of gamma-ray transients. For one GRB, we were able to obtain a high resolution spectrum and compare it with measurements from the Swift satellite. We find that, due to the variable background, the time fraction of about 67 % of the low-Earth polar orbit is suitable for gamma-ray burst detection. One year after launch, the detector performance is good and the degradation of the MPPC photon counters remains at an acceptable level. The same detector system, but double in size, was launched in January 2022 on VZLUSAT-2 (3U CubeSat). It performs well and already detected three GRBs and two solar flares. Here, we present early results from this mission as well.

The timing-based localization, which utilize the triangulation principle with the different arrival time of gamma-ray photons, with a fleet of Cubesats is a unique and powerful solution for the future all-sky gamma-ray observation, which is a key for identification of the electromagnetic counterpart of the gravitational wave sources. The Cubesats Applied for MEasuring and Localising Transients (CAMELOT) mission is now being promoted by the Hungarian and Japanese collaboration with a basic concept of the nine Cubesats constellations in low earth orbit. The simulation framework for estimation of the localization capability has been developed including orbital parameters, an algorithm to estimate the expected observed profile of gamma-ray photons, finding the peak of the cross-correlation function, and a statistical method to find a best-fit position and its uncertainty. It is revealed that a degree-scale localization uncertainty can be achieved by the CAMELOT mission concept for bright short gamma-ray bursts, which could be covered by future large field of view ground-based telescopes. The new approach utilizing machine-learning approach is also investigated to make the procedure automated for the future large scale constellations. The trained neural network with 10\\(^6\\) simulated light curves generated by the artificial short burst templates successfully predicts the time-delay of the real light curve and achieves a comparable performance to the cross-correlation algorithm with full automated procedures.

It is well known that silicon photomultipliers (SiPMs) are prone to radiation damage. With the increasing popularity of SiPMs among new spaceborne missions, especially on CubeSats, it is of paramount importance to characterize their performance in space environment. In this work, we report the in-orbit ageing of SiPM arrays, so-called multi-pixel photon counters (MPPCs), using measurements acquired by the GRBAlpha and VZLUSAT-2 CubeSats at low Earth orbit (LEO) spanning over three years, which in duration is unique. GRBAlpha is a 1U CubeSat launched on March 22, 2021, to a 550 km altitude sun-synchronous polar orbit (SSO) carrying on board a gamma-ray detector based on CsI(Tl) scintillator readout by eight MPPCs and regularly detecting gamma-ray transients such as gamma-ray bursts and solar flares in the energy range of ~30-900 keV. VZLUSAT-2 is a 3U CubeSat launched on January 13, 2022 also to a 550 km altitude SSO carrying on board, among other payloads, two gamma-ray detectors similar to the one on GRBAlpha. We have flight-proven the Hamamatsu MPPCs S13360-3050 PE and demonstrated that MPPCs, shielded by 2.5 mm of PbSb alloy, can be used in an LEO environment on a scientific mission lasting beyond three years. This manifests the potential of MPPCs being employed in future satellites.

GRBAlpha is a 1U CubeSat launched in March 2021 to a sun-synchronous LEO at an altitude of 550 km to perform an in-orbit demonstration of a novel gamma-ray burst detector developed for CubeSats. VZLUSAT-2 followed ten months later in a similar orbit carrying as a secondary payload a pair of identical detectors as used on the first mission. These instruments detecting gamma-rays in the range of 30-900 keV consist of a 56 cm2 5 mm thin CsI(Tl) scintillator read-out by a row of multi-pixel photon counters (MPPC or SiPM). The scientific motivation is to detect gamma-ray bursts and other HE transient events and serve as a pathfinder for a larger constellation of nanosatellites that could localize these events via triangulation. At the beginning of July 2024, GRBAlpha detected 140 such transients, while VZLUSAT-2 had 83 positive detections, confirmed by larger GRB missions. Almost a hundred of them are identified as gamma-ray bursts, including extremely bright GRB 221009A and GRB 230307A, detected by both satellites. We were able to characterize the degradation of SiPMs in polar orbit and optimize the duty cycle of the detector system also by using SatNOGS radio network for downlink.

Aims. Since launched on 2021 March 22, the 1U-sized CubeSat GRBAlpha operates and collects scientific data on high-energy transients, making it the smallest astrophysical space observatory to date. GRBAlpha is an in-obit demonstration of a gamma-ray burst (GRB) detector concept suitably small to fit into a standard 1U volume. As it was demonstrated in a companion paper, GRBAlpha adds significant value to the scientific community with accurate characterization of bright GRBs, including the recent outstanding event of GRB 221009A. Methods. The GRB detector is a 75x75x5 mm CsI(Tl) scintillator wrapped in a reflective foil (ESR) read out by an array of SiPM detectors, multi-pixel photon counters by Hamamatsu, driven by two separate, redundant units. To further protect the scintillator block from sunlight and protect the SiPM detectors from particle radiation, we apply a multi-layer structure of Tedlar wrapping, anodized aluminium casing and a lead-alloy shielding on one edge of the assembly. The setup allows observations of gamma radiation within the energy range of 70-890 keV with an energy resolution of ~30%. Results. Here, we summarize the system design of the GRBAlpha mission, including the electronics and software components of the detector, some aspects of the platform as well as the current way of semi-autonomous operations. In addition, details are given about the raw data products and telemetry in order to encourage the community for expansion of the receiver network for our initiatives with GRBAlpha and related experiments.

GRBAlpha is a 1U CubeSat mission with an expected launch date in the first half of 2021. It carries a 75 x 75 x 5 mm CsI(Tl) scintillator, read out by a dual-channel multi-pixel photon counter (MPPC) setup, to detect gamma-ray bursts (GRBs). The GRB detector is an in-orbit demonstration for the detector system on the Cubesats Applied for MEasuring and LOcalising Transients (CAMELOT) mission. While GRBAlpha provides 1/8th of the expected effective area of CAMELOT, the comparison of the observed light curves with other existing GRB monitoring satellites will allow us to validate the core idea of CAMELOT, i.e. the feasibility of timing-based localization.