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Groundwater contamination is a global problem that has a significant impact on human health and ecological services. Studies reported in this special issue focus on contaminants in groundwater of geogenic and anthropogenic origin distributed over a wide geographic range, with contributions from researchers studying groundwater contamination in India, China, Pakistan, Turkey, Ethiopia, and Nigeria. Thus, this special issue reports on the latest research conducted in the eastern hemisphere on the sources and scale of groundwater contamination and the consequences for human health and the environment, as well as technologies for removing selected contaminants from groundwater. In this article, the state of the science on groundwater contamination is reviewed, and the papers published in this special issue are summarized in terms of their contributions to the literature. Finally, some key issues for advancing research on groundwater contamination are proposed.

The main objective of the present research was to examine the risk of fluoride-rich groundwater in the Shanmuganadhi River basin, south India on human health. The non-carcinogenic risks were estimated into two classes: (1) risks associated with oral intake of water and (2) risks associated with dermal contact. Hazard Quotient for oral intake and dermal contact was separately calculated for adult men, adult women and children from the geochemical results of 61 representative samples collected from the wells constructed in hard rock aquifers during the post- (January-2018) and pre-monsoon (May-2018) seasons. The collected samples were analyzed immediately after the field work for all the major ions and fluoride. Finally, total hazard index was calculated for adults (men and women) and children to evaluate the risk. It directed that 41%, 49% and 74% of post-monsoon samples and 30%, 43% and 62% of pre-monsoon samples possessed a non-carcinogenic risk for men, women and children, respectively. Because the basin falls in the drought-prone region, the water supply for drinking and cultivation are commonly based on groundwater resources. The study revealed that the minerals such as apatite, fluorite, biotite and pyroxene in the hornblende–biotite gneiss formation contribute fluoride ions to the groundwater system due to water–rock interaction mechanism. The Durov diagram depicted that dissolution of silicate minerals and cation exchange are the foremost hydrogeochemical activities, which decide the overall chemical composition of groundwater in this region. The ionic concentrations including fluoride increased with respect to depth of occurrence of groundwater. Escalation of the water table due to monsoon recharge and artificial recharge through a check dam decreased the total dissolved solids and fluoride ion concentration. The investigation conducted around the existing check dam at Kaldurai village highlighted that the fluoride concentration is below the allowable limit of 1.5 mg/l (WHO in World health statistics 2017: monitoring health for the SDGs, Sustainable Development Goals. World Health Organization, Geneva, 2017) in the wells closer to the check dam toward the downstream side. The concentration increased with distance, which lead the groundwater unsuitable for consumption. Therefore, it is recommended to implement the managed aquifer recharge using check dams in the other parts of the basin to enrich the quantity and applicability of groundwater.

Nowadays, GIS and remote sensing techniques are effectively used to find groundwater prospect zones in various troublesome landscapes throughout the world. In the present work, groundwater potential zonation mapping was carried out for the Vattamalaikarai River basin in South India by overlaying ten thematic maps such as soil, drainage density, lineament density, geology, slope, land use/land cover, geomorphology, topographic position index, rainfall and groundwater level by giving appropriate weightages to each significant parameter with respect to its influence on groundwater. As the basin mainly depends on the groundwater resources, it is necessary to assess the groundwater prospect for the better management of aquifer system. Groundwater potential zonation map illustrates that more than 50% of the basin region falls under moderate to low groundwater potential category. Highly influential thematic layers were integrated to generate groundwater recharge zonation map. Based on this output, artificial recharge sites were selected to replenish the groundwater resources in the basin. Three check dam sites were suggested across the third- and fourth-order streams. Four suitable sites for the construction of percolation ponds and ten locations for the construction of recharge pits were also identified. Four injection well sites were recommended to augment groundwater in the aquifer present under the black cotton soil regions in the western part of the basin.

The aim of the study is to address the issues and associated health risks due to consumption of high-fluoride water supplied for drinking in a rural part of Shanmuganadhi River basin, Tamil Nadu, India. In this study, 61 groundwater samples were gathered from various tube and open wells and analysed for fluoride and other physicochemical parameters. The abundance of cations is Na+ > Ca2+ > Mg2+ > K+, and that of anions is HCO3− > SO42− > Cl− > F−. The fluoride concentration in drinking groundwater varied from 0.10 to 3.3 mg/l. According to the WHO standards, about 26% of the samples were unfit for drinking requirements (16 out of 61 samples) Water quality index (WQI) method was adopted to categorize the water into different classes to understand its suitability for drinking requirements. WQI signified that nearly 52% of the samples denoted poor, very poor and not suitable categories, whereas 48% of samples denoted good and excellent categories for consumption. Health risks associated with high-fluoride drinking water were assessed for various age groups of inhabitants such as children, teens and adults. The hazard quotient estimated based on the oral intake ranged from 0.00E+00 to 5.50E+00, from 0.00E+00 to 4.22E+00 and from 0.00E+00 to 3.45E+00 for children, teens and adults, respectively. It suggested that the health risks are associated with 75%, 59% and 43% of samples, respectively, among children, teens and adults. Therefore, children are more inclined towards risk than teens and adults in this region based on the intake of fluoride-rich drinking water. To improve the present scenario, groundwater should be either treated before drinking water supply or must be artificially recharged to lower the concentration of ions.

Samples of groundwater were collected during a post-monsoon period (January) and a pre-monsoon period (May) in 2020 from 30 locations in the rapidly developing industrial and residential area of the Coimbatore region in southern India. These sampling periods coincided with times before and during the lockdown in industrial activity and reduced agricultural activity that occurred in the region due to the COVID-19 pandemic. This provided a unique opportunity to evaluate the effects of reduced anthropogenic activity on groundwater quality. Approximately 17% of the wells affected by high fluoride concentrations in the post-monsoon period returned to levels suitable for human consumption in samples collected in the pre-monsoon period. This was probably due to ion exchange processes, infiltration of rainwater during the seasonal monsoon that diluted concentrations of ions including geogenic fluoride, as well as a reduction in anthropogenic inputs during the lockdown. The total hazard index for fluoride in the post-monsoon samples calculated for children, adult women, and adult men indicated that 73%, 60%, and 50% of the groundwater samples, respectively, had fluoride levels higher than the permissible limit. In this study, nitrate pollution declined by 33.4% by the pre-monsoon period relative to the post-monsoon period. The chemical facies of groundwater reverted from the Na-HCO3-Cl and Na–Cl to the Ca-HCO3 type in pre-monsoon samples. Various geogenic indicators like molar ratios, inter-ionic relations along with graphical tools demonstrated that plagioclase mineral weathering, carbonate dissolution, reverse ion exchange, and anthropogenic inputs are influencing the groundwater chemistry of this region. These findings were further supported by the saturation index assessed for the post- and pre-monsoon samples. COVID-19 lockdown considerably reduced groundwater pollution by Na+, K+, Cl–, NO3¯, and F– ions due to shutdown of industries and reduced agricultural activities. Further groundwater quality improvement during lockdown period there is evidence that the COVID-19 lockdown by increased HCO3¯ ion concentration. Overall results illustrate the positive benefits to groundwater quality that could occur as a result of measures to control anthropogenic inputs of pollutants.

In order to assess the geochemical mechanism liable for fluoride contamination in groundwater and its health effects on the people of the Shanmuganadhi River basin, Tamil Nadu, India, 61 groundwater samples were collected during post- and pre-monsoon seasons from the wells used for drinking purposes. Collected samples were analysed for various physico-chemical parameters. The parameters estimated in the present study are hydrogen ion concentration (pH), total dissolved solids, electrical conductivity, calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), bicarbonate (HCO3−), chloride (Cl−), sulphate (SO42−), nitrate (NO3−), phosphate (PO43−) and fluoride (F−). The fluoride ion concentration in the groundwater samples of this region varied from 0.01 to 2.50 mg/l and 0.01 to 3.30 mg/l during post- and pre-monsoon seasons, respectively. Out of 61 groundwater samples, 14 samples of post-monsoon season and 16 samples of pre-monsoon season represented high, very high and extremely high classes of fluoride, which cause dental fluorosis in this region. The fluoride-bearing minerals in the granitic and gneissic rocks such as apatite, hornblende, muscovite, biotite and amphiboles are the major sources for fluoride contamination in this area. In addition to the geogenic sources, applications of synthetic fertilizers in the agricultural fields also contribute significant amount of fluoride ions to groundwater. The spatial distribution of fluoride in different geological formations clearly indicate that the wells located in charnockite terrain were possessing very low fluoride concentration when compare with the wells located in the hornblende–biotite gneiss formation. Therefore, dental fluorosis risks are mostly associated with rock types in this region. People living over the basement rock comprising of hornblende–biotite gneiss are prone for fluorosis. Fluoride exhibited good positive correlation with bicarbonate in groundwater. As fluoridated endemic regions normally acquire lot of bicarbonate in groundwater samples, Shanmuganadhi basin falls under fluoride endemic category. The present study identified 26 villages in Shanmuganadhi basin as probable fluorosis risk areas where attention should be given to treat the fluoride-rich groundwater before drinking water supply. The groundwater level fluctuation study also designates that rise in water level reduces the concentration of fluoride due to dilution mechanism. Therefore, recharge of groundwater by artificial methods will definitely improve the present scenario.

The artificial recharge is an alternative technique to augment surface water and groundwater and for providing continuous supply of water to the demand regions. The scope of contemporary study helps in evaluation of groundwater potential zones and to find proper zones and sites for groundwater recharge using geospatial and multi-criteria decision analysis (MCDA) techniques. In this study, the pragmatic methodology was proposed for the implementation of water harvesting structures. The satellite and conventional datasets with field inferences were systematically processed to obtain various thematic information of the study area. The analytical hierarchical process (AHP) in geographical information system (GIS) was utilized to assign the geometric mean and the normalized weight for the individual features. Further, groundwater potential zones were identified, and they were categorized into four types viz. very high (523.58 km 2 ), high (798.22 km 2 ), moderate (646.04 km 2 ) and low (456.66 km 2 ). Nearly, 54.52% of the study area falls in the ‘very high’ to ‘high’ potential categories. The GIS-based Boolean logical method was also executed to identify suitable areas for creating recharge structures such as check dams (127.47 km 2 ), percolation ponds (115.23 km 2 ), flood and furrows (63.01 km 2 ) and ditch and furrows (1046.31 km 2 ). Based on the above results, 36 water harvesting structures were promoted to augment the groundwater resources of the basin. The highest priority was given to check dams (19 Nos), followed by percolation ponds (7 Nos), flood and furrows (5 Nos) and ditch and furrows (5 Nos). The suggested structures would improve the groundwater availability for agriculture and domestic purposes in the study area. Further, the outcomes could deliver a scientific procedure to the decision makers and water scientists for effective water resources development and management planning. Overall, the integrated remote sensing, GIS and MCDA methods are an efficient and useful tool for planning and improving groundwater recharge in the basin scale.

Preliminary investigation reveals that fluorosis is reported due to the continuous intake of fluoride-rich groundwater in Vattamalikarai River basin, Tamil Nadu, India. A detailed study was attempted for evaluating the health risks associated with the intake of fluoride-rich groundwater supplied to the rural community. Groundwater samples were collected from 60 and 58 dug and tube wells during winter and southwest (SW) monsoon seasons respectively. The samples were analyzed for the determination of fluoride and other chemical parameters to examine the fitness for drinking water. Spatio-temporal variation maps reveal that fluoride concentration is high during SW monsoon season when compared with the winter season in this region. The fluoride bearing minerals present in hornblende-biotite gneiss and charnockite rock formations leached into the groundwater during rock–water interaction. To understand the subsurface hydrogeochemical reactions, inverse mass balance model was developed using NETPATH code. The model output indicates that calcite dilution, silicate (hornblende and biotite) weathering, ion exchange (Ca/Na and Mg/Na) and illite precipitation are the dominant processes controlling the groundwater chemistry along the flow paths. Non-carcinogenic risks to children and adults (women and men) were evaluated by working out intake exposure of groundwater. Hazard quotient (HQ) based on fluoride intake was calculated for children and adults. It varied from 0.08 to 2.21 with an average of 1.07 for adults. For children, it varied from 0.01 to 2.99 with the mean of 1.44. About 78%, 69% and 61% of the samples fall under the risk category for children, women and men during winter season. However, more number of samples possessed health risks (83% of samples for children, 73% of samples for women and 64% of samples for men) during SW monsoon season.

A study was conducted to evaluate the suitability of groundwater in the drought-prone Shanmuganadhi River basin of south India for best agricultural practices since the surface water that exists in this basin is not sufficient to meet out the demand. As the quality of groundwater is not uniform in the hard rock aquifers of this basin, the work was carried out to demarcate the suitable groundwater quality zones for the agricultural activities. Sixty-one groundwater samples were collected and analyzed for various parameters such as electrical conductivity (EC), pH, TDS, major cations (Ca 2+ , Mg 2+ , Na + , and K + ) and anions (Cl − , SO 4 2− , HCO 3 − , PO 4 3− , NO 3 − , and F − ). To demarcate the feasible zones for agricultural practices, irrigation water quality parameters like EC, sodium adsorption ratio (SAR), percent sodium (Na %), residual sodium carbonate (RSC), magnesium hazard ratio (MHR), Kelly’s ratio (KR), and permeability index (PI) were computed. Furthermore, the irrigation water quality representation diagrams like USSL, Wilcox, and Doneen were prepared, and their outputs were spatially plotted using the Geographical Information System (GIS) to identify the suitability domains of groundwater for irrigational practices. Interpretation of irrigation water quality parameters and diagrams indicate that 2% of groundwater samples represented “low” salinity, 26% of samples represented “medium” salinity, 66% of samples represented “high” salinity, and 6% of samples represented “very high” salinity. Similarly, about 59% of samples represented the low alkaline/sodium category and 41% of them represented the medium alkaline category. The USSL output shows that about 2% of samples of the basin signified “low salinity with low alkalinity” category (C1S1), 28% of samples signified the “medium salinity with low alkalinity” category (C2S1), 33% of samples signified “high salinity with low alkalinity” category (C3S1), 28% of samples signified the “high salinity with medium alkalinity” category (C3S2), and 10% of samples signified the “very high salinity with medium alkalinity” category (C4S2). Groundwater is suitable for irrigation in 277.52 km 2 area of the basin. It is moderately suitable in an area of 318.46 km 2 and poorly suitable over 38.64 km 2 . This study recommends that groundwater with moderate suitability could only be used for irrigating permeable soils and for cultivating salt-tolerant crops. The addition of gypsum to soil might be helpful to increase the infiltration capacity and osmotic activity. However, poorly suitable area should be avoided for agricultural practices.