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Constructed wetlands are a versatile technology for various treatment approaches, especially in emerging countries. The research aims to study and optimize the hybridizing process of a vertical subsurface flow constructed wetland with adsorption technology to provide energy-efficient and sustainable removal of heavy metals and bulk organics before their discharge into water bodies or water reuse for irrigation. This study focuses on the adsorption of selected heavy metals present in sewage from Kanpur, India, a cluster of tanning industries and other relevant industrial polluters, investigating the pollutant adsorption onto activated carbon and zeolites in batch and column tests. The results of the batch tests indicated high zeolite loading rates for lead (91.6 mg/g), chromium (60.8 mg/g) and copper (47.4 mg/g). In the column tests applying different adsorbent combinations and ratios, the average removal rates were as follows: 54.6% for cadmium, 14.1% for chromium, 52.4% for copper, 2.2% for iron, 29.2% for manganese, 26.6% for nickel, 35.2% for lead and 44.6% for zinc. The column tests conducted in preparation for field testing in pilot wetlands showed that shorter retention times and background bulk organic concentrations, as well as high ammonium concentrations, negatively affected heavy metal removal by reducing the adsorption and ion exchange capacity of the adsorbents.

Due to concerns about ecotoxicological effects of pharmaceuticals and other micropollutants released from wastewater treatment plants, activated carbon adsorption is one of the few processes to effectively reduce the concentrations of micropollutants in wastewater. Although aimed mainly at apolar compounds, polar compounds are also simultaneously removed to a certain extent, which has rarely been studied before. In this study, adsorption isotherm and batch kinetic data were collected with two powdered activated carbons (PACs) to assess the removal of the polar pharmaceuticals 5-fluorouracil (5-Fu) and cytarabine (CytR) from ultrapure water and wastewater treatment plant effluent. At pH 7.8, single-solute adsorption isotherm data for the weak acid 5-Fu and the weak base CytR showed that their adsorption capacities were about 1 order of magnitude lower than those of the less polar endocrine disrupting chemicals bisphenol A (BPA) and 17-α-ethinylestradiol (EE2). To remove 90 % of the adsorbate from a single-solute solution 14, 18, 70, and 87 mg L −1 of HOK Super is required for EE2, BPA, CytR, and 5-Fu, respectively. Effects of solution pH, ionic strength, temperature, and effluent organic matter (EfOM) on 5-Fu and CytR adsorption were evaluated for one PAC. Among the studied factors, the presence of EfOM had the highest effect, due to a strong competition on 5-Fu and CytR adsorption. Adsorption isotherm and kinetic data and their modeling with a homogeneous surface diffusion model showed that removal percentage in the presence of EfOM was independent on the initial concentration of the ionizable compounds 5-Fu and CytR. These results are similar to neutral organic compounds in the presence of natural organic matter. Overall, results showed that PAC doses sufficient to remove >90 % of apolar adsorbates were able to remove no more than 50 % of the polar adsorbates 5-Fu and CytR and that the contact time is a critical parameter.

Natural zeolites have gained attention as low-cost adsorbents for the removal of heavy metals (HMs) from wastewater. However, their performance can be compromised by the presence of competing cations such as ammonium (NH4+). This study investigated the competitive adsorption and desorption dynamics of NH4+ and six HMs (Cd, Cr, Cu, Ni, Pb, and Zn) on two natural zeolites. Batch and column experiments using synthetic wastewater were conducted to evaluate the effects of different NH4+ concentrations, pH, and particle size on HM removal efficiency and desorption effects. Results showed that increasing NH4+ concentrations significantly reduce HM adsorption, with total capacity decreasing by ~45% at 100 mg/L NH4-N in kinetic tests. Adsorption isotherms of the HM mixture for both zeolite types followed a clear sigmoidal trend, which was captured well by the Hill model (R2 = 0.99), with loading rates up to 56.14 mg/g. Pb consistently exhibited the highest affinity for zeolites, while Cd, Cr, Ni, and Zn were most affected by NH4+ competition in the column tests. Desorption tests confirmed that NH4+ rapidly re-mobilises adsorbed metals, in particular Cd, Cu, and Zn. Slightly acidic to neutral pH conditions were optimal for minimising HM remobilisation. These findings underscore the need to consider competitive interactions and operational conditions when applying natural zeolites for HM removal, especially in ammonium-rich environments such constructed wetlands, soil filters, or other decentralised applications.

The removal of five selected pesticide compounds in a brackish model groundwater solution was examined using a bench scale direct contact membrane distillation (DCMD) system. It was found that the rejection rate of the pesticides in DCMD is mainly influenced by its properties. Compounds with low hydrophobic characteristics and low vapour pressure showed a high rejection rate (70–99%), whereas compounds with a high vapour pressure or high hydrophobicity (LogD) showed a reduced rejection (30–50%) at a water recovery of 75%. The influence of groundwater feed solution contents such as the presence of organics (humic acid) and inorganic ions (Na + , Ca 2+ , Mg 2+ , Cl − and SO 4 2− ) as well as feed temperature (40, 55 and 70 °C) on the rejection of the pesticides in DCMD operation was also evaluated. The results showed that the presence of inorganic ions and organics in the feed solution influences the pesticides rejection in DCMD operation to a minor degree. In contrast, reduced rejection of pesticides with high vapour pressure was observed. A rapid small-scale column test (RSSCT) was carried out to study the removal of any remaining substances in the permeate by adsorption onto granular activated carbon (GAC). RSSCT showed promising performance of GAC as a post-treatment option.

Resource recovery from wastewater treatment plants is crucial for India's circular economy, as emphasized by the national draft water reuse norms 2024. This study evaluated resource recovery technologies using circularity and sustainability assessment methods to inform technology selection. A multiple-criteria decision analysis compared three innovative and two reference treatment trains in Kanpur, India, based on treatment performance, costs, and resource recovery potential. Quantitative microbial risk and life cycle assessments further evaluated health and environmental benefits and burdens. Innovative systems, such as Andicos (ultrafiltration + co-digestion) and SFD-MBR (slow-forming dynamic membrane bioreactor) had slightly lower performance indices (ΔPI: 0.10–0.12) than the reference system MBR due to lower nutrient removal. The innovative systems generated 1.3 to 2 times more revenue from selling water, nutrients, and energy. Further, reusing nutrient-rich treated effluents for irrigation reduced eutrophication potential by 94%. Treatment trains with constructed wetland plus (CW+) achieved the highest faecal coliform (FC) removal, meeting reuse norms of <5 MPN/100 mL, potentially preventing up to 2,600 gastrointestinal infections annually among 4,000 farmers using the water for irrigation. This study highlights the potential environmental, health, and economic benefits of innovative wastewater treatment technologies for advancing resource recovery in India.