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result(s) for
"Khalvashi-Sutter, Nugzari"
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RETRACTED ARTICLE: Evidence of near-ambient superconductivity in a N-doped lutetium hydride
2023
The absence of electrical resistance exhibited by superconducting materials would have enormous potential for applications if it existed at ambient temperature and pressure conditions. Despite decades of intense research efforts, such a state has yet to be realized
1
,
2
. At ambient pressures, cuprates are the material class exhibiting superconductivity to the highest critical superconducting transition temperatures (
T
c
), up to about 133 K (refs.
3
–
5
). Over the past decade, high-pressure ‘chemical precompression’
6
,
7
of hydrogen-dominant alloys has led the search for high-temperature superconductivity, with demonstrated
T
c
approaching the freezing point of water in binary hydrides at megabar pressures
8
–
13
. Ternary hydrogen-rich compounds, such as carbonaceous sulfur hydride, offer an even larger chemical space to potentially improve the properties of superconducting hydrides
14
–
21
. Here we report evidence of superconductivity on a nitrogen-doped lutetium hydride with a maximum
T
c
of 294 K at 10 kbar, that is, superconductivity at room temperature and near-ambient pressures. The compound was synthesized under high-pressure high-temperature conditions and then—after full recoverability—its material and superconducting properties were examined along compression pathways. These include temperature-dependent resistance with and without an applied magnetic field, the magnetization (
M
) versus magnetic field (
H
) curve, a.c. and d.c. magnetic susceptibility, as well as heat-capacity measurements. X-ray diffraction (XRD), energy-dispersive X-ray (EDX) and theoretical simulations provide some insight into the stoichiometry of the synthesized material. Nevertheless, further experiments and simulations are needed to determine the exact stoichiometry of hydrogen and nitrogen, and their respective atomistic positions, in a greater effort to further understand the superconducting state of the material.
A nitrogen-doped lutetium hydride was synthesized under high-pressure high-temperature conditions and, following full recoverability, examination along compression pathways showed evidence of superconductivity at room temperature and near-ambient pressures.
Journal Article
Evidence of near-ambient superconductivity in a N-doped lutetium hydride
2023
The absence of electrical resistance exhibited by superconducting materials would have enormous potential for applications if it existed at ambient temperature and pressure conditions. Despite decades of intense research efforts, such a state has yet to be realized
. At ambient pressures, cuprates are the material class exhibiting superconductivity to the highest critical superconducting transition temperatures (T
), up to about 133 K (refs.
). Over the past decade, high-pressure 'chemical precompression'
of hydrogen-dominant alloys has led the search for high-temperature superconductivity, with demonstrated T
approaching the freezing point of water in binary hydrides at megabar pressures
. Ternary hydrogen-rich compounds, such as carbonaceous sulfur hydride, offer an even larger chemical space to potentially improve the properties of superconducting hydrides
. Here we report evidence of superconductivity on a nitrogen-doped lutetium hydride with a maximum T
of 294 K at 10 kbar, that is, superconductivity at room temperature and near-ambient pressures. The compound was synthesized under high-pressure high-temperature conditions and then-after full recoverability-its material and superconducting properties were examined along compression pathways. These include temperature-dependent resistance with and without an applied magnetic field, the magnetization (M) versus magnetic field (H) curve, a.c. and d.c. magnetic susceptibility, as well as heat-capacity measurements. X-ray diffraction (XRD), energy-dispersive X-ray (EDX) and theoretical simulations provide some insight into the stoichiometry of the synthesized material. Nevertheless, further experiments and simulations are needed to determine the exact stoichiometry of hydrogen and nitrogen, and their respective atomistic positions, in a greater effort to further understand the superconducting state of the material.
Journal Article
Observation of Conventional Near Room Temperature Superconductivity in Carbonaceous Sulfur Hydride
by
Smith, Dean
,
Pasan, Hiranya
,
Dias, Ranga P
in
Alloy systems
,
Carbon content
,
Diamond anvil cells
2023
The phenomenon of high temperature superconductivity, approaching room temperature, has been realized in a number of hydrogen-dominant alloy systems under high pressure conditions1-12. A significant discovery in reaching room temperature superconductivity is the photo-induced reaction of sulfur, hydrogen, and carbon that initially forms of van der Waals solids at sub-megabar pressures. Carbonaceous sulfur hydride has been demonstrated to be tunable with respect to carbon content, leading to different superconducting final states with different structural symmetries. A modulated AC susceptibility technique adapted for a diamond anvil cell confirms a Tc of 260 kelvin at 133 GPa in carbonaceous sulfur hydride. Furthermore, direct synchrotron infrared reflectivity measurements on the same sample under the same conditions reveal a superconducting gap of ~85 meV at 100 K in close agreement to the expected value from Bardeen-Cooper-Schrieffer (BCS) theory13-18. Additionally, x-ray diffraction in tandem with AC magnetic susceptibility measurements above and below the superconducting transition temperature, and as a function of pressure at 107-133 GPa, reveal the Pnma structure of the material is responsible for the close to room-temperature superconductivity at these pressures.