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705 result(s) for "Kim, Jaehyun"
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Probabilistic computing using Cu0.1Te0.9/HfO2/Pt diffusive memristors
A computing scheme that can solve complex tasks is necessary as the big data field proliferates. Probabilistic computing (p-computing) paves the way to efficiently handle problems based on stochastic units called probabilistic bits (p-bits). This study proposes p-computing based on the threshold switching (TS) behavior of a Cu 0.1 Te 0.9 /HfO 2 /Pt (CTHP) diffusive memristor. The theoretical background of the p-computing resembling the Hopfield network structure is introduced to explain the p-computing system. P-bits are realized by the stochastic TS behavior of CTHP diffusive memristors, and they are connected to form the p-computing network. The memristor-based p-bit is likely to be ‘0’ and ‘1’, of which probability is controlled by an input voltage. The memristor-based p-computing enables all 16 Boolean logic operations in both forward and inverted operations, showing the possibility of expanding its uses for complex operations, such as full adder and factorization. Designing a computing scheme to solve complex tasks as the big data field proliferates remains a challenge. Here, the authors present a probabilistic bit generation hardware built using the random nature of Cu x Te 1− x /HfO 2 /Pt memristors capable of performing logic gates with invertible mode, showing the expandability to complex logic circuits.
Unsupervised Video Anomaly Detection Based on Similarity with Predefined Text Descriptions
Research on video anomaly detection has mainly been based on video data. However, many real-world cases involve users who can conceive potential normal and abnormal situations within the anomaly detection domain. This domain knowledge can be conveniently expressed as text descriptions, such as “walking” or “people fighting”, which can be easily obtained, customized for specific applications, and applied to unseen abnormal videos not included in the training dataset. We explore the potential of using these text descriptions with unlabeled video datasets. We use large language models to obtain text descriptions and leverage them to detect abnormal frames by calculating the cosine similarity between the input frame and text descriptions using the CLIP visual language model. To enhance the performance, we refined the CLIP-derived cosine similarity using an unlabeled dataset and the proposed text-conditional similarity, which is a similarity measure between two vectors based on additional learnable parameters and a triplet loss. The proposed method has a simple training and inference process that avoids the computationally intensive analyses of optical flow or multiple frames. The experimental results demonstrate that the proposed method outperforms unsupervised methods by showing 8% and 13% better AUC scores for the ShanghaiTech and UCFcrime datasets, respectively. Although the proposed method shows −6% and −5% than weakly supervised methods for those datasets, in abnormal videos, the proposed method shows 17% and 5% better AUC scores, which means that the proposed method shows comparable results with weakly supervised methods that require resource-intensive dataset labeling. These outcomes validate the potential of using text descriptions in unsupervised video anomaly detection.
Atomically dispersed iridium catalysts on silicon photoanode for efficient photoelectrochemical water splitting
Stabilizing atomically dispersed single atoms (SAs) on silicon photoanodes for photoelectrochemical-oxygen evolution reaction is still challenging due to the scarcity of anchoring sites. Here, we elaborately demonstrate the decoration of iridium SAs on silicon photoanodes and assess the role of SAs on the separation and transfer of photogenerated charge carriers. NiO/Ni thin film, an active and highly stable catalyst, is capable of embedding the iridium SAs in its lattices by locally modifying the electronic structure. The isolated iridium SAs enable the effective photogenerated charge transport by suppressing the charge recombination and lower the thermodynamic energy barrier in the potential-determining step. The Ir SAs/NiO/Ni/ZrO 2 /n-Si photoanode exhibits a benchmarking photoelectrochemical performance with a high photocurrent density of 27.7 mA cm −2 at 1.23 V vs. reversible hydrogen electrode and 130 h stability. This study proposes the rational design of SAs on silicon photoelectrodes and reveals the potential of the iridium SAs to boost photogenerated charge carrier kinetics. Single atom catalysts not only maximize the atomic efficiency of noble metal but also introduce unconventional geometric and electronic structures. Here, the authors demonstrate the decoration of iridium single atoms on silicon photoanodes to boost the photogenerated charge carrier kinetics.
Full integration of highly stretchable inorganic transistors and circuits within molecular-tailored elastic substrates on a large scale
The emergence of high-form-factor electronics has led to a demand for high-density integration of inorganic thin-film devices and circuits with full stretchability. However, the intrinsic stiffness and brittleness of inorganic materials have impeded their utilization in free-form electronics. Here, we demonstrate highly integrated strain-insensitive stretchable metal-oxide transistors and circuitry (442 transistors/cm 2 ) via a photolithography-based bottom-up approach, where transistors with fluidic liquid metal interconnection are embedded in large-area molecular-tailored heterogeneous elastic substrates (5 × 5 cm 2 ). Amorphous indium-gallium-zinc-oxide transistor arrays (7 × 7), various logic gates, and ring-oscillator circuits exhibited strain-resilient properties with performance variation less than 20% when stretched up to 50% and 30% strain (10,000 cycles) for unit transistor and circuits, respectively. The transistors operate with an average mobility of 12.7 ( ± 1.7) cm 2 V −1 s −1 , on/off current ratio of > 10 7 , and the inverter, NAND, NOR circuits operate quite logically. Moreover, a ring oscillator comprising 14 cross-wired transistors validated the cascading of the multiple stages and device uniformity, indicating an oscillation frequency of ~70 kHz. Developing integrated stretchable metal-oxide transistors and circuits is challenging. Here, Kang et al. leveraged molecular-tailored elastic substrates for enhanced adhesion, thus achieving high performance and logical operation across various circuits under high strain.
In Situ Bioprinting of Autologous Skin Cells Accelerates Wound Healing of Extensive Excisional Full-Thickness Wounds
The early treatment and rapid closure of acute or chronic wounds is essential for normal healing and prevention of hypertrophic scarring. The use of split thickness autografts is often limited by the availability of a suitable area of healthy donor skin to harvest. Cellular and non-cellular biological skin-equivalents are commonly used as an alternative treatment option for these patients, however these treatments usually involve multiple surgical procedures and associated with high costs of production and repeated wound treatment. Here we describe a novel design and a proof-of-concept validation of a mobile skin bioprinting system that provides rapid on-site management of extensive wounds. Integrated imaging technology facilitated the precise delivery of either autologous or allogeneic dermal fibroblasts and epidermal keratinocytes directly into an injured area, replicating the layered skin structure. Excisional wounds bioprinted with layered autologous dermal fibroblasts and epidermal keratinocytes in a hydrogel carrier showed rapid wound closure, reduced contraction and accelerated re-epithelialization. These regenerated tissues had a dermal structure and composition similar to healthy skin, with extensive collagen deposition arranged in large, organized fibers, extensive mature vascular formation and proliferating keratinocytes.
Anion exchange membrane water electrolysis for sustainable large‐scale hydrogen production
The development of sustainable energy technology has received considerable attention to meet the increasing energy demands and realize carbon neutrality. Hydrogen is a promising alternative energy source to replace fossil fuels and mitigate environmental issues. However, most hydrogen is produced by reforming fossil fuels, called gray hydrogen, and the production of gray hydrogen emits a large amount of carbon dioxide. As a sustainable approach, water electrolysis technology has been developed to produce high‐purity hydrogen, called green hydrogen. Among various technologies, water electrolysis equipped with an anion exchange membrane has been regarded as an attractive pathway for large‐scale H2 production at a low cost. The status of anion exchange membrane water electrolyzers is approaching toward megawatt‐scale H2 production by companies, which has the potential to become competitive technology for existing water electrolyzers (alkaline electrolyzer, proton exchange membrane electrolyser). This review article represents recent advances in the development of major components (membrane, catalyst, membrane electrode assembly) of anion exchange water electrolyzers. By recognizing the current water electrolysis performance and solving the remaining challenges, anion exchange membrane electrolysis can be a leading technology for green hydrogen production. Anion exchange membrane water electrolysis (AEMWE) is a technology that complements the disadvantages of alkaline water electrolysis and proton exchange membrane water electrolysis. However, AEMWE possesses several challenges to be overcome for sustainable large‐scale hydrogen production. Component development and optimization of cell operation are prerequisites for the practical AEMWEs with high stability and current density.
The Polysulfide‐Cathode Binding Energy Landscape for Lithium Sulfide Growth in Lithium‐Sulfur Batteries
A cathode substrate with strong adsorption of lithium polysulfides (LiPSs) has been preferred for lithium‐sulfur (Li‐S) batteries. However, the recent finding that controlled growth of lithium sulfides (Li2S) during discharge is crucial for S utilization stimulates improvement of this preference. Here, the Li2S growth and cell capacity in the LiPS binding energy landscape of cathode substrates are investigated. Specifically, Co‐based ternary oxides are employed to obtain binding energies in the range of 4.0–7.4 eV. Of these substrates, only the MnCo2O4 substrate with moderate LiPS affinity exhibits 3D Li2S growth. The MnCo2O4 cells achieve high sulfur utilization up to 84% at 0.2 C and excellent performance even under high sulfur loading/lean electrolyte conditions. In contrast, weak affinity substrates such as ZnCo2O4 and strong affinity substrates such as NiCo2O4 and CuCo2O4 exhibit low discharge capacity with 2D Li2S growth. For optimal LiPS affinity driving 3D growth, a balance between promoting LiPS adsorption and diffusion limitation in the LiPS adsorption layer is suggested. Lithium sulfide (Li2S) growth and cell performance are analyzed in the lithium polysulfide (LiPS) binding energy landscape of the cathode substrate. Among Co‐based ternary oxides, only the MnCo2O4 substrate with moderate LiPS affinity exhibits 3D Li2S growth and also achieves the highest cell performance.
Noniterative Generalized Camera Model for Near-Central Camera System
This paper proposes a near-central camera model and its solution approach. ’Near-central’ refers to cases in which the rays do not converge to a point and do not have severely arbitrary directions (non-central cases). Conventional calibration methods are difficult to apply in such cases. Although the generalized camera model can be applied, dense observation points are required for accurate calibration. Moreover, this approach is computationally expensive in the iterative projection framework. We developed a noniterative ray correction method based on sparse observation points to address this problem. First, we established a smoothed three-dimensional (3D) residual framework using a backbone to avoid using the iterative framework. Second, we interpolated the residual by applying local inverse distance weighting on the nearest neighbor of a given point. Specifically, we prevented excessive computation and the deterioration in accuracy that may occur in inverse projection through the 3D smoothed residual vectors. Moreover, the 3D vectors can represent the ray directions more accurately than the 2D entities. Synthetic experiments show that the proposed method can achieve prompt and accurate calibration. The depth error is reduced by approximately 63% in the bumpy shield dataset, and the proposed approach is noted to be two digits faster than the iterative methods.
Unusual high thermal conductivity in boron arsenide bulk crystals
Thermal management becomes increasingly important as we decrease device size and increase computing power. Engineering materials with high thermal conductivity, such as boron arsenide (BAs), is hard because it is essential to avoid defects and impurities during synthesis, which would stop heat flow. Three different research groups have synthesized BAs with a thermal conductivity around 1000 watts per meter-kelvin: Kang et al. , Li et al. , and Tian et al. succeeded in synthesizing high-purity BAs with conductivities half that of diamond but more than double that of conventional metals (see the Perspective by Dames). The advance validates the search for high-thermal-conductivity materials and provides a new material that may be more easily integrated into semiconducting devices. Science , this issue p. 575 , p. 579 , p. 582 ; see also p. 549 Boron arsenide has an ultrahigh thermal conductivity, making it competitive with diamond for thermal management applications. Conventional theory predicts that ultrahigh lattice thermal conductivity can only occur in crystals composed of strongly bonded light elements, and that it is limited by anharmonic three-phonon processes. We report experimental evidence that departs from these long-held criteria. We measured a local room-temperature thermal conductivity exceeding 1000 watts per meter-kelvin and an average bulk value reaching 900 watts per meter-kelvin in bulk boron arsenide (BAs) crystals, where boron and arsenic are light and heavy elements, respectively. The high values are consistent with a proposal for phonon-band engineering and can only be explained by higher-order phonon processes. These findings yield insight into the physics of heat conduction in solids and show BAs to be the only known semiconductor with ultrahigh thermal conductivity.
Superior electroadhesion force with permittivity-engineered bilayer films using electrostatic simulation and machine learning approaches
Electroadhesive forces are crucial in various applications, including grasping devices, electro-sticky boards, electrostatic levitation, and climbing robots. However, the design of electroadhesive devices relies on speculative or empirical error approaches. Therefore, we present a theoretical model comprising predictive coplanar electrodes and protective layers for analyzing the electrostatic fields between an object and electroadhesive device. The model considers the role of protective layer and the air gap between the electrode surface and the object. To exert a higher electroadhesive force, the higher permeability of the protective layer is required. However, a high permeability of the protective layer is hard to withstand high applied voltage. To overcome this, two materials with different permeabilities were employed as protective layers—a low-permeability inner layer and a high-permeability outer layer—to maintain a high voltage and generate a large electroadhesive force. Because a low-permeability inner layer material was selected, a more permeable outer layer material was considered. A theoretical analysis revealed complex relationships between various design parameters. The impact of key design parameters and working environments on the electroadhesion behavior was further investigated. This study reveals the fundamental principles of electroadhesion and proposes prospective methods to enhance the design of electroadhesive devices for various engineering applications.