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"Kong, Fanyue"
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3D printing of metal-based materials for renewable energy applications
by
Mooraj, Shahryar
,
Kong, Fanyue
,
Liu, Liang
in
3-D printers
,
3D printing
,
additive manufacturing
2021
Large-scale renewable energy must overcome conversion and storage challenges before it can replace fossil fuels due to its intermittent nature. However, current sustainable energy devices still suffer from high cost, low efficiency, and poor service life problems. Recently, porous metal-based materials have been widely used as desirable cross-functional platforms for electrochemical and photochemical energy systems for their unique electrical conductivity, catalytic activity, and chemical stability. To tailor the porosity length scale, ordering, and compositions, 3D printing has been applied as a disruptive manufacturing revolution to create complex architected components by directly joining sequential layers into designed structures. This article intends to summarize cutting-edge advances of metal-based materials for renewable energy devices (e.g., fuel cells, solar cells, supercapacitors, and batteries) over the past decade.
Journal Article
Gypsum Binder With Increased Water Resistance Derived From Membrane Water Desalination Waste
2025
A method has been developed for separating a mixture of calcium, magnesium and sodium sulfates obtained through the interaction of sulfuric acid and waste from the water purification process generated by using membrane filters. The primary goal of this method is to extract gypsum and produce gypsum‐based binders. Patterns were identified regarding how various types, ratio and quantities of additives: blast furnace slag, granite screenings, portland cement, electric steel smelting slag affect the water‐gypsum ratio, strength properties, and water resistance of high‐strength gypsum binders. It was found that adding a single‐component additive specifically to enhance water resistance does not significantly impact these properties. Complex additives have been developed based on Portland cement, granulated blast furnace slag, electric furnace slag, expanded clay dust, and granite screenings of various fractions. These additives are designed to maximize the water resistance of high‐strength gypsum binder based on synthetic calcium sulfate dihydrate. As a result, the water resistance coefficient increased from 0.45 to 0.52. Additionally, a technological block diagram of the process has been proposed. Gypsum binders with increased water resistance were obtained from membrane water desalination waste and additives derived from industrial wastes had high grades.
Journal Article
Strong yet ductile nanolamellar high-entropy alloys by additive manufacturing
2022
Additive manufacturing produces net-shaped components layer by layer for engineering applications. The additive manufacture of metal alloys by laser powder bed fusion (L-PBF) involves large temperature gradients and rapid cooling, which enables microstructural refinement at the nanoscale to achieve high strength. However, high-strength nanostructured alloys produced by laser additive manufacturing often have limited ductility. In this work, we use L-PBF to print dual-phase nanolamellar high-entropy alloys (HEAs) of AlCoCrFeNi2.1 that exhibit a combination of a high yield strength of about 1.3 gigapascals and a large uniform elongation of about 14 percent, which surpasses those of other state-of-the-art additively manufactured metal alloys. The high yield strength stems from the strong strengthening effects of the dual-phase structures that consist of alternating face-centred cubic and body-centred cubic nanolamellae; the body-centred cubic nanolamellae exhibit higher strengths and higher hardening rates than the face-centred cubic nanolamellae. The large tensile ductility arises owing to the high work-hardening capability of the as-printed hierarchical microstructures in the form of dual-phase nanolamellae embedded in microscale eutectic colonies, which have nearly random orientations to promote isotropic mechanical properties. The mechanistic insights into the deformation behaviour of additively manufactured HEAs have broad implications for the development of hierarchical, dual- and multi-phase, nanostructured alloys with exceptional mechanical properties.
Journal Article
Strong yet ductile nanolamellar high-entropy alloys by additive manufacturing
2022
Additive manufacturing produces net-shaped components layer by layer for engineering applications
1
–
7
. The additive manufacture of metal alloys by laser powder bed fusion (L-PBF) involves large temperature gradients and rapid cooling
2
,
6
, which enables microstructural refinement at the nanoscale to achieve high strength. However, high-strength nanostructured alloys produced by laser additive manufacturing often have limited ductility
3
. Here we use L-PBF to print dual-phase nanolamellar high-entropy alloys (HEAs) of AlCoCrFeNi
2.1
that exhibit a combination of a high yield strength of about 1.3 gigapascals and a large uniform elongation of about 14 per cent, which surpasses those of other state-of-the-art additively manufactured metal alloys. The high yield strength stems from the strong strengthening effects of the dual-phase structures that consist of alternating face-centred cubic and body-centred cubic nanolamellae; the body-centred cubic nanolamellae exhibit higher strengths and higher hardening rates than the face-centred cubic nanolamellae. The large tensile ductility arises owing to the high work-hardening capability of the as-printed hierarchical microstructures in the form of dual-phase nanolamellae embedded in microscale eutectic colonies, which have nearly random orientations to promote isotropic mechanical properties. The mechanistic insights into the deformation behaviour of additively manufactured HEAs have broad implications for the development of hierarchical, dual- and multi-phase, nanostructured alloys with exceptional mechanical properties.
An additive manufacturing strategy is used to produce dual-phase nanolamellar high-entropy alloys that show a combination of enhanced high yield strength and high tensile ductility.
Journal Article