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The use of graphene in a form of discontinuous flakes in polymer composites limits the full exploitation of the unique properties of graphene, thus requiring high filler loadings for achieving- for example- satisfactory electrical and mechanical properties. Herein centimetre-scale CVD graphene/polymer nanolaminates have been produced by using an iterative ‘lift-off/float-on’ process and have been found to outperform, for the same graphene content, state-of-the-art flake-based graphene polymer composites in terms of mechanical reinforcement and electrical properties. Most importantly these thin laminate materials show a high electromagnetic interference (EMI) shielding effectiveness, reaching 60 dB for a small thickness of 33 μm, and an absolute EMI shielding effectiveness close to 3·10 5  dB cm 2 g −1 which is amongst the highest values for synthetic, non-metallic materials produced to date. The properties of graphene/polymer composites are usually limited by the use of discontinuous graphene flakes. Here, the authors report a fabrication method to realise continuous cm-scale graphene/polymer nanolaminates with enhanced electromagnetic interference shielding effectiveness, conductivity and mechanical properties.

We report on the realisation of a customized THz time domain spectroscopic ellipsometer (THz-TDSE) based on fiber-coupled photoconductive antennas, operating in a wide range of incident angles and allowing also standard transmission spectroscopy without any optical realignment. To ensure accurate parameter extraction for a broad range of materials, we developed a fast and effective algorithm-assisted method to calibrate the setup and compensate for the nonideality in the response of the THz system. The procedure allows to minimise errors induced by imperfect response of the antennas and polarizers, imprecise setting of the impinging and receiving angles in the goniometric mechanical arms, and unavoidable mismatches in the THz beam optics. Differently from other calibration methods applied in the literature, our approach compares in time domain the ellipsometric derived electric field s- and p-polarised components at a given angle of incidence with the reconstructed ones, attained by using the complex dielectric function of a known sample. The calibrated response is determined with high precision by setting the system in transmission mode. In order to validate the technique, ellipsometric measurements have been carried out at various angle of incidences on a number of materials both in solid and liquid form, and their data compared with what obtained by conventional THz spectroscopy. Results show that THz-TDSE accompanied with an accurate calibration procedure is an effective technique for material characterization, especially in case of samples with a high absorption rate that are not easily investigated through transmission measurements.

The transmission response of metallo-dielectric grid metasurfaces is experimentally investigated through Terahertz Time Domain Spectroscopy and the corresponding effective dielectric function is retrieved. Using a lumped element model we can determine the dependence of the effective plasma frequency (the transition frequency) on the metasurface filling factor F. The change of the transition frequency vs. F spans over one order of magnitude and sets the threshold between the metamaterial (homogeneous) and the photonic crystal (diffraction-like) regime, ruling the onset of two different Surface Plasmon Polaritons, spoof and high order. Field symmetry and spatial extension of such excitations are investigated for the possible applications of THz grid metasurfaces in bio- and chemical sensing and sub-wavelength imaging.

With advances in terahertz technology, achieving high and nearly constant birefringence over a wide frequency range plays an extreme role in many advanced applications. In the past decade, significant research efforts have been devoted to creating new systems or elements with high birefringence. To our knowledge, the maximum birefringence attainable using artificial crystals, intrinsic liquid crystals or fiber-based systems has been less than unity. More importantly, the birefringence created in previous studies has exhibited a strong frequency dependence, limiting their practical applications. In this work, we propose a novel approach to achieve extraordinarily high birefringence over a broad terahertz frequency band (>100 GHz). To address the limitation of frequency dependence, we combined the principle of metamaterials with the form birefringence concept. First, we designed a metamaterial with an exceptionally high refractive index, thoroughly characterizing it using simulations and analytical analysis. Next, we systematically investigated the form birefringence concept, exploring its frequency response, geometric limitations, and complex refractive index differences between constituent elements. Finally, we designed a hybrid material system, combining the strengths of both metamaterials and form birefringence. Our results demonstrate the feasibility of achieving a birefringent medium exceeding three orders of magnitude higher than previous reports while maintaining a time-invariant frequency response in the sub-terahertz regime.

We describe an experimental strategy for the use of Terahertz (THz) metasurfaces as a platform for label-free wide range detection of the dielectric function in biological fluids. Specifically, we propose a metagrid (MG), opportunely infiltrated with a fluid and then capped, as the reference structure for sensing experiments with a high reproducibility character. By combining experiments and full-wave simulations of the transmission T of such a structure, we introduce a reliable set up where the volume of the involved analyte in each unit cell is precisely determined. The unavoidable decrease in the quality factor of the intrinsic resonances due to the lossy fluid and cap layer is circumvented using an appropriate transformation of T that amplifies the change in the MG intrinsic resonances, improving in such a way the sensor sensitivity to values close to the experimental limits. The transformed signal features delta-like peaks enabling an easy readout of frequency positions at resonances.

Towards new and improved techniques in liquid biopsy for the diagnosis of diseases, this study reports experimental evidence of a rapid and reliable method based on terahertz (THz) time-domain spectroscopic ellipsometry (TDSE) for the early diagnosis of kidney-related diseases, using the detection of uric acid (UA) content in urine. Employing a custom-built THz-TDSE system, we analyzed the absorption and dispersion response of synthetic urine samples with varying concentrations of UA. The technique provides a prompt indication of UA presence and concentration, thanks to the sensitivity of THz waves to intermolecular interactions such as hydrogen bonding. The results clearly show a linear correlation between the UA concentration and changes in the absorption spectra of urine in the frequency window 0.2–1.2 THz, with the minimum detectable UA concentration being approximately close to the upper limit of normal UA levels in urine. The increase in the absorption coefficient as a function of the UA concentration provides a means for a quantifiable measure of the UA biomarker in urine for assessing disease stage. This study proves that THz-TDSE is capable of detecting UA at concentrations relevant for early-stage diagnosis of renal diseases, with an estimated sensitivity of 0.2 g/L in the region where the material response is linear.

We report the design, fabrication and experimental validation of a THz all-dielectric multi-mode q-plate having a fixed rate of change of the optical axis. The device consists of space-variant birefringent slabs manufactured by 3D printing using melt-extruded Acrylonitrile Butadiene Styrene (ABS). The desired form birefringence is analytically evaluated and experimentally measured by the THz time domain spectroscopy technique. The manufactured q-plate design is characterized using a polarization-sensitive imaging setup. The full electric field spatial maps are acquired from the beam propagating through the q-plate. The device enables the realization of both radial and azimuthal vector beams at discrete frequency intervals by controlling the space-dependent orientation of the ordinary and extraordinary axes in the transverse plane with a multi-mode sequence.

The monoclinic structures of vanadium dioxide are widely studied as appealing systems due to a plethora of functional properties in several technological fields. In particular, the possibility to obtain the VO2 material in the form of thin film with a high control of structure and morphology represents a key issue for their use in THz devices and sensors. Herein, a fine control of the crystal habit has been addressed through an in-depth study of the metal organic chemical vapor deposition (MOCVD) synthetic approach. The focus is devoted to the key operative parameters such as deposition temperature inside the reactor in order to stabilize the P21/c or the C2/m monoclinic VO2 structures. Furthermore, the compositional purity, the morphology and the thickness of the VO2 films have been assessed through energy dispersive X-ray (EDX) analyses and field-emission scanning electron microscopy (FE-SEM), respectively. THz time domain spectroscopy is used to validate at very high frequency the functional properties of the as-prepared VO2 films.

We present the design, fabrication, and experimental test of a THz all-dielectric phase shifter plate. The design consists of two wave plate zones coupled in a perpendicular orientation with respect to each other. A large surface area device is realized by an additive manufacturing technique using Acrylonitrile Butadiene Styrene (ABS). Its characteristics are analytically evaluated and experimentally measured in the THz band using time domain spectroscopy and imaging routines. The proposed design enables the creation of quasi-ideal phase retardation in between the two planes with good uniformity on a large surface area. We also achieve the flexibility to select the plane of symmetry around the chosen central axes of choice with a sensitive control over the electromagnetic field polarization direction without inducing any temporal shifts in between the wave front components of the traversed beam. Due to its inherent simplicity and robustness, the phase shifter can be easily scaled at higher frequencies and potentially used in several advanced applications, including free-electron laser (FEL) systems where an accurate polarization control of high intensity beams is required.

The electromagnetic characterisation of different materials for the inner wall coating of beam pipes is a long-standing problem in accelerator physics, regardless the purpose they are used for, since their presence may affect in an unpredictable way the beam coupling impedance and therefore the machine performance. Moreover, in particle accelerators and storage rings of new generation very short bunches might be required, extending far in frequency the exploration of the beam spectrum and rendering therefore more and more important to assess the coating material response up to hundreds of GHz. This paper describes a time domain method based on THz waveguide spectroscopy to infer the coating properties at very high frequencies. The technique has been tested on Non Evaporable Getter thick films deposited by DC magnetron sputtering on copper plates.