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Transit spectroscopy is a powerful tool for probing atmospheric structures of exoplanets. Accurately accounting for the effects of aerosols is key to reconstructing atmospheric properties from transit spectra, yet this remains a significant challenge. To advance this effort, it is invaluable to examine the spectral features of well-characterized planetary atmospheres. Here, we synthesize empirical transit spectra of Mars across different seasons based on data from the NOMAD’s Solar Occultation channel on board ExoMars/TGO, which operates at wavelengths of 0.2–0.65 and 2–4 μm. In the generated empirical transit spectra, the atmosphere below 25 km is found to be largely opaque due to the presence of micron-sized dust and H2O ice clouds, both of which substantially weaken spectral features. The spectra exhibit CO2 absorption features at 2.7–2.8 μm and signatures of submicron-sized mesospheric H2O ice clouds around 3.1 μm, accompanied by a continuum slope. The amplitudes of these spectral features are found to vary with the Martian seasons, where the dust storms weaken the CO2 signatures and strengthen the H2O ice features, which serve as potential indicators of a dusty planet like Mars. If TRAPPIST-1f possessed a Mars-like atmospheric structure, both CO2 and H2O ice features would be detectable at a noise level of 3 ppm, a level likely beyond current observational capabilities. Nevertheless, the 3.1 μm feature produced by submicron-sized mesospheric H2O ice clouds offers a novel avenue for characterizing the atmospheres of habitable-zone exoplanets.

The Martian mesosphere and thermosphere, the region above about 60 km, is not the primary target of the ExoMars 2016 mission but its Trace Gas Orbiter (TGO) can explore it and address many interesting issues, either in-situ during the aerobraking period or remotely during the regular mission. In the aerobraking phase TGO peeks into thermospheric densities and temperatures, in a broad range of latitudes and during a long continuous period. TGO carries two instruments designed for the detection of trace species, NOMAD and ACS, which will use the solar occultation technique. Their regular sounding at the terminator up to very high altitudes in many different molecular bands will represent the first time that an extensive and precise dataset of densities and hopefully temperatures are obtained at those altitudes and local times on Mars. But there are additional capabilities in TGO for studying the upper atmosphere of Mars, and we review them briefly. Our simulations suggest that airglow emissions from the UV to the IR might be observed outside the terminator. If eventually confirmed from orbit, they would supply new information about atmospheric dynamics and variability. However, their optimal exploitation requires a special spacecraft pointing, currently not considered in the regular operations but feasible in our opinion. We discuss the synergy between the TGO instruments, specially the wide spectral range achieved by combining them. We also encourage coordinated operations with other Mars-observing missions capable of supplying simultaneous measurements of its upper atmosphere.

The study of atmospheric emissions from orbit to probe the middle and upper atmosphere of Mars, which started with the Mariner missions, is living a golden era thanks to the European Space Agency (ESA) Mars Express mission and other subsequent missions built upon its success, including the ESA ExoMars Trace Gas Orbiter (TGO) mission. Here we summarize the most relevant information obtained by the analysis of atmospheric emissions data from Mars Express and TGO, about the temperature and density structure, the atmospheric dynamics, the chemistry and the atmospheric escape to space. Mars Express also opened a new field of research on Mars with the discovery of aurorae on the planet. We present here the most outstanding results collected by Mars Express about aurorae. Finally, we also discuss how later measurements by other missions have complemented Mars Express and TGO results, and the potential future developments relevant to this field of research.

Mars almost certainly had a considerable amount of water in its past. Recent observations reveal that during southern summer, when the atmosphere is warmer and dustier, water vapor can reach high altitudes without condensing, leading to water loss to space. Here, by combining infrared, visible, and ultraviolet data from multiple Mars orbiters, we identify a new pathway for water loss, observed for the first time to our knowledge during the opposite season. Our findings show that a strong, localized, and short-lived dust storm in Martian Year 37 (August 2023) drove considerable vertical transport of water vapor in the northern summer season. Just days after the storm, enhanced water vapor concentrations were observed at altitudes over 40 km across northern high latitudes, followed by an increase in escaping hydrogen detected at the exobase. These results suggest that water loss on Mars can be triggered by strong local dust storms at any time of year. Observations compiled from several Mars observation missions suggest a significant but short-lived dust storm during the Northern hemisphere summer of Mars Year 37 drove substantial vertical transport of water vapor into the upper atmosphere.

We present one Martian year of observations of the density and temperature in the upper atmosphere of Mars (between 60 and 130 km) obtained by the Mars Express ultraviolet spectrometer Spectroscopy for Investigation of Characteristics of the Atmosphere of Mars (SPICAM). Six hundred sixteen profiles were retrieved using stellar occultations technique at various latitude and longitude. The atmospheric densities exhibit large seasonal fluctuations due to variations in the dust content of the lower atmosphere which controls the temperature and, thus, the atmospheric scale height, below 50 km. In particular, the year observed by SPICAM was affected by an unexpected dust loading around Ls = 130° which induced a sudden increase of density above 60 km. The diurnal cycle could not be analyzed in detail because most data were obtained at nighttime, except for a few occultations observed around noon during northern winter. There, the averaged midday profile is found to slightly differ from the corresponding midnight profile, with the observed differences being consistent with propagating thermal tides and variations in local solar heating. About 6% of the observed mesopause temperatures exhibits temperature below the CO2 frost point, especially during northern summer in the tropics. Comparison with atmospheric general circulation model predictions shows that the existing models overestimate the temperature around the mesopause (above 80 to 100 km) by up to 30 K, probably because of an underestimation of the atomic oxygen concentration which controls the CO2 infrared cooling.

It is still unknown how much water has escaped from Mars during its history. Hydrogen escape from Mars’s atmosphere probably played a major role in drying the planet, but present-day H loss rates (~3 × 10 26 atoms per second on average) cannot explain the geological evidence for the large volumes of liquid water on ancient Mars. Here we used the three-dimensional Mars-Planetary Climate Model to show that H loss rates could have increased by more than one order of magnitude (6 × 10 27 atoms per second) during higher spin axis obliquity periods, notably in the last few million years when Mars’s obliquity was about 35° on average. The resulting accumulated H escape over Mars’s history translates into an ~80 m global equivalent layer, which is close to the lower limit of geological estimates, assessing the major role of atmospheric escape in drying Mars. Hydrogen escape has contributed to Mars’s progressive aridity, but current hydrogen loss rates cannot explain inferred past water abundances. A three-dimensional model shows that during periods of increased axis tilt, hydrogen loss rates were up to ten times higher than present values.

The surname of author Cathy Quantin-Nataf was misspelled ‘Quantin-Nata’ , authors Ehouarn Millour and Roland Young were missing from the ACS Science Team list, and minor changes have been made to the author and affiliation lists; see accompanying Amendment. These errors have been corrected online.

We present aeronomical observations collected using remote sensing instruments on board Venus Express, complemented with ground-based observations and numerical modeling. They are mostly based on VIRTIS and SPICAV measurements of airglow obtained in the nadir mode and at the limb above 90 km. They complement our understanding of the behavior of Venus’ upper atmosphere that was largely based on Pioneer Venus observations mostly performed over thirty years earlier. Following a summary of recent spectral data from the EUV to the infrared, we examine how these observations have improved our knowledge of the composition, thermal structure, dynamics and transport of the Venus upper atmosphere. We then synthesize progress in three-dimensional modeling of the upper atmosphere which is largely based on global mapping and observations of time variations of the nitric oxide and O 2 nightglow emissions. Processes controlling the escape flux of atoms to space are described. Results based on the VeRA radio propagation experiment are summarized and compared to ionospheric measurements collected during earlier space missions. Finally, we point out some unsolved and open questions generated by these recent datasets and model comparisons.

In this paper, we summarize the main capabilities of the James Webb Space Telescope (JWST) for performing observations of Mars. The distinctive vantage point of JWST at the Sun-Earth Lagrange point (L2) will allow sampling the full observable disk, permitting the study of short-term phenomena, diurnal processes (across the east-west axis), and latitudinal processes between the hemispheres (including seasonal effects) with excellent spatial resolutions (0 07 at 2 m). Spectroscopic observations will be achievable in the 0.7-5 m spectral region with NIRSpec at a maximum resolving power of 2700 and with 8000 in the 1-1.25 m range. Imaging will be attainable with the Near-Infrared Camera at 4.3 m and with two narrow filters near 2 m, while the nightside will be accessible with several filters in 0.5 to 2 m. Such a powerful suite of instruments will be a major asset for the exploration and characterization of Mars. Some science cases include the mapping of the water D/H ratio, investigations of the Martian mesosphere via the characterization of the non-local thermodynamic equilibrium CO2 emission at 4.3 m, studies of chemical transport via observations of the O2 nightglow at 1.27 m, high-cadence mapping of the variability dust and water-ice clouds, and sensitive searches for trace species and hydrated features on the Martian surface. In-flight characterization of the instruments may allow for additional science opportunities.

Global dust storms on Mars are rare1,2 but can affect the Martian atmosphere for several months. They can cause changes in atmospheric dynamics and inflation of the atmosphere3, primarily owing to solar heating of the dust3. In turn, changes in atmospheric dynamics can affect the distribution of atmospheric water vapour, with potential implications for the atmospheric photochemistry and climate on Mars4. Recent observations of the water vapour abundance in the Martian atmosphere during dust storm conditions revealed a high-altitude increase in atmospheric water vapour that was more pronounced at high northern latitudes5,6, as well as a decrease in the water column at low latitudes7,8. Here we present concurrent, high-resolution measurements of dust, water and semiheavy water (HDO) at the onset of a global dust storm, obtained by the NOMAD and ACS instruments onboard the ExoMars Trace Gas Orbiter. We report the vertical distribution of the HDO/H2O ratio (D/H) from the planetary boundary layer up to an altitude of 80 kilometres. Our findings suggest that before the onset of the dust storm, HDO abundances were reduced to levels below detectability at altitudes above 40 kilometres. This decrease in HDO coincided with the presence of water-ice clouds. During the storm, an increase in the abundance of H2O and HDO was observed at altitudes between 40 and 80 kilometres. We propose that these increased abundances may be the result of warmer temperatures during the dust storm causing stronger atmospheric circulation and preventing ice cloud formation, which may confine water vapour to lower altitudes through gravitational fall and subsequent sublimation of ice crystals3. The observed changes in H2O and HDO abundance occurred within a few days during the development of the dust storm, suggesting a fast impact of dust storms on the Martian atmosphere.