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The discovery of efficient and stable nanopesticides with improved water solubility and sustained release effects has become particularly important. Pyrimethanil (Pyr) as a low toxicity fungicide of an aniline pyrimidine group is widely used for the prevention and control of gray mold in crops and ornamental plants, however, poor water solubility hinders its further development. Herein, we use a supramolecular self-assembly process to encapsulate a pyrimethanil in a hydroxypropyl-gamma-cyclodextrin (HPγCD) via electrostatic interactions, thereby constructing the inclusion complex nanofibers. The HPγCD as an environmentally friendly carrier material for pesticide delivery is favorable for facilitating the control efficacy, water solubility, and thermostability with Pyr. The diameter of the prepared inclusion nanofiber is 426.6 ± 82.1 nm. Pyr/HPγCD inclusion complex nanofibers could be completely dissolved in water within 3 s. As predicted, the fungicidal activity of Pyr/HPγCD inclusion complex nanofibers is much higher than that of either Pyr, and the EC50 value of Pyr/HPγCD inclusion nanofibers is 0.437 μg/mL, which is about half of that of Pyr (0.840 μg/mL). The inclusion strategy achieved by Pyr and HPγCD is important for improving the safety of nanopesticides. This work provides a versatile insight to promote the development of water-based pesticide dosage forms and reduce pesticide losses in agricultural production.

Combustion instability is an abnormal working state that often occurs in advanced solid rocket motors (SRMs), which can arouse pressure oscillations, increase the risk of mission failure, and even cause structural damage. In this paper, a numerical simulation method is adapted to analyze the combustion instability problem of a typical finocyl grain SRM, and the working process and pressure oscillation of different-structure SRMs are compared and analyzed. Firstly, the acoustic finite element analysis (FEA) method and the large eddy simulation (LES) method for SRM combustion instability analysis are given. Then, the numerical simulation method presented in this paper is verified by comparing the present results with the experimental data of Ariane-5 P230 motor, and finally, the pressure oscillation characteristics of SRMs with different structures by external pulse excitation are studied. The simulation results show that the pressure decay rate of the front finocyl grain structure is faster than that of the rear finocyl grain structure under the same external excitation. The excitation position has a relatively minor influence on the decay characteristics of pressure oscillations. The results can provide a certain reference for the combustion stability design of SRMs.

Post-harvest deterioration in strawberries is an urgent and critical issue that requires significant attention. Glycerol monolaurate (GML), a broad-spectrum food-grade antimicrobial agent, faces limited applicability due to its poor water solubility. In this study, a confined encapsulation strategy was employed to encapsulate GML within hydroxypropyl-γ-cyclodextrin (HPγCD), which improved the physicochemical properties of GML and enhanced its stability in the environment. The fiber morphology was observed through scanning electron microscopy (SEM) and transmission electron microscopy (TEM), confirming the presence of a uniform, non-nodular core–shell structure. The Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) validated the successful encapsulation of GML within the cavity of HPγCD. Thermogravimetric analysis (TGA) demonstrated that the thermal stability of the core–shell system was significantly improved. In vitro release followed first-order kinetics (R2 = 0.9842), with 79.5% of GML released over 68 h. The DPPH and ABTS assays demonstrated that PLA/GML-HPγCD NF exhibited sustained radical scavenging activity (p < 0.05, ANOVA). Compared to GML-HPγCD NF, PLA/GML-HPγCD NF exhibited prolonged antibacterial activity against Escherichia coli and superior antifungal efficacy in strawberry preservation. Meanwhile, PLA/GML-HPγCD NF significantly reduced lesion diameter and weight loss while maintaining hardness, total soluble solids, and vitamin C content over 8 days of storage. In conclusion, these characteristics highlighted the potential of P/G-HPγCD NF as a promising active packaging material for extending the shelf life of perishable fruits.

The photocatalytic degradation, as an environmental-friendly technology, has great significance for cost-effective and efficient catalysis processes, wherein piezo-photocatalysis can significantly increase the catalytic degradation rate using both solar and mechanical energy. Here, a ternary heterostructure PVDF/ZnO/Au (PZA) nanobrush photocatalyst with high piezo-photocatalytic efficiency was presented via low-temperature hydrothermal and chemical reduction methods. Under both solar and mechanical energy, the current response and degradation rate of the as-synthesized PZA nanobrush all increase significantly compared with that under solar alone and under mechanical energy alone, and the excellent recyclability is investigated. It is found that the PZA nanobrush with ultrasonic-assisted piezo-photocatalysis completely degrade MO of 20 mg/L in 60 min, which exhibits greater enhancement of photocatalytic activity than with stirring-assisted piezo-photocatalysis due to higher power. The high piezo-photocatalytic activity of PZA nanobrush is attributed to the surface plasmon resonance (SPR) coupling of Au and built-in electric field originating from the ZnO and PVDF, which can increase the absorption of visible light, promote the charge transfer and separation of photogenerated electrons/holes. This work introduces the SPR and bipiezotronic effect to improve plasmonic photocatalysis with PZA heterostructures, which offers a new solution in green technologies to design high-performance catalysts for the environmental remediation.

Monitoring of drinking water has shown an increase in nitrate-nitrogen (NO ₃ ⁻ -N) concentration in groundwater in some areas of the Heihe River Basin, Northwest China. A combination of careful irrigation and nitrogen (N) management is needed to improve N uptake efficiency and to minimize fertilizer N loss. A 2-year experiment investigated the effects of different irrigation and N application rates on soil NO ₃ ⁻ -N distribution and fertilizer N loss, wheat grain yield and N uptake on recently reclaimed sandy farmland. The experiment followed a completely randomized split-plot design, taking flood irrigation (0.6, 0.8 and 1.0 of the estimated evapotranspiration) as main plot treatment and N-supply as split-plot treatment (with five levels of 0, 79, 140, 221, 300 kg N ha⁻¹). Fertilizer N loss was calculated according to N balance equation. Our results showed that, under deficit irrigation conditions, N fertilizer application at a rate of 300 kg ha⁻¹ promoted NO ₃ ⁻ -N concentration in 0-200 cm depth soil profiles, and treatments with 221 kg N ha⁻¹ also increased soil NO ₃ ⁻ -N concentrations only in the surface layers. Fertilizer N rates of 70 and 140 kg ha⁻¹ did not increase NO ₃ ⁻ -N concentration in the 0-200 cm soil profile remaining after the spring wheat growing season. The amount of residual NO ₃ ⁻ -N in soil profiles decreased with the amount of irrigation. Compared with N₀, the increases of fertilizer N loss, in N₇₉, N₁₄₀, N₂₂₁ and N₃₀₀ respectively, were 59.9, 104.6, 143.5 and 210.6 kg ha⁻¹ over 2 years. Under these experimental conditions, a N rate of 221 kg ha⁻¹ obtained the highest values of grain yield (2775 kg ha⁻¹), above-ground dry matter (5310 kg ha⁻¹) and plant N uptake (103.8 kg ha⁻¹) over 2 years. The results clearly showed that the relative high grain yield and irrigation water productivity, and relative low N loss were achieved with application of 221 kg N ha⁻¹ and low irrigation, the recommendation should be for those farmers who use the upper range of the recommended 150-400 kg N ha⁻¹, that they can save about 45% of their N and 40% of their irrigation water application.

Leaf shape is a vital agronomic trait that affects plant and canopy architecture, yield, and other production attributes of upland cotton. Compared with normal leaves, lobed leaves have potential advantages in improving canopy structure and increasing cotton yield. A chromosomal introgression segment from Gossypium barbadense L. conferring sub-okra leaf shape to Gossypium hirsutum L. was identified on chromosome D01. To determine the effects of this transferred sub-okra leaf shape on the leaf anatomical characteristics, photosynthesis-related traits, and yield of short-season cotton, we performed a field experiment with three sets of near-isogenic lines carrying okra, sub-okra, and normal leaf shape in Lu54 (L54) and Shizao 2 (SZ2) backgrounds. Compared with normal leaves, sub-okra leaves exhibited reduced leaf thickness and smaller leaf mass per area; moreover, the deeper lobes of sub-okra leaves improved the plant canopy structure by decreasing leaf area index by 11.24%–22.84%. Similarly, the intercepted PAR rate of lines with sub-okra leaf shape was also reduced. The chlorophyll content of sub-okra leaves was lower than that of okra and normal leaf shapes; however, the net photosynthetic rate of sub-okra leaves was 8.17%–29.81% higher than that of other leaf shapes at most growth stages. Although the biomass of lines with sub-okra leaf shape was less than that of lines with normal leaves, the average first harvest yield and total yield of lines with the sub-okra leaf shape increased by 6.36% and 5.72%, respectively, compared with those with normal leaves. Thus, improvements in the canopy structure and photosynthetic and physiological characteristics contributed to optimizing the light environment, thereby increasing the yield of lines with sub-okra leaf shape. Our results suggest that the sub-okra leaf trait from G. barbadense L. may have practical applications for cultivating short-season varieties with high photosynthetic efficiency, and improving yield, which will be advantageous for short-season varieties.

This study addresses the challenge of estimating reference crop evapotranspiration (ETO) in Xizang Plateau irrigation districts with limited meteorological data by proposing a coupled LASSO-BP model that integrates LASSO regression with a BP neural network. The model was applied to three irrigation districts: Moda (MD), Jiangbei (JB), and Manla (ML). Using ETO values calculated by the FAO-56 Penman–Monteith (FAO-56PM) model as a benchmark, the performance and applicability of the LASSO-BP model were assessed. Short-term ETO predictions for the three districts were also conducted using the mean-generating function optimal subset regression algorithm. The results revealed significant multicollinearity among six meteorological factors (maximum temperature, minimum temperature, average temperature, average relative humidity, sunshine duration, and average wind speed), as identified through tolerance, variance inflation factor (VIF), and eigenvalue analysis. The LASSO-BP model effectively captured the interannual variation of ETO, accurately identifying peaks and troughs, with trends closely aligned with the FAO-56PM model. The model demonstrated strong performance across all three districts, with evaluation metrics showing MAE, RMSE, NSE, and R2 values ranging from 4.26 to 9.48 mm·a−1, 5.91 to 11.78 mm·a−1, 0.92 to 0.96, and 0.82 to 0.94, respectively. Prediction results indicated a statistically insignificant declining trend in annual ETO across the three districts over the study period. Overall, the LASSO-BP model is a reliable and accurate tool for estimating ETO in Xizang Plateau irrigation districts with limited meteorological data.

A field study was conducted to determine runoff efficiency and the effects of different ridge: furrow ratios and ridge-covering materials on tuber yield, soil moisture storage and water use efficiency (WUE) in the ridge and furrow micro-water harvesting system in a dry semi-arid region of China, during two consecutive years of 2002 and 2003. The average runoff efficiency of ridges with compacted soil (SR) was very low (24.6-28.8%) compared to that of ridges covered with plastic film (MR) (91.1-94.3%). The minimal rainfall necessary to produce runoff was 2.76-2.78 mm for SR, only 0.23-0.47 mm for MR. The field experiments using potato as an indicator crop showed that tuber yields in the MR system were significantly higher than that in the flat planting (control), with an average increase of 158.6-175.0% during 2 years. In the SR system, the average increase was valued of 14.9-28.4% during 2 years. Regression analysis between tuber yields and ridge widths indicated the optimum ridge: furrow ratio for MR was 39: 60 cm in 2002 and 48: 60 cm in 2003 respectively. The WUE values of potato in MR were 1.50 times greater than that of the controls in 2002 and 1.62 times greater than the controls in 2003. No differences were found in the WUE between the SR and the controls on average of 2 years. Due to the different runoff efficiency between two ridge-covering materials and absence of runoff occurrence in the controls, the soil water content in the MR was higher than that in the SR, both of which were greater than the controls. With the soil crust development, the distribution of soil water at the bottom of the furrow, at the side of the furrow and at the top of the ridge, is similar between the SR and the MR.

Introduction: The measurement of soil magnetic susceptibility is rapid, nondestructive, and highly sensitive and has, therefore, been widely applied in soil research. In soil systems, the relationship between environmental factors and magnetic susceptibility is complex and interferes with the interpretation of magnetic susceptibility data. Therefore, clarifying the effects of soil factors on magnetic susceptibility and their mechanisms is necessary to explain changes in magnetic susceptibility. Magnetic characterization of tropical forest soils, which is primarily indicative of the climate, has been relatively poorly studied. Therefore, the magnetic characteristics of tropical forest soils and their correlations with soil physical and chemical properties must be systematically studied. Here, we describe a tropical rainforest soil profile that has not been disturbed by human activities and its patterns of low-frequency magnetic susceptibility (χlf), frequency-dependent magnetic susceptibility (χfd%), and susceptibility of anhysteretic remanent magnetization (χARM).Methods: Soil sampling was conducted in six plots in Xishuangbanna, China. Soil profiles were explored in 11 layers, and various soil properties were measured. Magnetic susceptibility was assessed using susceptometry, and structural equation modeling was used to analyze the relationships between soil factors and magnetic susceptibility.Results: In all profiles, the values of χlf and χARM increased with depth from 0 to 30 cm, decreased with depth from 30 to 80 cm, and tended to stabilize below 80 cm. χfd% values increased with depth from 0 to 80 cm and decreased with depth below 80 cm, with particularly rapid attenuation at the bottom of the F1 and F6 profiles. Soil properties were determined, including bulk density, water content, electrical conductivity (EC), soil particle size, soil organic carbon (SOC), pH, free iron (Fed), poorly crystalline iron (Feo), total iron (Fet), total nitrogen (TN), and the primary chemical elements P, S, K, Si, Al, Mn, Mg, and Zr. Linear regression and structural equation modeling were used to explore the relationships between soil factors and χlf, to identify the main factors influencing the vertical distribution of soil χlf, and to analyze the processes and mechanisms by which various factors affect χlf. The results showed that the positive influence path followed EC → SOC → TN → Feo → χlf, and the negative influence path followed pH → N → Feo → χlf. Feo was the most important factor that directly affects χlf (β = 0.952). The ferrihydrite in Feo forms fine-grained magnetite and maghemite via the aging process, which is the main mechanism for increasing χlf in the 0–80-cm layer in this area. TN had an important effect on χlf because it affects Feo (β = 0.85).Discussion: SOC, pH, and EC indirectly affect χlf by promoting the conversion of ferrihydrite and silicate-bound iron to Feo. This study highlights the role of forest soils in storing SOC and nutrients, contributing to the ecological management of forest soils.

Agricultural irrigation depends heavily on freshwater resources. Under the context of increasingly severe water shortages, studying the relationship among crop water requirements (ETc), actual crop evapotranspiration (ETa), irrigation water requirements (Ir), yield, and water use efficiency (WUE) would be beneficial to improve the agricultural application of irrigation water. Based on the daily data of 26 meteorological stations in Heilongjiang Province from 1960 to 2015, this study used the calibrated AquaCrop model to calculate the ETc, ETa, Ir, and yield of maize (Zea mays L.) in different hydrological years (extremely dry years, dry years, normal years, and wet years) along with WUE to evaluate the mass of yield produced per unit mass of crop evapotranspiration (ET) under rainfed and irrigated scenarios. The results showed that ETc and ETa decreased first and then increased from the west to the east during the four types of hydrological years. Ir exhibited a decreasing trend from the west to the east. Compared with the irrigation scenario, the rainfed scenario’s average yield only decreased by 2.18, 0.55, 0.03, and 0.05 ton/ha, while the WUE increased by 0.32, 0.4, 0.33, and 0.21 kg/m3 in the extremely dry years, dry years, normal years, and wet years, respectively. The results indicated that in the normal and wet years, the WUE was high in the central regions, and irrigation did not significantly increase yield; further, we determined that irrigation should not be considered in these two hydrological years in Heilongjiang Province. In the extremely dry and dry years, irrigation was necessary because it increased the yield, even though the WUE decreased. This study provides a theoretical basis for studying the regional irrigation schedule in Heilongjiang Province.